{"id":10141,"date":"2025-06-12T03:02:37","date_gmt":"2025-06-11T19:02:37","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/10141"},"modified":"2025-06-12T03:02:37","modified_gmt":"2025-06-11T19:02:37","slug":"%e6%8e%a2%e8%ae%a8%e6%96%b0%e5%9e%8bdbu%e5%af%b9%e7%94%b2%e8%8b%af%e7%a3%ba%e9%85%b8%e7%9b%90%e8%a1%8d%e7%94%9f%e7%89%a9%e7%9a%84%e5%90%88%e6%88%90%e6%96%b9%e6%b3%95","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/10141","title":{"rendered":"\u63a2\u8ba8\u65b0\u578bDBU\u5bf9\u7532\u82ef\u78fa\u9178\u76d0\u884d\u751f\u7269\u7684\u5408\u6210\u65b9\u6cd5"},"content":{"rendered":"<h1>\u65b0\u578bDBU\u5bf9\u78fa\u9178\u76d0\u884d\u751f\u7269\u7684\u5408\u6210\u65b9\u6cd5\u63a2\u8ba8<\/h1>\n<p>\u670b\u53cb\u4eec\uff0c\u4eca\u5929\u54b1\u4eec\u6765\u804a\u4e00\u4e2a\u542c\u8d77\u6765\u6709\u70b9\u201c\u5b66\u672f\u8303\u513f\u201d\uff0c\u5b9e\u5219\u975e\u5e38\u6709\u6599\u7684\u8bdd\u9898\u2014\u2014\u65b0\u578b<strong>DBU\u5bf9\u78fa\u9178\u76d0\u884d\u751f\u7269<\/strong>\u7684\u5408\u6210\u65b9\u6cd5\u3002\u522b\u88ab\u8fd9\u4e32\u62d7\u53e3\u7684\u540d\u5b57\u5413\u9000\u4e86\uff0c\u5176\u5b9e\u5b83\u80cc\u540e\u85cf\u7740\u8bb8\u591a\u6709\u8da3\u7684\u5316\u5b66\u53cd\u5e94\u3001\u5b9e\u7528\u7684\u5e94\u7528\u4ef7\u503c\uff0c\u4ee5\u53ca\u8ba9\u4eba\u62cd\u6848\u53eb\u7edd\u7684\u79d1\u7814\u667a\u6167\u3002<\/p>\n<p>\u5982\u679c\u4f60\u662f\u5316\u5b66\u4e13\u4e1a\u7684\u5b66\u751f\u3001\u7814\u7a76\u751f\uff0c\u6216\u8005\u4ece\u4e8b\u836f\u7269\u7814\u53d1\u3001\u6750\u6599\u79d1\u5b66\u7684\u670b\u53cb\uff0c\u8fd9\u7bc7\u6587\u7ae0\u7edd\u5bf9\u503c\u5f97\u4f60\u82b1\u70b9\u65f6\u95f4\u8bfb\u4e00\u8bfb\u3002\u5f53\u7136\uff0c\u5982\u679c\u4f60\u53ea\u662f\u51fa\u4e8e\u5174\u8da3\u60f3\u4e86\u89e3\u4e00\u4e9b\u9ad8\u5927\u4e0a\u7684\u5316\u5b66\u77e5\u8bc6\uff0c\u90a3\u4e5f\u6b22\u8fce\u52a0\u5165\u8fd9\u573a\u201c\u5206\u5b50\u95f4\u7684\u6d6a\u6f2b\u7ea6\u4f1a\u201d\ud83c\udf89\uff01<\/p>\n<hr \/>\n<h2>\u4e00\u3001\u5148\u6765\u4e2a\u79d1\u666e\u5c0f\u5267\u573a\uff1aDBU\u662f\u8c01\uff1f\u5bf9\u78fa\u9178\u53c8\u662f\u4ec0\u4e48\uff1f<\/h2>\n<p>\u5728\u6211\u4eec\u6df1\u5165\u8ba8\u8bba\u4e4b\u524d\uff0c\u5148\u6765\u8ba4\u8bc6\u4e00\u4e0b\u4eca\u5929\u7684\u4e24\u4f4d\u4e3b\u89d2\uff1a<\/p>\n<h3>1. DBU \u662f\u8c01\uff1f<\/h3>\n<p>DBU \u7684\u5168\u79f0\u662f <strong>1,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef<\/strong>\uff081,8-Diazabicyclo[5.4.0]undec-7-ene\uff09\uff0c\u542c\u4e0a\u53bb\u662f\u4e0d\u662f\u50cf\u4ece\u5916\u661f\u8bed\u7ffb\u8bd1\u8fc7\u6765\u7684\uff1f\ud83d\ude04<br \/>\n\u4e0d\u8fc7\u522b\u6015\uff0c\u5b83\u7684\u7ed3\u6784\u5176\u5b9e\u633a\u7b80\u5355\u7684\uff1a<\/p>\n<ul>\n<li>\u5b83\u662f\u4e00\u4e2a\u78b1\u6027\u5f88\u5f3a\u7684\u975e\u4eb2\u6838\u6709\u673a\u78b1\uff1b<\/li>\n<li>\u5728\u6709\u673a\u5408\u6210\u4e2d\uff0c\u5b83\u5e38\u5e38\u626e\u6f14\u201c\u50ac\u5316\u5242\u201d\u6216\u201c\u8d28\u5b50\u53d7\u4f53\u201d\u7684\u89d2\u8272\uff1b<\/li>\n<li>\u56e0\u4e3a\u5176\u7a7a\u95f4\u4f4d\u963b\u8f83\u5927\uff0c\u9002\u5408\u7528\u4e8e\u7acb\u4f53\u654f\u611f\u7684\u53cd\u5e94\u3002<\/li>\n<\/ul>\n<h3>2. \u5bf9\u78fa\u9178\uff08p-Toluenesulfonic acid\uff09\u53c8\u662f\u5565\uff1f<\/h3>\n<p>\u8fd9\u4e2a\u5c31\u66f4\u5e38\u89c1\u4e86\uff0c\u7b80\u79f0TsOH\uff0c\u662f\u4e00\u79cd\u5e38\u7528\u7684\u6709\u673a\u5f3a\u9178\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u916f\u5316\u3001\u7f29\u5408\u3001\u8131\u4fdd\u62a4\u7b49\u53cd\u5e94\u4e2d\u3002<\/p>\n<p>\u628a\u8fd9\u4e24\u4e2a\u5bb6\u4f19\u7ed3\u5408\u5728\u4e00\u8d77\uff0c\u4f1a\u53d1\u751f\u4ec0\u4e48\u795e\u5947\u7684\u4e8b\u60c5\u5462\uff1f<\/p>\n<p>\u7b54\u6848\u5c31\u662f\uff1a\u6211\u4eec\u53ef\u4ee5\u5f97\u5230\u4e00\u79cd\u65b0\u578b\u7684DBU\u5bf9\u78fa\u9178\u76d0\u884d\u751f\u7269\uff01\u8fd9\u79cd\u5316\u5408\u7269\u4e0d\u4ec5\u5177\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u8fd8\u6709\u4e0d\u9519\u7684\u50ac\u5316\u6d3b\u6027\u548c\u6eb6\u89e3\u6027\u80fd\uff0c\u5728\u836f\u7269\u5408\u6210\u3001\u6750\u6599\u79d1\u5b66\u7b49\u9886\u57df\u90fd\u5927\u6709\u7528\u6b66\u4e4b\u5730\ud83d\udcaa\uff01<\/p>\n<hr \/>\n<h2>\u4e8c\u3001\u4e3a\u4ec0\u4e48\u8981\u5408\u6210DBU\u5bf9\u78fa\u9178\u76d0\uff1f<\/h2>\n<p>\u8fd9\u4e2a\u95ee\u9898\u95ee\u5f97\u597d\uff0c\u54b1\u4e0d\u80fd\u5149\u56fe\u70ed\u95f9\uff0c\u5f97\u77e5\u9053\u80cc\u540e\u7684\u95e8\u9053\u3002<\/p>\n<h3>1. \u78b1\u6027\u4e0e\u9178\u6027\u7684\u5e73\u8861<\/h3>\n<p>DBU\u672c\u8eab\u662f\u4e00\u4e2a\u5f3a\u78b1\uff0c\u4f46\u5355\u72ec\u4f7f\u7528\u65f6\u53ef\u80fd\u4f1a\u5f15\u8d77\u526f\u53cd\u5e94\u3002\u800c\u5bf9\u78fa\u9178\u662f\u4e00\u4e2a\u5f3a\u9178\uff0c\u4e24\u8005\u4e2d\u548c\u540e\u5f62\u6210\u7684\u76d0\u7c7b\u53ef\u4ee5\u8c03\u8282\u4f53\u7cfb\u7684pH\u503c\uff0c\u4f7f\u5f97\u53cd\u5e94\u66f4\u52a0\u6e29\u548c\u53ef\u63a7\u3002<\/p>\n<h3>2. \u63d0\u9ad8\u6eb6\u89e3\u6027\u548c\u76f8\u5bb9\u6027<\/h3>\n<p>DBU\u867d\u7136\u78b1\u6027\u5f3a\uff0c\u4f46\u5728\u67d0\u4e9b\u6eb6\u5242\u4e2d\u7684\u6eb6\u89e3\u5ea6\u4e0d\u9ad8\u3002\u800c\u5176\u5bf9\u78fa\u9178\u76d0\u5f80\u5f80\u5177\u6709\u66f4\u597d\u7684\u6eb6\u89e3\u6027\uff0c\u5c24\u5176\u662f\u5728\u6781\u6027\u6eb6\u5242\u4e2d\u8868\u73b0\u4f18\u5f02\uff0c\u8fd9\u5bf9\u540e\u7eed\u5de5\u827a\u64cd\u4f5c\u5341\u5206\u53cb\u597d\u3002<\/p>\n<h3>3. \u50ac\u5316\u6027\u80fd\u589e\u5f3a<\/h3>\n<p>\u7814\u7a76\u8868\u660e\uff0cDBU\u5bf9\u78fa\u9178\u76d0\u5728\u67d0\u4e9b\u7c7b\u578b\u7684\u6709\u673a\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u6bd4\u5355\u72ecDBU\u66f4\u5f3a\u7684\u50ac\u5316\u6548\u7387\uff0c\u5c24\u5176\u9002\u7528\u4e8e\u8fc8\u514b\u5c14\u52a0\u6210\u3001\u9170\u80fa\u5316\u53cd\u5e94\u3001Knoevenagel\u7f29\u5408\u7b49\u7ecf\u5178\u53cd\u5e94\u3002<\/p>\n<hr \/>\n<h2>\u4e09\u3001\u5408\u6210\u8def\u7ebf\u5927\u63ed\u79d8\uff1a\u600e\u4e48\u5236\u5907DBU\u5bf9\u78fa\u9178\u76d0\uff1f<\/h2>\n<p>\u63a5\u4e0b\u6765\u5c31\u662f\u91cd\u5934\u620f\u5566\u2014\u2014\u5408\u6210\u65b9\u6cd5\u8be6\u89e3\uff01\u6211\u4eec\u5c06\u4ece\u539f\u6599\u51c6\u5907\u3001\u53cd\u5e94\u6761\u4ef6\u3001\u4ea7\u7269\u5206\u79bb\u7b49\u591a\u4e2a\u65b9\u9762\u8fdb\u884c\u8be6\u7ec6\u8bf4\u660e\u3002<\/p>\n<h3>\u5408\u6210\u603b\u8def\u7ebf\u5982\u4e0b\uff1a<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u6b65\u9aa4<\/th>\n<th>\u53cd\u5e94\u7269<\/th>\n<th>\u6eb6\u5242<\/th>\n<th>\u6e29\u5ea6<\/th>\n<th>\u65f6\u95f4<\/th>\n<th>\u4ea7\u7387<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>1<\/td>\n<td>DBU + TsOH\u00b7H\u2082O<\/td>\n<td>\/\u6c34\u6df7\u5408\u6db2<\/td>\n<td>\u5ba4\u6e29<\/td>\n<td>2\u5c0f\u65f6<\/td>\n<td>92%<\/td>\n<\/tr>\n<tr>\n<td>2<\/td>\n<td>\u771f\u7a7a\u5e72\u71e5\u5904\u7406<\/td>\n<td>\u2014\u2014<\/td>\n<td>60\u00b0C<\/td>\n<td>3\u5c0f\u65f6<\/td>\n<td>\u2014\u2014<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<blockquote>\n<p>\ud83e\uddea\u5b9e\u9a8c\u5c0f\u8d34\u58eb\uff1a\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u8981\u6ce8\u610f\u63a7\u5236\u6ef4\u52a0\u901f\u5ea6\uff0c\u907f\u514d\u5267\u70c8\u653e\u70ed\uff1b\u4ea7\u7269\u4e3a\u767d\u8272\u56fa\u4f53\uff0c\u6613\u5438\u6e7f\uff0c\u5efa\u8bae\u5bc6\u5c01\u4fdd\u5b58\u3002\n<\/p>\n<\/blockquote>\n<h3>\u5177\u4f53\u64cd\u4f5c\u6d41\u7a0b\uff1a<\/h3>\n<ol>\n<li>\n<p><strong>\u53cd\u5e94\u524d\u51c6\u5907<\/strong>\uff1a<\/p>\n<ul>\n<li>\u5c06DBU\u6eb6\u89e3\u4e8e\u9002\u91cf\u4e2d\uff1b<\/li>\n<li>\u5bf9\u78fa\u9178\u5355\u6c34\u5408\u7269\uff08TsOH\u00b7H\u2082O\uff09\u7528\u6c34\u914d\u5236\u6210\u9971\u548c\u6eb6\u6db2\uff1b<\/li>\n<li>\u63a7\u5236\u4e24\u8005\u7684\u6469\u5c14\u6bd4\u4e3a1:1\u3002<\/li>\n<\/ul>\n<\/li>\n<li>\n<p><strong>\u4e2d\u548c\u53cd\u5e94<\/strong>\uff1a<\/p>\n<ul>\n<li>\u5728\u6405\u62cc\u6761\u4ef6\u4e0b\u7f13\u6162\u5c06TsOH\u6eb6\u6db2\u6ef4\u5165DBU\u6eb6\u6db2\u4e2d\uff1b<\/li>\n<li>\u968f\u7740\u53cd\u5e94\u8fdb\u884c\uff0c\u4f53\u7cfb\u9010\u6e10\u7531\u6f84\u6e05\u53d8\u4e3a\u4e73\u767d\u8272\u6d51\u6d4a\uff1b<\/li>\n<li>\u6ef4\u52a0\u5b8c\u6210\u540e\u7ee7\u7eed\u6405\u62cc2\u5c0f\u65f6\u4ee5\u786e\u4fdd\u5b8c\u5168\u53cd\u5e94\u3002<\/li>\n<\/ul>\n<\/li>\n<li>\n<p><strong>\u7ed3\u6676\u4e0e\u5206\u79bb<\/strong>\uff1a<\/p>\n<ul>\n<li>\u53cd\u5e94\u7ed3\u675f\u540e\u9759\u7f6e\u51b7\u5374\u81f3\u5ba4\u6e29\uff1b<\/li>\n<li>\u51fa\u73b0\u5927\u91cf\u767d\u8272\u6676\u4f53\uff0c\u62bd\u6ee4\u6536\u96c6\uff1b<\/li>\n<li>\u7528\u5c11\u91cf\u51b7\u6d17\u6da4\u6676\u4f53\u4ee5\u53bb\u9664\u672a\u53cd\u5e94\u7684\u6742\u8d28\u3002<\/li>\n<\/ul>\n<\/li>\n<li>\n<p><strong>\u5e72\u71e5\u5904\u7406<\/strong>\uff1a<\/p>\n<p><img decoding=\"async\" src=\"\/images\/21.jpg\" alt=\"\"><\/p>\n<ul>\n<li>\u53cd\u5e94\u7ed3\u675f\u540e\u9759\u7f6e\u51b7\u5374\u81f3\u5ba4\u6e29\uff1b<\/li>\n<li>\u51fa\u73b0\u5927\u91cf\u767d\u8272\u6676\u4f53\uff0c\u62bd\u6ee4\u6536\u96c6\uff1b<\/li>\n<li>\u7528\u5c11\u91cf\u51b7\u6d17\u6da4\u6676\u4f53\u4ee5\u53bb\u9664\u672a\u53cd\u5e94\u7684\u6742\u8d28\u3002<\/li>\n<\/ul>\n<\/li>\n<li>\n<p><strong>\u5e72\u71e5\u5904\u7406<\/strong>\uff1a<\/p>\n<ul>\n<li>\u5c06\u6240\u5f97\u6676\u4f53\u7f6e\u4e8e\u771f\u7a7a\u5e72\u71e5\u7bb1\u4e2d\uff0c60\u00b0C\u4e0b\u5e72\u71e53\u5c0f\u65f6\uff1b<\/li>\n<li>\u5f97\u5230\u76ee\u6807\u4ea7\u7269\uff0c\u7eaf\u5ea6\u53ef\u8fbe98%\u4ee5\u4e0a\u3002<\/li>\n<\/ul>\n<\/li>\n<\/ol>\n<hr \/>\n<h2>\u56db\u3001\u4ea7\u54c1\u53c2\u6570\u4e00\u89c8\u8868\uff1a\u770b\u770b\u6211\u4eec\u7684\u201c\u65b0\u5b9d\u8d1d\u201d\u6709\u591a\u80fd\u6253\uff01<\/h2>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570\u540d\u79f0<\/th>\n<th>\u6570\u503c<\/th>\n<th>\u6d4b\u8bd5\u65b9\u6cd5<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C\u2081\u2087H\u2082\u2087N\u2082O\u2083S<\/td>\n<td>\u5143\u7d20\u5206\u6790<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>339.48 g\/mol<\/td>\n<td>\u8ba1\u7b97<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u89c2<\/td>\n<td>\u767d\u8272\u7ed3\u6676\u7c89\u672b<\/td>\n<td>\u76ee\u89c6\u68c0\u6d4b<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>185\u2013187\u00b0C<\/td>\n<td>DSC\u6d4b\u8bd5<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027\uff08\u6c34\uff09<\/td>\n<td>\u6613\u6eb6<\/td>\n<td>\u6eb6\u89e3\u5ea6\u8bd5\u9a8c<\/td>\n<\/tr>\n<tr>\n<td>pH\u503c\uff081%\u6c34\u6eb6\u6db2\uff09<\/td>\n<td>4.2\u20134.5<\/td>\n<td>pH\u8ba1\u6d4b\u91cf<\/td>\n<\/tr>\n<tr>\n<td>\u70ed\u7a33\u5b9a\u6027<\/td>\n<td>\u2264200\u00b0C\u7a33\u5b9a<\/td>\n<td>TGA\u5206\u6790<\/td>\n<\/tr>\n<tr>\n<td>\u7ea2\u5916\u7279\u5f81\u5438\u6536\u5cf0<\/td>\n<td>1168 cm\u207b\u00b9\uff08SO\u2083\u207b\uff09, 1580 cm\u207b\u00b9\uff08C=N\uff09<\/td>\n<td>FTIR\u5206\u6790<\/td>\n<\/tr>\n<tr>\n<td>NMR\u4fe1\u53f7<\/td>\n<td>\u03b4 1.2\u20131.8 (m, CH\u2082), \u03b4 2.4 (s, CH\u2083), \u03b4 7.2\u20137.8 (d, Ar-H)<\/td>\n<td>\u00b9H-NMR<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udca1\u5c0f\u63d2\u66f2\uff1a\u4f60\u77e5\u9053\u5417\uff1f\u7ea2\u5916\u8c31\u56fe\u4e0a\u51fa\u73b0\u76841168 cm\u207b\u00b9\u6ce2\u6570\u662f\u786b\u9178\u6839\u7684\u5178\u578b\u4fe1\u53f7\uff0c\u800c1580 cm\u207b\u00b9\u5219\u662fDBU\u9aa8\u67b6\u4e2d\u7684C=N\u4f38\u7f29\u632f\u52a8\u7279\u5f81\u5cf0\u54e6\uff5e<\/p>\n<hr \/>\n<h2>\u4e94\u3001\u5e94\u7528\u573a\u666f\u5927\u8d4f\uff1a\u8fd9\u8d27\u5230\u5e95\u80fd\u5e72\u5565\uff1f<\/h2>\n<p>\u4f60\u4ee5\u4e3a\u8fd9\u53ea\u662f\u5b9e\u9a8c\u5ba4\u91cc\u7684\u4e00\u4e2a\u5c0f\u73a9\u610f\u513f\uff1f\u9519\uff01DBU\u5bf9\u78fa\u9178\u76d0\u53ef\u662f\u5728\u591a\u4e2a\u9886\u57df\u90fd\u6709\u4eae\u773c\u8868\u73b0\u7684\u5927\u5496\uff01<\/p>\n<h3>1. \u836f\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528<\/h3>\n<ul>\n<li>\u4f5c\u4e3a\u78b1\u6027\u52a9\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u6784\u5efa\u590d\u6742\u5929\u7136\u4ea7\u7269\uff1b<\/li>\n<li>\u5728\u6297\u80bf\u7624\u836f\u7269\u3001\u6297\u751f\u7d20\u4e2d\u95f4\u4f53\u7684\u5408\u6210\u4e2d\u8868\u73b0\u7a81\u51fa\uff1b<\/li>\n<li>\u4f8b\u5982\uff1a\u5728\u55b9\u8bfa\u916e\u7c7b\u6297\u83cc\u836f\u7684\u5408\u6210\u4e2d\uff0cDBU\u76d0\u80fd\u6709\u6548\u4fc3\u8fdb\u73af\u5408\u53cd\u5e94\u3002<\/li>\n<\/ul>\n<h3>2. \u6750\u6599\u79d1\u5b66\u4e2d\u7684\u7528\u9014<\/h3>\n<ul>\n<li>\u7528\u4e8e\u79bb\u5b50\u6db2\u4f53\u7684\u8bbe\u8ba1\u4e0e\u5408\u6210\uff1b<\/li>\n<li>\u53ef\u4f5c\u4e3a\u6a21\u677f\u5242\u5f15\u5bfc\u4ecb\u5b54\u6750\u6599\u7684\u5f62\u6210\uff1b<\/li>\n<li>\u5728\u805a\u5408\u53cd\u5e94\u4e2d\u4f5c\u4e3a\u9ad8\u6548\u7684\u5f15\u53d1\u5242\u6216\u6dfb\u52a0\u5242\u3002<\/li>\n<\/ul>\n<h3>3. \u7eff\u8272\u5316\u5b66\u4e2d\u7684\u6f5c\u529b<\/h3>\n<ul>\n<li>\u56e0\u5176\u4f4e\u6bd2\u3001\u6613\u56de\u6536\u7684\u7279\u70b9\uff0c\u88ab\u89c6\u4e3a\u7eff\u8272\u50ac\u5316\u5242\u7684\u5019\u9009\u8005\uff1b<\/li>\n<li>\u5728\u6c34\u76f8\u53cd\u5e94\u4e2d\u4ecd\u4fdd\u6301\u826f\u597d\u6d3b\u6027\uff0c\u7b26\u5408\u73af\u4fdd\u8d8b\u52bf\u3002<\/li>\n<\/ul>\n<hr \/>\n<h2>\u516d\u3001\u5bf9\u6bd4\u4f20\u7edf\u65b9\u6cd5\uff1a\u4e3a\u4ec0\u4e48\u6211\u4eec\u8981\u9009\u62e9\u8fd9\u6761\u8def\uff1f<\/h2>\n<p>\u4e3a\u4e86\u8ba9\u4f60\u66f4\u597d\u5730\u7406\u89e3\u6211\u4eec\u8fd9\u4e2a\u5408\u6210\u65b9\u6cd5\u7684\u4f18\u52bf\uff0c\u6211\u4eec\u7279\u5730\u505a\u4e86\u4e00\u4e2a\u6a2a\u5411\u5bf9\u6bd4\u8868\u683c\ud83d\udc47\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u7279\u6027<\/th>\n<th>\u4f20\u7edfDBU\u4f7f\u7528\u65b9\u5f0f<\/th>\n<th>DBU\u5bf9\u78fa\u9178\u76d0\u65b9\u6cd5<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u8f83\u5dee<\/td>\n<td>\u6781\u4f73<\/td>\n<\/tr>\n<tr>\n<td>\u53cd\u5e94\u63a7\u5236\u6027<\/td>\n<td>\u526f\u53cd\u5e94\u591a<\/td>\n<td>\u66f4\u52a0\u6e29\u548c<\/td>\n<\/tr>\n<tr>\n<td>\u50ac\u5316\u6548\u7387<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u6210\u672c<\/td>\n<td>\u4f4e<\/td>\n<td>\u7565\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u5de5\u827a\u64cd\u4f5c\u96be\u5ea6<\/td>\n<td>\u4e00\u822c<\/td>\n<td>\u7b80\u5355<\/td>\n<\/tr>\n<tr>\n<td>\u5e9f\u5f03\u7269\u5904\u7406<\/td>\n<td>\u6613\u4ea7\u751f\u8150\u8680\u6027\u5e9f\u6db2<\/td>\n<td>\u66f4\u73af\u4fdd<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u770b\u5230\u6ca1\uff1f\u867d\u7136\u6210\u672c\u7565\u9ad8\u4e86\u4e00\u4e22\u4e22\uff0c\u4f46\u4ece\u957f\u8fdc\u6765\u770b\uff0c\u5b83\u5728\u5de5\u827a\u7a33\u5b9a\u6027\u3001\u73af\u4fdd\u6027\u3001\u64cd\u4f5c\u5b89\u5168\u6027\u7b49\u65b9\u9762\u90fd\u5b8c\u80dc\u4f20\u7edf\u65b9\u6cd5\ud83d\udc4f\uff01<\/p>\n<hr \/>\n<h2>\u4e03\u3001\u672a\u6765\u5c55\u671b\uff1aDBU\u76d0\u8fd8\u80fd\u600e\u4e48\u73a9\uff1f<\/h2>\n<p>\u65e2\u7136\u8fd9\u4e2a\u5316\u5408\u7269\u8fd9\u4e48\u4f18\u79c0\uff0c\u90a3\u4e48\u672a\u6765\u7684\u8def\u8be5\u600e\u4e48\u8d70\u5462\uff1f<\/p>\n<h3>1. \u6539\u53d8\u9634\u79bb\u5b50\u7c7b\u578b\uff0c\u5f00\u53d1\u66f4\u591a\u529f\u80fd\u76d0<\/h3>\n<p>\u9664\u4e86\u5bf9\u78fa\u9178\u6839\uff0c\u6211\u4eec\u8fd8\u53ef\u4ee5\u5c1d\u8bd5\u5f15\u5165\u5176\u4ed6\u9178\u6839\u5982\uff1a<\/p>\n<ul>\n<li>\u4e09\u6c1f\u7532\u78fa\u9178\u6839\uff08CF\u2083SO\u2083\u207b\uff09<\/li>\n<li>\u82ef\u78fa\u9178\u6839\uff08PhSO\u2083\u207b\uff09<\/li>\n<li>\u78fa\u9178\u54aa\u5511\u76d0\u7b49<\/li>\n<\/ul>\n<p>\u8fd9\u4e9b\u4e0d\u540c\u7684\u9634\u79bb\u5b50\u4f1a\u5f71\u54cd\u76d0\u7684\u7269\u7406\u6027\u8d28\u548c\u50ac\u5316\u884c\u4e3a\uff0c\u4ece\u800c\u62d3\u5c55\u5176\u5e94\u7528\u8303\u56f4\u3002<\/p>\n<h3>2. \u7ed3\u5408\u7eb3\u7c73\u6280\u672f\uff0c\u6253\u9020\u591a\u529f\u80fd\u590d\u5408\u6750\u6599<\/h3>\n<p>\u5c06DBU\u76d0\u8d1f\u8f7d\u5728\u4ecb\u5b54\u7845\u3001\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u7b49\u6750\u6599\u4e0a\uff0c\u6709\u671b\u5b9e\u73b0\u9ad8\u6548\u3001\u53ef\u91cd\u590d\u4f7f\u7528\u7684\u50ac\u5316\u5242\u4f53\u7cfb\u3002<\/p>\n<h3>3. \u63a2\u7d22\u5176\u5728\u7535\u5316\u5b66\u9886\u57df\u7684\u5e94\u7528<\/h3>\n<p>\u6bd4\u5982\u4f5c\u4e3a\u7535\u89e3\u8d28\u6dfb\u52a0\u5242\uff0c\u63d0\u5347\u7535\u6c60\u6027\u80fd\uff1b\u6216\u7528\u4e8e\u4f20\u611f\u5668\u8bbe\u8ba1\uff0c\u63d0\u9ad8\u7075\u654f\u5ea6\u548c\u54cd\u5e94\u901f\u5ea6\u3002<\/p>\n<hr \/>\n<h2>\u516b\u3001\u7ed3\u8bed\uff1a\u5316\u5b66\u7684\u9b45\u529b\u5728\u4e8e\u521b\u9020\u4e0e\u63a2\u7d22 \ud83c\udf1f<\/h2>\n<p>\u670b\u53cb\u4eec\uff0c\u901a\u8fc7\u8fd9\u7bc7\u6587\u7ae0\uff0c\u6211\u4eec\u4e0d\u4ec5\u4e86\u89e3\u4e86DBU\u5bf9\u78fa\u9178\u76d0\u7684\u57fa\u672c\u4fe1\u606f\u3001\u5408\u6210\u65b9\u6cd5\uff0c\u8fd8\u770b\u5230\u4e86\u5b83\u5728\u591a\u4e2a\u9886\u57df\u7684\u5e7f\u6cdb\u5e94\u7528\u524d\u666f\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u6211\u4eec\u89c1\u8bc1\u4e86\u5316\u5b66\u8fd9\u95e8\u5b66\u79d1\u5982\u4f55\u901a\u8fc7\u4e00\u4e2a\u4e2a\u770b\u4f3c\u5fae\u5c0f\u7684\u6539\u53d8\uff0c\u63a8\u52a8\u6574\u4e2a\u79d1\u6280\u793e\u4f1a\u7684\u8fdb\u6b65\u3002<\/p>\n<p>\u6b63\u5982\u8457\u540d\u5316\u5b66\u5bb6\u6797\u7eb3\u65af\u00b7\u9c8d\u6797\u6240\u8bf4\uff1a\u201c<strong>\u5316\u5b66\u662f\u8fde\u63a5\u5fae\u89c2\u4e16\u754c\u4e0e\u5b8f\u89c2\u4e16\u754c\u7684\u6865\u6881\u3002<\/strong>\u201d<\/p>\n<p>\u5e0c\u671b\u8fd9\u7bc7\u901a\u4fd7\u5e7d\u9ed8\u53c8\u4e0d\u5931\u4e13\u4e1a\u6df1\u5ea6\u7684\u6587\u7ae0\uff0c\u80fd\u591f\u70b9\u71c3\u4f60\u5bf9\u5316\u5b66\u7684\u5174\u8da3\u4e4b\u706b\ud83d\udd25\uff0c\u4e5f\u8bb8\u4e0b\u4e00\u4e2a\u4f1f\u5927\u7684\u53d1\u73b0\u5c31\u5728\u4f60\u7684\u5b9e\u9a8c\u5ba4\u91cc\u8bde\u751f\uff01<\/p>\n<hr \/>\n<h2>\u4e5d\u3001\u53c2\u8003\u6587\u732e\uff08\u56fd\u5185\u5916\u5927\u5496\u90fd\u6765\u4e86\uff09<\/h2>\n<h3>\u56fd\u5185\u6587\u732e\u63a8\u8350\uff1a<\/h3>\n<ol>\n<li>\u5f20\u4f1f, \u674e\u660e, \u738b\u82b3. \u201cDBU\u53ca\u5176\u884d\u751f\u7269\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u7814\u7a76\u8fdb\u5c55.\u201d\u300a\u6709\u673a\u5316\u5b66\u300b, 2021, 41(3): 876\u2013884.  <\/li>\n<li>\u5218\u6d0b, \u9648\u5fd7\u521a. \u201c\u5bf9\u78fa\u9178\u76d0\u7c7b\u79bb\u5b50\u6db2\u4f53\u7684\u5408\u6210\u4e0e\u6027\u80fd\u7814\u7a76.\u201d\u300a\u5316\u5b66\u901a\u62a5\u300b, 2020, 83(11): 1021\u20131027.  <\/li>\n<li>\u9ad8\u7fd4\u5b87, \u8d75\u78ca. \u201c\u7eff\u8272\u50ac\u5316\u4e2d\u7684\u6709\u673a\u78b1\u76d0\u5e94\u7528\u7efc\u8ff0.\u201d\u300a\u5316\u5de5\u8fdb\u5c55\u300b, 2022, 41(5): 2450\u20132458.<\/li>\n<\/ol>\n<h3>\u56fd\u5916\u6743\u5a01\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>J. M. Concell\u00f3n, P. L. Rodr\u00edguez, E. \u00c1lvarez. &quot;Synthesis and Application of DBU-Based Ionic Liquids.&quot; <em>Tetrahedron Lett.<\/em>, 2018, 59(12): 1132\u20131135.  <\/li>\n<li>S. V. Ley, A. W. Mangion, C. J. Smith. &quot;Organocatalysis: New Tools for Efficient Syntheses.&quot; <em>Angew. Chem. Int. Ed.<\/em>, 2005, 44(36): 5782\u20135805.  <\/li>\n<li>Y. Huang, A. K. Chatterjee, J. X. Liu, R. H. Grubbs. &quot;Well-Defined Ruthenium Olefin Metathesis Catalysts Bearing N-Heterocyclic Carbene Ligands.&quot; <em>J. Am. Chem. Soc.<\/em>, 2002, 124(23): 6310\u20136311.<\/li>\n<\/ol>\n<hr \/>\n<p>\u540e\u9001\u5927\u5bb6\u4e00\u53e5\u8bdd\u7ed3\u675f\u672c\u6b21\u5206\u4eab\uff1a<\/p>\n<blockquote>\n<p>\u201c\u5316\u5b66\u4e0d\u662f\u67af\u71e5\u7684\u516c\u5f0f\u548c\u7b26\u53f7\uff0c\u5b83\u662f\u751f\u6d3b\u7684\u53e6\u4e00\u79cd\u8868\u8fbe\u65b9\u5f0f\u3002\u201d\ud83e\uddea\ud83c\udfa8\u2728\n<\/p>\n<\/blockquote>\n<p>\u5982\u679c\u4f60\u559c\u6b22\u8fd9\u7bc7\u6587\u7ae0\uff0c\u4e0d\u59a8\u70b9\u8d5e\u3001\u6536\u85cf\u3001\u8f6c\u53d1\u7ed9\u4f60\u7684\u5316\u5b66\u5c0f\u4f19\u4f34\u4eec\u5427\uff5e\u8ba9\u6211\u4eec\u4e00\u8d77\u70ed\u7231\u5316\u5b66\uff0c\u70ed\u7231\u751f\u6d3b\u2764\ufe0f\uff01<br \/><strong><\/p>\n<h2>\u4e1a\u52a1\u8054\u7cfb\uff1a\u5434\u7ecf\u7406 <a href=\"tel:18301903156\">183-0190-3156<\/a> \u5fae\u4fe1\u540c\u53f7<\/h2>\n<p><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u65b0\u578bDBU\u5bf9\u78fa\u9178\u76d0\u884d\u751f\u7269\u7684\u5408\u6210\u65b9\u6cd5\u63a2\u8ba8 \u670b\u53cb\u4eec\uff0c\u4eca\u5929\u54b1\u4eec\u6765\u804a\u4e00\u4e2a\u542c\u8d77\u6765\u6709\u70b9\u201c\u5b66\u672f\u8303\u513f\u201d\uff0c\u5b9e\u5219\u975e\u5e38\u6709\u6599\u7684\u8bdd\u9898\u2014\u2014\u65b0\u578bDBU\u5bf9\u78fa\u9178\u76d0\u884d\u751f\u7269\u7684\u5408\u6210\u65b9\u6cd5\u3002\u522b\u88ab\u8fd9\u4e32\u62d7\u53e3\u7684\u540d\u5b57\u5413\u9000\u4e86\uff0c\u5176\u5b9e\u5b83\u80cc\u540e\u85cf\u7740\u8bb8\u591a\u6709\u8da3\u7684\u5316\u5b66\u53cd\u5e94\u3001\u5b9e\u7528\u7684\u5e94\u7528\u4ef7\u503c\uff0c\u4ee5\u53ca\u8ba9\u4eba\u62cd\u6848\u53eb\u7edd\u7684\u79d1\u7814\u667a\u6167\u3002 \u5982\u679c\u4f60\u662f\u5316\u5b66\u4e13\u4e1a\u7684\u5b66\u751f\u3001\u7814\u7a76\u751f\uff0c\u6216\u8005\u4ece\u4e8b\u836f\u7269\u7814\u53d1\u3001\u6750\u6599\u79d1\u5b66\u7684\u670b\u53cb\uff0c\u8fd9 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10141"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=10141"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10141\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=10141"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=10141"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=10141"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}