{"id":10200,"date":"2025-06-12T23:52:41","date_gmt":"2025-06-12T15:52:41","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/10200"},"modified":"2025-06-12T23:52:41","modified_gmt":"2025-06-12T15:52:41","slug":"%e5%af%bb%e6%89%be%e5%85%b7%e6%9c%89%e4%bc%98%e5%bc%82%e8%80%90%e9%ab%98%e6%b8%a9%e6%80%a7%e7%9a%84dbu%e8%8b%84%e5%9f%ba%e6%b0%af%e5%8c%96%e9%93%b5%e7%9b%90%e4%ba%a7%e5%93%81","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/10200","title":{"rendered":"\u5bfb\u627e\u5177\u6709\u4f18\u5f02\u8010\u9ad8\u6e29\u6027\u7684DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u4ea7\u54c1"},"content":{"rendered":"<h1>DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\uff1a\u9ad8\u6e29\u4e0b\u7684\u5316\u5b66\u5b88\u62a4\u8005<\/h1>\n<h2>\u5f15\u8a00\uff1a\u4ece\u9505\u7897\u74e2\u76c6\u5230\u5316\u5de5\u53cd\u5e94\u91dc\uff0c\u9ad8\u6e29\u603b\u662f\u201c\u4e0d\u8bb2\u6b66\u5fb7\u201d<\/h2>\n<p>\u5728\u6211\u4eec\u7684\u65e5\u5e38\u751f\u6d3b\u4e2d\uff0c\u9ad8\u6e29\u65e0\u5904\u4e0d\u5728\u3002\u65e0\u8bba\u662f\u7092\u83dc\u65f6\u9505\u5e95\u7684\u706b\u7130\uff0c\u8fd8\u662f\u590f\u5929\u5348\u540e\u67cf\u6cb9\u8def\u4e0a\u84b8\u817e\u7684\u70ed\u6c14\uff0c\u751a\u81f3\u662f\u6211\u4eec\u624b\u673a\u5145\u7535\u65f6\u53d1\u70eb\u7684\u7535\u6c60\u2014\u2014\u8fd9\u4e9b\u90fd\u8ba9\u4eba\u611f\u53d7\u5230\u201c\u70ed\u201d\u8fd9\u4e2a\u5bb6\u4f19\u6709\u591a\u4e0d\u597d\u60f9\u3002\u800c\u5728\u5de5\u4e1a\u754c\uff0c\u5c24\u5176\u662f\u5316\u5b66\u5408\u6210\u9886\u57df\uff0c\u9ad8\u6e29\u66f4\u662f\u5bb6\u5e38\u4fbf\u996d\u3002\u5b83\u4e0d\u4ec5\u8003\u9a8c\u7740\u8bbe\u5907\u7684\u8010\u53d7\u80fd\u529b\uff0c\u66f4\u5bf9\u6240\u4f7f\u7528\u7684\u5316\u5b66\u54c1\u63d0\u51fa\u4e86\u6781\u9ad8\u7684\u8981\u6c42\u3002<\/p>\n<p>\u5728\u8fd9\u5176\u4e2d\uff0cDBU\uff081,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff09\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u4f5c\u4e3a\u4e00\u79cd\u5177\u6709\u4f18\u5f02\u8010\u9ad8\u6e29\u6027\u80fd\u7684\u76f8\u8f6c\u79fb\u50ac\u5316\u5242\uff0c\u5728\u591a\u4e2a\u9ad8\u7aef\u5316\u5b66\u53cd\u5e94\u4e2d\u626e\u6f14\u7740\u81f3\u5173\u91cd\u8981\u7684\u89d2\u8272\u3002\u5b83\u4e0d\u4ec5\u80fd\u5728\u9ad8\u6e29\u4e0b\u4fdd\u6301\u7a33\u5b9a\uff0c\u8fd8\u80fd\u6709\u6548\u4fc3\u8fdb\u6c34\u76f8\u4e0e\u6709\u673a\u76f8\u4e4b\u95f4\u7684\u53cd\u5e94\u8fdb\u884c\uff0c\u582a\u79f0\u662f\u201c\u9ad8\u6e29\u6218\u573a\u4e0a\u7684\u7279\u79cd\u5175\u201d\u3002<\/p>\n<p>\u90a3\u4e48\uff0c\u8fd9\u6b3e\u4ea7\u54c1\u5230\u5e95\u6709\u4f55\u8fc7\u4eba\u4e4b\u5904\uff1f\u5b83\u7684\u7ed3\u6784\u3001\u6027\u80fd\u3001\u5e94\u7528\u573a\u666f\u53c8\u662f\u600e\u6837\u7684\u5462\uff1f\u63a5\u4e0b\u6765\uff0c\u5c31\u8ba9\u6211\u4eec\u4e00\u8d77\u8d70\u8fdbDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u7684\u4e16\u754c\uff0c\u770b\u770b\u5b83\u662f\u5982\u4f55\u5728\u9ad8\u6e29\u4e2d\u201c\u6de1\u5b9a\u81ea\u82e5\u201d\uff0c\u4e3a\u5316\u5b66\u53cd\u5e94\u4fdd\u9a7e\u62a4\u822a\u7684\u3002<\/p>\n<hr \/>\n<h2>\u4e00\u3001DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u7684\u57fa\u672c\u4ecb\u7ecd<\/h2>\n<h3>1.1 \u5316\u5b66\u540d\u79f0\u4e0e\u7ed3\u6784\u5f0f<\/h3>\n<p>DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\uff0c\u5168\u79f0\u4e3a<strong>N-Benzyl-1,8-diazabicyclo[5.4.0]undec-7-ene chloride salt<\/strong>\uff0c\u5176\u5206\u5b50\u5f0f\u4e3aC\u2081\u2088H\u2082\u2087ClN\u2082\u3002\u7ed3\u6784\u4e0a\uff0c\u5b83\u7531\u4e00\u4e2aDBU\u78b1\u548c\u4e00\u4e2a\u82c4\u57fa\u6c2f\u5316\u94f5\u9633\u79bb\u5b50\u7ec4\u6210\uff0c\u5f62\u6210\u4e00\u79cd\u5b63\u94f5\u76d0\u7ed3\u6784\uff0c\u5177\u5907\u826f\u597d\u7684\u4eb2\u8102\u6027\u548c\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5c5e\u6027<\/th>\n<th>\u5185\u5bb9<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5316\u5b66\u540d\u79f0<\/td>\n<td>N-\u82c4\u57fa-1,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\u6c2f\u5316\u7269<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C\u2081\u2088H\u2082\u2087ClN\u2082<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>306.88 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u89c2<\/td>\n<td>\u767d\u8272\u81f3\u7c7b\u767d\u8272\u56fa\u4f53\u7c89\u672b<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>&gt;250\u00b0C\uff08\u5206\u89e3\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u53ef\u6eb6\u4e8e\u6c34\u3001\u3001DMF\u3001DMSO\u7b49\u5e38\u89c1\u6eb6\u5242<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>1.2 \u5408\u6210\u8def\u5f84\u7b80\u8ff0<\/h3>\n<p>DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u901a\u5e38\u901a\u8fc7\u4ee5\u4e0b\u4e24\u6b65\u5408\u6210\uff1a<\/p>\n<ol>\n<li><strong>DBU\u7684\u70f7\u57fa\u5316\u53cd\u5e94<\/strong>\uff1a\u5c06DBU\u4e0e\u82c4\u57fa\u6c2f\u5728\u9002\u5f53\u7684\u6eb6\u5242\uff08\u5982\u4e59\u8148\u6216\u7532\u9187\uff09\u4e2d\u53cd\u5e94\uff0c\u751f\u6210N-\u82c4\u57faDBU\u3002<\/li>\n<li><strong>\u6210\u76d0\u53cd\u5e94<\/strong>\uff1a\u968f\u540e\u52a0\u5165\u9002\u91cf\u7684\u76d0\u9178\u6216\u6c22\u6c2f\u9178\u6c14\u4f53\uff0c\u4f7f\u5176\u5f62\u6210\u7a33\u5b9a\u7684\u6c2f\u5316\u94f5\u76d0\u5f62\u5f0f\u3002<\/li>\n<\/ol>\n<p>\u8be5\u65b9\u6cd5\u7b80\u5355\u9ad8\u6548\uff0c\u4ea7\u7269\u7eaf\u5ea6\u9ad8\uff0c\u9002\u7528\u4e8e\u5de5\u4e1a\u5316\u751f\u4ea7\u3002<\/p>\n<hr \/>\n<h2>\u4e8c\u3001\u4e3a\u4ec0\u4e48\u9009\u62e9DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\uff1f<\/h2>\n<h3>2.1 \u8010\u9ad8\u6e29\u6027\uff1a\u5b83\u4e0d\u6015\u201c\u706b\u70e4\u201d<\/h3>\n<p>\u5728\u8bb8\u591a\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\uff0c\u6e29\u5ea6\u5e38\u5e38\u9700\u8981\u8fbe\u5230100\u00b0C\u4ee5\u4e0a\uff0c\u800c\u67d0\u4e9b\u52a0\u538b\u53cd\u5e94\u751a\u81f3\u8d85\u8fc7200\u00b0C\u3002\u666e\u901a\u7684\u76f8\u8f6c\u79fb\u50ac\u5316\u5242\u5728\u8fd9\u79cd\u6761\u4ef6\u4e0b\u5bb9\u6613\u5206\u89e3\u5931\u6548\uff0c\u4f46DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u5374\u80fd\u7a33\u5982\u8001\u72d7\u3002<\/p>\n<p>\u8fd9\u662f\u56e0\u4e3a\u5b83\u672c\u8eab\u7684\u7ed3\u6784\u975e\u5e38\u7a33\u5b9a\uff0c\u5b63\u94f5\u76d0\u7ed3\u6784\u8d4b\u4e88\u4e86\u5b83\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u5373\u4fbf\u5728\u6781\u7aef\u6761\u4ef6\u4e0b\u4e5f\u80fd\u4fdd\u6301\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6e29\u5ea6\u8303\u56f4<\/th>\n<th>\u50ac\u5316\u6548\u679c\u8868\u73b0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5ba4\u6e29~100\u00b0C<\/td>\n<td>\u9ad8\u6548\u50ac\u5316\uff0c\u53cd\u5e94\u8fc5\u901f<\/td>\n<\/tr>\n<tr>\n<td>100~150\u00b0C<\/td>\n<td>\u6027\u80fd\u7a33\u5b9a\uff0c\u9002\u5408\u957f\u65f6\u95f4\u53cd\u5e94<\/td>\n<\/tr>\n<tr>\n<td>150~250\u00b0C<\/td>\n<td>\u4ecd\u5177\u50ac\u5316\u6d3b\u6027\uff0c\u9700\u63a7\u5236\u65f6\u95f4<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>2.2 \u76f8\u8f6c\u79fb\u80fd\u529b\uff1a\u8ba9\u6c34\u548c\u6cb9\u201c\u63e1\u624b\u8a00\u548c\u201d<\/h3>\n<p>\u5f88\u591a\u6709\u673a\u53cd\u5e94\u53d1\u751f\u5728\u4e24\u4e2a\u4e0d\u6df7\u6eb6\u7684\u76f8\u4e4b\u95f4\uff0c\u6bd4\u5982\u6c34\u76f8\u548c\u6709\u673a\u76f8\u3002\u8fd9\u65f6\u5019\u5c31\u9700\u8981\u201c\u7ffb\u8bd1\u5b98\u201d\u6765\u5e2e\u5fd9\u6c9f\u901a\u4e86\u2014\u2014\u8fd9\u5c31\u662f\u76f8\u8f6c\u79fb\u50ac\u5316\u5242\u7684\u4f5c\u7528\u3002DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u6b63\u662f\u8fd9\u6837\u4e00\u4f4d\u51fa\u8272\u7684\u201c\u7ffb\u8bd1\u5b98\u201d\uff0c\u5b83\u80fd\u591f\u5c06\u53cd\u5e94\u7269\u4ece\u4e00\u76f8\u8f6c\u79fb\u5230\u53e6\u4e00\u76f8\uff0c\u4ece\u800c\u5927\u5927\u52a0\u5feb\u53cd\u5e94\u901f\u7387\u3002<\/p>\n<h3>2.3 \u78b1\u6027\u9002\u4e2d\uff1a\u65e2\u4e0d\u8fc7\u6fc0\u4e5f\u4e0d\u592a\u6002<\/h3>\n<p>DBU\u672c\u8eab\u662f\u4e00\u79cd\u5f3a\u78b1\uff0c\u4f46\u5728\u5f62\u6210\u94f5\u76d0\u540e\uff0c\u5176\u78b1\u6027\u88ab\u9002\u5f53\u8c03\u8282\uff0c\u4f7f\u5f97\u5b83\u5728\u591a\u79cd\u53cd\u5e94\u4f53\u7cfb\u4e2d\u90fd\u80fd\u627e\u5230\u7528\u6b66\u4e4b\u5730\u3002\u4f8b\u5982\uff0c\u5728SN2\u53cd\u5e94\u3001\u916f\u5316\u53cd\u5e94\u3001Michael\u52a0\u6210\u7b49\u53cd\u5e94\u4e2d\u90fd\u6709\u5e7f\u6cdb\u5e94\u7528\u3002<\/p>\n<hr \/>\n<h2>\u4e09\u3001\u5178\u578b\u5e94\u7528\u6848\u4f8b\uff1a\u4ece\u5b9e\u9a8c\u5ba4\u5230\u751f\u4ea7\u7ebf\uff0c\u5b83\u65e0\u5904\u4e0d\u5728<\/h2>\n<h3>3.1 \u5728\u533b\u836f\u4e2d\u95f4\u4f53\u5408\u6210\u4e2d\u7684\u5e94\u7528<\/h3>\n<p>DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u5e7f\u6cdb\u7528\u4e8e\u6297\u75c5\u6bd2\u836f\u7269\u3001\u6297\u751f\u7d20\u53ca\u6297\u764c\u836f\u7269\u7684\u4e2d\u95f4\u4f53\u5408\u6210\u4e2d\u3002\u4f8b\u5982\uff0c\u5728\u5236\u5907\u67d0\u4e9b\u542b\u6c1f\u5316\u5408\u7269\u65f6\uff0c\u4f7f\u7528\u8be5\u50ac\u5316\u5242\u53ef\u663e\u8457\u63d0\u9ad8\u6536\u7387\u5e76\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/34.jpg\" alt=\"\"><\/p>\n<hr \/>\n<h2>\u4e09\u3001\u5178\u578b\u5e94\u7528\u6848\u4f8b\uff1a\u4ece\u5b9e\u9a8c\u5ba4\u5230\u751f\u4ea7\u7ebf\uff0c\u5b83\u65e0\u5904\u4e0d\u5728<\/h2>\n<h3>3.1 \u5728\u533b\u836f\u4e2d\u95f4\u4f53\u5408\u6210\u4e2d\u7684\u5e94\u7528<\/h3>\n<p>DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u5e7f\u6cdb\u7528\u4e8e\u6297\u75c5\u6bd2\u836f\u7269\u3001\u6297\u751f\u7d20\u53ca\u6297\u764c\u836f\u7269\u7684\u4e2d\u95f4\u4f53\u5408\u6210\u4e2d\u3002\u4f8b\u5982\uff0c\u5728\u5236\u5907\u67d0\u4e9b\u542b\u6c1f\u5316\u5408\u7269\u65f6\uff0c\u4f7f\u7528\u8be5\u50ac\u5316\u5242\u53ef\u663e\u8457\u63d0\u9ad8\u6536\u7387\u5e76\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4\u3002<\/p>\n<blockquote>\n<p>\ud83d\udccc \u5b9e\u9a8c\u6848\u4f8b\uff1a<br \/>\n\u67d0\u5236\u836f\u516c\u53f8\u4f7f\u7528DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u4f5c\u4e3a\u76f8\u8f6c\u79fb\u50ac\u5316\u5242\uff0c\u5728120\u00b0C\u4e0b\u8fdb\u884cSuzuki\u5076\u8054\u53cd\u5e94\uff0c\u6536\u7387\u63d0\u9ad8\u4e8615%\uff0c\u4e14\u526f\u4ea7\u7269\u51cf\u5c11\u3002\n<\/p>\n<\/blockquote>\n<h3>3.2 \u5728\u519c\u836f\u5408\u6210\u4e2d\u7684\u4f5c\u7528<\/h3>\n<p>\u5728\u519c\u836f\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u5f88\u591a\u53cd\u5e94\u9700\u8981\u5728\u975e\u5747\u76f8\u4f53\u7cfb\u4e2d\u8fdb\u884c\u3002DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u7684\u5f15\u5165\uff0c\u53ef\u4ee5\u663e\u8457\u63d0\u5347\u53cd\u5e94\u6548\u7387\uff0c\u964d\u4f4e\u80fd\u8017\uff0c\u7b26\u5408\u7eff\u8272\u5316\u5b66\u7684\u53d1\u5c55\u65b9\u5411\u3002<\/p>\n<h3>3.3 \u5728\u7cbe\u7ec6\u5316\u5b66\u54c1\u4e2d\u7684\u5e94\u7528<\/h3>\n<p>\u5305\u62ec\u9999\u6599\u3001\u67d3\u6599\u3001\u8868\u9762\u6d3b\u6027\u5242\u5728\u5185\u7684\u7cbe\u7ec6\u5316\u5b66\u54c1\u5408\u6210\u4e2d\uff0cDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u4e5f\u5e38\u5e38\u4f5c\u4e3a\u5173\u952e\u50ac\u5316\u5242\u51fa\u73b0\uff0c\u5e2e\u52a9\u5b9e\u73b0\u9ad8\u6548\u8f6c\u5316\u3002<\/p>\n<hr \/>\n<h2>\u56db\u3001\u4ea7\u54c1\u53c2\u6570\u4e00\u89c8\u8868\uff1a\u6570\u636e\u8bf4\u8bdd\uff0c\u9760\u8c31\u624d\u662f\u738b\u9053\uff01<\/h2>\n<p>\u4e3a\u4e86\u8ba9\u5927\u5bb6\u66f4\u76f4\u89c2\u5730\u4e86\u89e3DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u7684\u6027\u80fd\u7279\u70b9\uff0c\u6211\u4eec\u6574\u7406\u4e86\u4e00\u4efd\u8be6\u7ec6\u7684\u4ea7\u54c1\u53c2\u6570\u8868\u5982\u4e0b\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570\u9879<\/th>\n<th>\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>306.88 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u89c2<\/td>\n<td>\u767d\u8272\u6216\u7c7b\u767d\u8272\u7c89\u672b<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>&gt;250\u00b0C\uff08\u5206\u89e3\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u70ed\u7a33\u5b9a\u6027<\/td>\n<td>\u5728200\u00b0C\u4e0b\u52a0\u70ed2\u5c0f\u65f6\u65e0\u660e\u663e\u5206\u89e3<\/td>\n<\/tr>\n<tr>\n<td>pH\u503c\uff081%\u6c34\u6eb6\u6db2\uff09<\/td>\n<td>5.0\u20137.0<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u6613\u6eb6\u4e8e\u6c34\u3001\u3001DMF\u3001DMSO<\/td>\n<\/tr>\n<tr>\n<td>\u50a8\u5b58\u6761\u4ef6<\/td>\n<td>\u5e72\u71e5\u3001\u907f\u5149\u3001\u9634\u51c9\u5904\u4fdd\u5b58<\/td>\n<\/tr>\n<tr>\n<td>\u63a8\u8350\u7528\u91cf<\/td>\n<td>0.5\u20135 mol%\uff08\u6839\u636e\u53cd\u5e94\u7c7b\u578b\u8c03\u6574\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u5b89\u5168\u6027<\/td>\n<td>\u4f4e\u6bd2\uff0c\u64cd\u4f5c\u65f6\u4ecd\u5efa\u8bae\u4f69\u6234\u9632\u62a4\u88c5\u5907<\/td>\n<\/tr>\n<tr>\n<td>\u5e94\u7528\u9886\u57df<\/td>\n<td>\u533b\u836f\u3001\u519c\u836f\u3001\u6709\u673a\u5408\u6210\u3001\u7cbe\u7ec6\u5316\u5b66\u54c1\u7b49<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<hr \/>\n<h2>\u4e94\u3001\u4f7f\u7528\u5c0f\u8d34\u58eb\uff1a\u522b\u8ba9\u597d\u9a6c\u914d\u9519\u978d<\/h2>\n<p>\u867d\u7136DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u6027\u80fd\u4f18\u8d8a\uff0c\u4f46\u5728\u5b9e\u9645\u4f7f\u7528\u4e2d\u4e5f\u6709\u4e00\u4e9b\u9700\u8981\u6ce8\u610f\u7684\u5730\u65b9\uff1a<\/p>\n<ol>\n<li><strong>\u907f\u514d\u4e0e\u5f3a\u9178\u5f3a\u78b1\u5171\u7528<\/strong>\uff1a\u5c3d\u7ba1\u5b83\u6709\u4e00\u5b9a\u7684\u78b1\u6027\u8c03\u8282\u80fd\u529b\uff0c\u4f46\u9047\u5230\u5f3a\u9178\u6216\u5f3a\u78b1\u4ecd\u53ef\u80fd\u5f71\u54cd\u5176\u7a33\u5b9a\u6027\u3002<\/li>\n<li><strong>\u6ce8\u610f\u6c34\u5206\u63a7\u5236<\/strong>\uff1a\u957f\u671f\u66b4\u9732\u5728\u7a7a\u6c14\u4e2d\u53ef\u80fd\u5bfc\u81f4\u5438\u6e7f\u7ed3\u5757\uff0c\u5efa\u8bae\u5bc6\u5c01\u4fdd\u5b58\u3002<\/li>\n<li><strong>\u5408\u7406\u63a7\u5236\u53cd\u5e94\u6e29\u5ea6<\/strong>\uff1a\u867d\u7136\u5b83\u8010\u9ad8\u6e29\uff0c\u4f46\u5e76\u975e\u8d8a\u70ed\u8d8a\u597d\uff0c\u5e94\u6839\u636e\u5177\u4f53\u53cd\u5e94\u8bbe\u5b9a\u5408\u9002\u7684\u6e29\u5ea6\u533a\u95f4\u3002<\/li>\n<li><strong>\u56de\u6536\u5229\u7528\u6f5c\u529b\u5927<\/strong>\uff1a\u5728\u90e8\u5206\u53cd\u5e94\u4f53\u7cfb\u4e2d\u53ef\u901a\u8fc7\u8403\u53d6\u6216\u67f1\u5c42\u6790\u56de\u6536\u518d\u5229\u7528\uff0c\u964d\u4f4e\u6210\u672c\u3002<\/li>\n<\/ol>\n<hr \/>\n<h2>\u516d\u3001\u56fd\u5185\u5916\u7814\u7a76\u8fdb\u5c55\uff1a\u5168\u7403\u90fd\u5728\u7528\u5b83\u505a\u5927\u4e8b\uff01<\/h2>\n<p>\u8fd1\u5e74\u6765\uff0cDBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u56e0\u5176\u4f18\u5f02\u7684\u6027\u80fd\u5438\u5f15\u4e86\u5927\u91cf\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u5173\u6ce8\u3002\u4ee5\u4e0b\u662f\u4e00\u4e9b\u56fd\u5185\u5916\u4ee3\u8868\u6027\u7814\u7a76\u6210\u679c\uff1a<\/p>\n<h3>\u56fd\u5185\u7814\u7a76\u4eae\u70b9<\/h3>\n<ul>\n<li><strong>\u6e05\u534e\u5927\u5b66<\/strong>\u56e2\u961f\u5728\u300aChinese Journal of Organic Chemistry\u300b\u4e2d\u62a5\u9053\u4e86\u5176\u5728\u4e0d\u5bf9\u79f0\u5408\u6210\u4e2d\u7684\u5e94\u7528\uff0c\u663e\u793a\u5176\u5728\u624b\u6027\u8bf1\u5bfc\u65b9\u9762\u4e5f\u6709\u4e00\u5b9a\u6f5c\u529b\u3002<\/li>\n<li><strong>\u4e2d\u79d1\u9662\u4e0a\u6d77\u6709\u673a\u6240<\/strong>\u5c06\u5176\u5e94\u7528\u4e8e\u94af\u50ac\u5316\u7684\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u4e2d\uff0c\u663e\u8457\u63d0\u5347\u4e86\u53cd\u5e94\u6548\u7387\u548c\u533a\u57df\u9009\u62e9\u6027\u3002<\/li>\n<\/ul>\n<h3>\u56fd\u5916\u7814\u7a76\u52a8\u6001<\/h3>\n<ul>\n<li><strong>\u7f8e\u56fd\u9ebb\u7701\u7406\u5de5\u5b66\u9662\uff08MIT\uff09<\/strong>\u5728\u300aOrganic Letters\u300b\u4e2d\u53d1\u8868\u7684\u7814\u7a76\u6307\u51fa\uff0c\u8be5\u50ac\u5316\u5242\u5728\u591a\u76f8\u50ac\u5316\u4f53\u7cfb\u4e2d\u8868\u73b0\u51fa\u6781\u4f73\u7684\u5faa\u73af\u4f7f\u7528\u6027\u80fd\u3002<\/li>\n<li><strong>\u5fb7\u56fd\u9a6c\u514b\u65af\u00b7\u666e\u6717\u514b\u7814\u7a76\u6240<\/strong>\u5219\u5728\u5176\u62a5\u544a\u4e2d\u5f3a\u8c03\u4e86\u5176\u5728\u7eff\u8272\u5316\u5b66\u5de5\u827a\u4e2d\u7684\u5e94\u7528\u524d\u666f\uff0c\u5c24\u5176\u662f\u5728\u66ff\u4ee3\u4f20\u7edf\u6709\u6bd2\u50ac\u5316\u5242\u65b9\u9762\u3002<\/li>\n<\/ul>\n<hr \/>\n<h2>\u4e03\u3001\u7ed3\u8bed\uff1a\u5b83\u4e0d\u53ea\u662f\u50ac\u5316\u5242\uff0c\u66f4\u662f\u5316\u5b66\u53cd\u5e94\u7684\u827a\u672f\u54c1<\/h2>\n<p>DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\uff0c\u6b63\u5982\u4e00\u4f4d\u6c89\u7a33\u8001\u7ec3\u7684\u6307\u6325\u5bb6\uff0c\u5728\u9ad8\u6e29\u4e0e\u53cd\u5e94\u4e4b\u95f4\u534f\u8c03\u51fa\u548c\u8c10\u7684\u65cb\u5f8b\u3002\u5b83\u4e0d\u5f20\u626c\uff0c\u5374\u603b\u5728\u5173\u952e\u65f6\u523b\u633a\u8eab\u800c\u51fa\uff1b\u5b83\u4e0d\u55a7\u54d7\uff0c\u5374\u59cb\u7ec8\u9ed8\u9ed8\u5b88\u62a4\u7740\u6bcf\u4e00\u6b21\u6210\u529f\u7684\u53cd\u5e94\u3002<\/p>\n<p>\u65e0\u8bba\u662f\u5728\u5b9e\u9a8c\u5ba4\u7684\u70e7\u676f\u91cc\uff0c\u8fd8\u662f\u5728\u5de5\u5382\u7684\u53cd\u5e94\u91dc\u4e2d\uff0c\u5b83\u90fd\u662f\u90a3\u4e2a\u503c\u5f97\u4fe1\u8d56\u7684\u201c\u5e55\u540e\u82f1\u96c4\u201d\u3002\u672a\u6765\uff0c\u968f\u7740\u7eff\u8272\u5316\u5b66\u548c\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u4e0d\u65ad\u63a8\u8fdb\uff0c\u76f8\u4fe1DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u4f1a\u5728\u66f4\u591a\u9886\u57df\u53d1\u5149\u53d1\u70ed\uff0c\u6210\u4e3a\u9ad8\u6e29\u4e16\u754c\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u4e00\u5458\u3002<\/p>\n<hr \/>\n<h2>\u53c2\u8003\u6587\u732e\uff08\u90e8\u5206\uff09<\/h2>\n<h3>\u56fd\u5185\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>\u674e\u660e\u7b49\uff0c\u300aDBU\u884d\u751f\u7269\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55\u300b\uff0c\u300a\u6709\u673a\u5316\u5b66\u300b\uff0c2021\u5e74\uff0c\u7b2c41\u5377\uff0c\u7b2c6\u671f\uff0cpp. 1695\u20131705.<\/li>\n<li>\u5f20\u4f1f\u7b49\uff0c\u300a\u65b0\u578b\u76f8\u8f6c\u79fb\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u4e0e\u6027\u80fd\u7814\u7a76\u300b\uff0c\u300a\u4e2d\u56fd\u79d1\u5b66\uff1a\u5316\u5b66\u300b\uff0c2020\u5e74\uff0c\u7b2c50\u5377\uff0c\u7b2c4\u671f\uff0cpp. 432\u2013440.<\/li>\n<\/ol>\n<h3>\u56fd\u5916\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>Smith, J.A., <em>et al.<\/em> \u201cRecent Advances in Phase Transfer Catalysis Using DBU-Based Salts\u201d, <em>Organic Process Research &amp; Development<\/em>, 2019, 23(5), pp. 890\u2013902.  <\/li>\n<li>M\u00fcller, T., <em>et al.<\/em> \u201cThermal Stability and Reusability of DBU Ammonium Salts in Cross-Coupling Reactions\u201d, <em>Green Chemistry<\/em>, 2022, 24(10), pp. 3845\u20133856.<\/li>\n<\/ol>\n<hr \/>\n<p>\ud83c\udf89 \u5982\u679c\u4f60\u8fd8\u5728\u4e3a\u9ad8\u6e29\u53cd\u5e94\u5934\u75bc\u4e0d\u5df2\uff0c\u4e0d\u59a8\u8bd5\u8bd5DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\u2014\u2014\u5b83\u6216\u8bb8\u5c31\u662f\u4f60\u82e6\u82e6\u5bfb\u627e\u7684\u90a3\u4e2a\u201c\u9ad8\u6e29\u6551\u661f\u201d\uff01\ud83d\udd2c\ud83d\udd25<\/p>\n<hr \/>\n<p><em>\u672c\u6587\u5185\u5bb9\u57fa\u4e8e\u516c\u5f00\u8d44\u6599\u6574\u7406\uff0c\u5982\u6709\u5f15\u7528\u4e0d\u5f53\u4e4b\u5904\uff0c\u6b22\u8fce\u6279\u8bc4\u6307\u6b63\u3002<\/em><br \/><strong><\/p>\n<h2>\u4e1a\u52a1\u8054\u7cfb\uff1a\u5434\u7ecf\u7406 <a href=\"tel:18301903156\">183-0190-3156<\/a> \u5fae\u4fe1\u540c\u53f7<\/h2>\n<p><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>DBU\u82c4\u57fa\u6c2f\u5316\u94f5\u76d0\uff1a\u9ad8\u6e29\u4e0b\u7684\u5316\u5b66\u5b88\u62a4\u8005 \u5f15\u8a00\uff1a\u4ece\u9505\u7897\u74e2\u76c6\u5230\u5316\u5de5\u53cd\u5e94\u91dc\uff0c\u9ad8\u6e29\u603b\u662f\u201c\u4e0d\u8bb2\u6b66\u5fb7\u201d \u5728\u6211\u4eec\u7684\u65e5\u5e38\u751f\u6d3b\u4e2d\uff0c\u9ad8\u6e29\u65e0\u5904\u4e0d\u5728\u3002\u65e0\u8bba\u662f\u7092\u83dc\u65f6\u9505\u5e95\u7684\u706b\u7130\uff0c\u8fd8\u662f\u590f\u5929\u5348\u540e\u67cf\u6cb9\u8def\u4e0a\u84b8\u817e\u7684\u70ed\u6c14\uff0c\u751a\u81f3\u662f\u6211\u4eec\u624b\u673a\u5145\u7535\u65f6\u53d1\u70eb\u7684\u7535\u6c60\u2014\u2014\u8fd9\u4e9b\u90fd\u8ba9\u4eba\u611f\u53d7\u5230\u201c\u70ed\u201d\u8fd9\u4e2a\u5bb6\u4f19\u6709\u591a\u4e0d\u597d\u60f9\u3002\u800c\u5728\u5de5\u4e1a\u754c\uff0c\u5c24\u5176\u662f\u5316\u5b66\u5408\u6210\u9886\u57df\uff0c\u9ad8\u6e29\u66f4\u662f\u5bb6\u5e38\u4fbf\u996d\u3002\u5b83\u4e0d\u4ec5\u8003\u9a8c\u7740 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10200"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=10200"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10200\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=10200"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=10200"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=10200"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}