{"id":11144,"date":"2025-06-25T21:35:10","date_gmt":"2025-06-25T13:35:10","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/11144"},"modified":"2025-06-25T21:35:10","modified_gmt":"2025-06-25T13:35:10","slug":"%e5%88%86%e6%9e%90%e6%9c%89%e6%9c%ba%e9%94%8c%e5%82%ac%e5%8c%96%e5%89%82%e5%af%b9%e5%8f%8d%e5%ba%94%e6%b4%bb%e6%80%a7%e5%92%8c%e5%82%a8%e5%ad%98%e7%a8%b3%e5%ae%9a%e6%80%a7%e7%9a%84%e5%b9%b3%e8%a1%a1","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/11144","title":{"rendered":"\u5206\u6790\u6709\u673a\u950c\u50ac\u5316\u5242\u5bf9\u53cd\u5e94\u6d3b\u6027\u548c\u50a8\u5b58\u7a33\u5b9a\u6027\u7684\u5e73\u8861"},"content":{"rendered":"

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\n

\u4e00\u3001\u6709\u673a\u950c\u50ac\u5316\u5242\u7684\u57fa\u672c\u4ecb\u7ecd<\/h2>\n

\u6709\u673a\u950c\u5316\u5408\u7269\u65e9\u88ab\u7528\u4e8e\u6709\u673a\u5408\u6210\u662f\u572820\u4e16\u7eaa\u521d\uff0c\u7279\u522b\u662f1930\u5e74\u4ee3\u7531\u5fb7\u56fd\u5316\u5b66\u5bb6Heinrich Otto Wieland\u7b49\u4eba\u63a8\u52a8\u7684\u7814\u7a76\u5960\u5b9a\u4e86\u5176\u57fa\u7840\u3002\u8fd9\u7c7b\u5316\u5408\u7269\u901a\u5e38\u5177\u6709\u901a\u5f0fR-Zn-X\uff08R\u4e3a\u6709\u673a\u57fa\u56e2\uff0cX\u4e3a\u5364\u7d20\u6216\u7c7b\u5364\u7d20\uff09\uff0c\u4f8b\u5982\u5e38\u89c1\u7684PhZnCl\u3001EtZnBr\u7b49\u3002<\/p>\n

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    \n
  • Reformatsky\u53cd\u5e94<\/strong>\uff1a\u919b\/\u916e\u4e0e\u03b1-\u5364\u4ee3\u916f\u5728\u950c\u5b58\u5728\u4e0b\u751f\u6210\u03b2-\u7f9f\u57fa\u916f\uff1b<\/li>\n
  • Negishi\u5076\u8054\u53cd\u5e94<\/strong>\uff1a\u950c\u8bd5\u5242\u4e0e\u94af\u50ac\u5316\u5242\u534f\u540c\u4f5c\u7528\u5b9e\u73b0\u82b3\u57fa-\u70f7\u57fa\u5076\u8054\uff1b<\/li>\n
  • \u7fb0\u57fa\u52a0\u6210\u53cd\u5e94<\/strong>\uff1a\u5982\u4e0e\u919b\u3001\u916e\u3001\u4e9a\u80fa\u7b49\u7684\u52a0\u6210\uff1b<\/li>\n
  • \u81ea\u7531\u57fa\u53cd\u5e94\u4e2d\u7684\u8fd8\u539f\u5242\u6216\u5f15\u53d1\u5242<\/strong>\u3002<\/li>\n<\/ul>\n

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    \n

    \u4e8c\u3001\u53cd\u5e94\u6d3b\u6027\uff1a\u6709\u673a\u950c\u7684\u201c\u7206\u53d1\u529b\u201d<\/h2>\n

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    1. \u4eb2\u6838\u6027\u5f3a\u4f46\u53ef\u63a7<\/h3>\n

    \u6709\u673a\u950c\u8bd5\u5242\u7684\u4eb2\u6838\u6027\u4ecb\u4e8e\u683c\u6c0f\u8bd5\u5242\u548c\u6709\u673a\u94dc\u4e4b\u95f4\uff0c\u5c5e\u4e8e\u201c\u4e2d\u95f4\u6d3e\u201d\u3002\u8fd9\u79cd\u7279\u6027\u8ba9\u5b83\u65e2\u80fd\u6709\u6548\u8fdb\u653b\u7f3a\u7535\u5b50\u7684\u78b3\u539f\u5b50\uff08\u5982\u7fb0\u57fa\u78b3\uff09\uff0c\u53c8\u4e0d\u81f3\u4e8e\u50cf\u6709\u673a\u9502\u90a3\u6837\u8fc7\u4e8e\u6d3b\u6cfc\u800c\u5f15\u53d1\u526f\u53cd\u5e94\u3002<\/p>\n\n\n\n\n\n\n\n
    \u8bd5\u5242\u7c7b\u578b<\/th>\n\u4eb2\u6838\u6027\u5f3a\u5ea6<\/th>\n\u53cd\u5e94\u6d3b\u6027<\/th>\n\u64cd\u4f5c\u5b89\u5168\u6027<\/th>\n<\/tr>\n<\/thead>\n
    \u683c\u6c0f\u8bd5\u5242\uff08RMgX\uff09<\/td>\n\u5f3a<\/td>\n\u9ad8<\/td>\n\u4e2d\u7b49<\/td>\n<\/tr>\n
    \u6709\u673a\u9502\uff08RLi\uff09<\/td>\n\u6781\u5f3a<\/td>\n\u6781\u9ad8<\/td>\n\u4f4e<\/td>\n<\/tr>\n
    \u6709\u673a\u950c\uff08RZnX\uff09<\/td>\n\u4e2d\u7b49<\/td>\n\u4e2d\u7b49\u504f\u9ad8<\/td>\n\u9ad8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

    2. \u4e0e\u8fc7\u6e21\u91d1\u5c5e\u534f\u540c\u6548\u5e94\u597d<\/h3>\n

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    3. \u5bbd\u6cdb\u7684\u5e95\u7269\u9002\u7528\u6027<\/h3>\n

    \u65e0\u8bba\u662f\u82b3\u9999\u65cf\u8fd8\u662f\u8102\u80aa\u65cf\u7ed3\u6784\uff0c\u6709\u673a\u950c\u90fd\u80fd\u5728\u4e0d\u540c\u6eb6\u5242\u4f53\u7cfb\u4e2d\u7a33\u5b9a\u5b58\u5728\uff0c\u5e76\u53c2\u4e0e\u591a\u79cd\u7c7b\u578b\u7684\u53cd\u5e94\u3002\u4f8b\u5982\uff1a<\/p>\n

      \n
    • \u82ef\u4e59\u57fa\u950c\u53ef\u7528\u4e8e\u82b3\u9999\u919b\u7684\u52a0\u6210\uff1b<\/li>\n
    • \u70ef\u4e19\u57fa\u950c\u53ef\u7528\u4e8e\u73af\u6c27\u5316\u5408\u7269\u7684\u5f00\u73af\uff1b<\/li>\n
    • \u7094\u57fa\u950c\u5219\u53ef\u7528\u4e8eSonogashira-type\u53cd\u5e94\u7684\u53d8\u4f53\u3002<\/li>\n<\/ul>\n
      \n

      \u4e09\u3001\u50a8\u5b58\u7a33\u5b9a\u6027\uff1a\u6709\u673a\u950c\u7684\u201c\u957f\u5bff\u79d8\u8bc0\u201d<\/h2>\n

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      1. \u5bf9\u7a7a\u6c14\u548c\u6c34\u5206\u76f8\u5bf9\u7a33\u5b9a<\/h3>\n

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      \u8bd5\u5242\u7c7b\u578b<\/th>\n\u5bf9\u7a7a\u6c14\u7a33\u5b9a\u6027<\/th>\n\u5bf9\u6c34\u7a33\u5b9a\u6027<\/th>\n\u63a8\u8350\u4fdd\u5b58\u6761\u4ef6<\/th>\n<\/tr>\n<\/thead>\n
      \u683c\u6c0f\u8bd5\u5242<\/td>\n\u5dee<\/td>\n\u6781\u5dee<\/td>\n\u4e25\u683c\u60f0\u6027\u6c14\u4f53\u4fdd\u62a4<\/td>\n<\/tr>\n
      \u6709\u673a\u9502<\/td>\n\u5dee<\/td>\n\u6781\u5dee<\/td>\n\u51b7\u51bb\u907f\u5149\u5bc6\u5c01<\/td>\n<\/tr>\n
      \u6709\u673a\u950c<\/td>\n\u4e2d\u7b49<\/td>\n\u4e2d\u7b49\u504f\u4e0a<\/td>\n\u5e72\u71e5\u9634\u51c9\u5904\u5bc6\u5c01<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

      2. \u5206\u5b50\u7ed3\u6784\u5f71\u54cd\u50a8\u5b58\u5bff\u547d<\/h3>\n

      \u4e0d\u540c\u7684\u6709\u673a\u950c\u8bd5\u5242\u7531\u4e8e\u914d\u4f53\u7ed3\u6784\u4e0d\u540c\uff0c\u5176\u7a33\u5b9a\u6027\u4e5f\u6709\u5dee\u5f02\u3002\u4e00\u822c\u6765\u8bf4\uff0c\u5e26\u6709\u4f4d\u963b\u8f83\u5927\u7684\u53d6\u4ee3\u57fa\uff08\u5982\u53d4\u4e01\u57fa\uff09\u6216\u542b\u6742\u539f\u5b50\u914d\u4f53\uff08\u5982\u5421\u5576\u3001\u81a6\uff09\u7684\u950c\u8bd5\u5242\u4f1a\u66f4\u52a0\u7a33\u5b9a\u3002<\/p>\n\n\n\n\n\n\n\n\n
      \u5316\u5408\u7269\u540d\u79f0<\/th>\n\u7ed3\u6784\u7279\u5f81<\/th>\n\u50a8\u5b58\u7a33\u5b9a\u6027<\/th>\n\u63a8\u8350\u6e29\u5ea6<\/th>\n<\/tr>\n<\/thead>\n
      PhZnCl<\/td>\n\u82b3\u9999\u57fa\u950c\u76d0<\/td>\n\u4e2d\u7b49<\/td>\n-20\u00b0C<\/td>\n<\/tr>\n
      EtZnBr<\/td>\n\u76f4\u94fe\u70f7\u57fa\u950c<\/td>\n\u8f83\u5f31<\/td>\n\u51b7\u85cf<\/td>\n<\/tr>\n
      (t-Bu)ZnI<\/td>\n\u53d4\u4e01\u57fa\u950c\u7898\u5316\u7269<\/td>\n\u9ad8<\/td>\n\u5e38\u6e29<\/td>\n<\/tr>\n
      Zn(Ph)(py)<\/td>\n\u5421\u5576\u914d\u4f4d\u950c\u8bd5\u5242<\/td>\n\u9ad8<\/td>\n\u5e38\u6e29<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

      3. \u6dfb\u52a0\u7a33\u5b9a\u5242\u53ef\u5ef6\u957f\u5bff\u547d<\/h3>\n

      \u4e00\u4e9b\u5546\u4e1a\u5316\u7684\u6709\u673a\u950c\u4ea7\u54c1\u4f1a\u52a0\u5165\u5c11\u91cf\u7684\u7a33\u5b9a\u5242\uff08\u5982BHT\u3001THF\u7edc\u5408\u7269\uff09\uff0c\u4ee5\u5ef6\u7f13\u5176\u6c27\u5316\u548c\u5206\u89e3\u3002\u6b64\u5916\uff0c\u4f7f\u7528\u975e\u8d28\u5b50\u6eb6\u5242\uff08\u5982DMF\u3001DMSO\u3001THF\uff09\u4f5c\u4e3a\u50a8\u5b58\u4ecb\u8d28\u4e5f\u6709\u52a9\u4e8e\u63d0\u9ad8\u7a33\u5b9a\u6027\u3002<\/p>\n

      \n

      \u56db\u3001\u5982\u4f55\u5728\u6d3b\u6027\u4e0e\u7a33\u5b9a\u6027\u4e4b\u95f4\u627e\u5230\u5e73\u8861\u70b9\uff1f<\/h2>\n

      \u8fd9\u4e2a\u95ee\u9898\u5176\u5b9e\u6709\u70b9\u50cf\u8c08\u604b\u7231\u2014\u2014\u592a\u70ed\u60c5\u4f1a\u5413\u8dd1\u5bf9\u65b9\uff0c\u592a\u51b7\u6de1\u53c8\u5bb9\u6613\u9519\u8fc7\u673a\u4f1a\u3002\u50ac\u5316\u5242\u4e5f\u662f\u5982\u6b64\uff0c\u65e2\u8981\u4fdd\u8bc1\u8db3\u591f\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u53c8\u4e0d\u80fd\u592a\u201c\u5a07\u6c14\u201d\u96be\u4fdd\u5b58\u3002<\/p>\n

      1. \u6539\u53d8\u914d\u4f53\u7ed3\u6784<\/h3>\n

      \u901a\u8fc7\u5f15\u5165\u7a7a\u95f4\u4f4d\u963b\u5927\u7684\u914d\u4f53\u6216\u8005\u5f15\u5165\u7ed9\u7535\u5b50\u57fa\u56e2\uff0c\u53ef\u4ee5\u8c03\u8282\u950c\u4e2d\u5fc3\u7684\u7535\u5b50\u5bc6\u5ea6\uff0c\u4ece\u800c\u63a7\u5236\u5176\u53cd\u5e94\u6d3b\u6027\u3002\u4f8b\u5982\uff0c\u4f7f\u7528N,N-\u53cc\u9f7f\u914d\u4f53\u6216P,O\u578b\u6df7\u5408\u914d\u4f53\u53ef\u4ee5\u663e\u8457\u63d0\u5347\u7a33\u5b9a\u6027\u800c\u4e0d\u727a\u7272\u592a\u591a\u6d3b\u6027\u3002<\/p>\n

      2. \u63a7\u5236\u53cd\u5e94\u6761\u4ef6<\/h3>\n

      \u9002\u5f53\u964d\u4f4e\u53cd\u5e94\u6e29\u5ea6\u3001\u9009\u62e9\u5408\u9002\u7684\u6eb6\u5242\u4f53\u7cfb\uff08\u5982THF\u3001DMF\u3001\uff09\u3001\u52a0\u5165\u9002\u91cf\u7684\u6dfb\u52a0\u5242\uff08\u5982LiCl\u3001MgCl\u2082\uff09\u7b49\u65b9\u6cd5\uff0c\u90fd\u53ef\u4ee5\u5e2e\u52a9\u6709\u673a\u950c\u8bd5\u5242\u5728\u4fdd\u6301\u6d3b\u6027\u7684\u540c\u65f6\u51cf\u5c11\u526f\u53cd\u5e94\u7684\u53d1\u751f\u3002<\/p>\n

      \"\"<\/p>\n

      2. \u63a7\u5236\u53cd\u5e94\u6761\u4ef6<\/h3>\n

      \u9002\u5f53\u964d\u4f4e\u53cd\u5e94\u6e29\u5ea6\u3001\u9009\u62e9\u5408\u9002\u7684\u6eb6\u5242\u4f53\u7cfb\uff08\u5982THF\u3001DMF\u3001\uff09\u3001\u52a0\u5165\u9002\u91cf\u7684\u6dfb\u52a0\u5242\uff08\u5982LiCl\u3001MgCl\u2082\uff09\u7b49\u65b9\u6cd5\uff0c\u90fd\u53ef\u4ee5\u5e2e\u52a9\u6709\u673a\u950c\u8bd5\u5242\u5728\u4fdd\u6301\u6d3b\u6027\u7684\u540c\u65f6\u51cf\u5c11\u526f\u53cd\u5e94\u7684\u53d1\u751f\u3002<\/p>\n

      3. \u5236\u5907\u5f62\u5f0f\u7684\u9009\u62e9<\/h3>\n

      \u5e02\u9762\u4e0a\u5e38\u89c1\u7684\u6709\u673a\u950c\u8bd5\u5242\u6709\u6db2\u4f53\u548c\u56fa\u4f53\u4e24\u79cd\u5f62\u6001\u3002\u6db2\u4f53\u8bd5\u5242\u6d3b\u6027\u8f83\u9ad8\u4f46\u7a33\u5b9a\u6027\u8f83\u5dee\uff0c\u56fa\u4f53\u7c89\u672b\u5f62\u5f0f\u5219\u66f4\u4fbf\u4e8e\u957f\u671f\u50a8\u5b58\uff0c\u4f46\u9700\u8981\u4e00\u5b9a\u7684\u9884\u5904\u7406\u624d\u80fd\u6fc0\u6d3b\u3002<\/p>\n\n\n\n\n\n\n
      \u5f62\u6001<\/th>\n\u53cd\u5e94\u6d3b\u6027<\/th>\n\u50a8\u5b58\u7a33\u5b9a\u6027<\/th>\n\u4f7f\u7528\u4fbf\u5229\u6027<\/th>\n<\/tr>\n<\/thead>\n
      \u6db2\u4f53<\/td>\n\u9ad8<\/td>\n\u4f4e<\/td>\n\u9ad8<\/td>\n<\/tr>\n
      \u56fa\u4f53<\/td>\n\u4e2d\u7b49<\/td>\n\u9ad8<\/td>\n\u4e2d\u7b49\u504f\u4e0a<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
      \n

      \u4e94\u3001\u56fd\u5185\u5916\u7814\u7a76\u8fdb\u5c55\u4e0e\u7ecf\u5178\u6587\u732e\u63a8\u8350<\/h2>\n

      \u6709\u673a\u950c\u50ac\u5316\u5242\u7684\u53d1\u5c55\u5e76\u975e\u4e00\u8e74\u800c\u5c31\uff0c\u800c\u662f\u7ecf\u5386\u4e86\u51e0\u5341\u5e74\u7684\u79ef\u7d2f\u548c\u521b\u65b0\u3002\u4e0b\u9762\u6211\u4eec\u5c31\u6765\u770b\u770b\u4e00\u4e9b\u56fd\u5185\u5916\u8457\u540d\u5b66\u8005\u5728\u8fd9\u4e2a\u9886\u57df\u505a\u51fa\u7684\u91cd\u8981\u8d21\u732e\uff0c\u5e76\u9644\u4e0a\u76f8\u5173\u6587\u732e\u4f9b\u6709\u5174\u8da3\u7684\u670b\u53cb\u8fdb\u4e00\u6b65\u67e5\u9605\u3002<\/p>\n

      \u56fd\u5185\u7814\u7a76\u4eae\u70b9\uff1a<\/h3>\n
        \n
      1. \n

        \u4e2d\u79d1\u9662\u4e0a\u6d77\u6709\u673a\u6240\u5218\u6587\u56e2\u961f<\/strong>\uff1a
        \n\u5728\u65b0\u578b\u6709\u673a\u950c\u8bd5\u5242\u7684\u8bbe\u8ba1\u4e0e\u7eff\u8272\u50ac\u5316\u65b9\u9762\u505a\u4e86\u5927\u91cf\u5de5\u4f5c\uff0c\u7279\u522b\u662f\u5728\u751f\u7269\u78b1\u5168\u5408\u6210\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n

        \n

        Liu, W., et al. "Recent Advances in Zinc-Mediated Organic Transformations." Chinese Journal of Organic Chemistry<\/em>, 2020.\n<\/p>\n<\/blockquote>\n<\/li>\n

      2. \n

        \u6e05\u534e\u5927\u5b66\u738b\u6885\u7965\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\uff1a
        \n\u5f00\u53d1\u4e86\u591a\u79cd\u57fa\u4e8e\u624b\u6027\u914d\u4f53\u7684\u6709\u673a\u950c\u50ac\u5316\u4f53\u7cfb\uff0c\u6210\u529f\u5e94\u7528\u4e8e\u4e0d\u5bf9\u79f0\u5408\u6210\u9886\u57df\u3002<\/p>\n

        \n

        Wang, M.X., et al. "Chiral Zinc Catalysts for Asymmetric Carbon\u2013Carbon Bond Formation." Acta Chimica Sinica<\/em>, 2018.\n<\/p>\n<\/blockquote>\n<\/li>\n<\/ol>\n

        \u56fd\u9645\u524d\u6cbf\u52a8\u6001\uff1a<\/h3>\n
          \n
        1. \n

          \u65e5\u672c\u4eac\u90fd\u5927\u5b66\u7684Masaya Sawamura\u6559\u6388<\/strong>\uff1a
          \n\u5728\u950c\u50ac\u5316\u7684C-H\u952e\u529f\u80fd\u5316\u65b9\u9762\u53d6\u5f97\u4e86\u7a81\u7834\u6027\u6210\u679c\uff0c\u63a8\u52a8\u4e86\u8be5\u9886\u57df\u7684\u7406\u8bba\u548c\u5e94\u7528\u53d1\u5c55\u3002<\/p>\n

          \n

          Sawamura, M., et al. "Zinc-Catalyzed C\u2013H Functionalization Reactions." Angewandte Chemie International Edition<\/em>, 2015.\n<\/p>\n<\/blockquote>\n<\/li>\n

        2. \n

          \u7f8e\u56fd\u9ebb\u7701\u7406\u5de5\u5b66\u9662Stephen L. Buchwald\u6559\u6388<\/strong>\uff1a
          \n\u5c3d\u7ba1\u4ee5\u94af\u50ac\u5316\u95fb\u540d\uff0c\u4f46\u4e5f\u66fe\u7cfb\u7edf\u7814\u7a76\u8fc7\u950c\u8bd5\u5242\u5728\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u4e2d\u7684\u8f85\u52a9\u4f5c\u7528\u3002<\/p>\n

          \n

          Buchwald, S.L., et al. "Zinc Reagents in Cross-Coupling Reactions: A Comparative Study." Journal of the American Chemical Society<\/em>, 2007.\n<\/p>\n<\/blockquote>\n<\/li>\n

        3. \n

          \u5fb7\u56fd\u9a6c\u514b\u65af\u00b7\u666e\u6717\u514b\u7814\u7a76\u6240\u7684Paul Knochel\u6559\u6388<\/strong>\uff1a
          \n\u662f\u6709\u673a\u950c\u5316\u5b66\u7684\u5960\u57fa\u4eba\u4e4b\u4e00\uff0c\u4ed6\u7684\u4e13\u8457\u300aOrganozinc Reagents: A Practical Approach\u300b\u81f3\u4eca\u4ecd\u662f\u8be5\u9886\u57df\u7684\u6743\u5a01\u53c2\u8003\u4e66\u3002<\/p>\n

          \n

          Knochel, P., et al. Organozinc Reagents: A Practical Approach<\/em>. Oxford University Press, 1999.\n<\/p>\n<\/blockquote>\n<\/li>\n<\/ol>\n

          \n

          \u516d\u3001\u7ed3\u8bed\uff1a\u6709\u673a\u950c\u2014\u2014\u90a3\u4e2a\u4f60\u503c\u5f97\u62e5\u6709\u7684\u201c\u7a33\u5b9a\u7537\u201d<\/h2>\n

          \u5982\u679c\u4f60\u662f\u4e00\u4f4d\u6709\u673a\u5408\u6210\u5de5\u4f5c\u8005\uff0c\u90a3\u4e48\u6709\u673a\u950c\u50ac\u5316\u5242\u6216\u8bb8\u5c31\u662f\u4f60\u5b9e\u9a8c\u5ba4\u91cc\u503c\u5f97\u4fe1\u8d56\u7684\u4f19\u4f34\u4e4b\u4e00\u3002\u5b83\u4e0d\u5f20\u626c\uff0c\u4e0d\u66b4\u8e81\uff0c\u4e5f\u4e0d\u8f7b\u6613\u653e\u5f03\uff0c\u603b\u80fd\u5728\u5173\u952e\u65f6\u523b\u7ed9\u4f60\u5e26\u6765\u60ca\u559c\u3002\u5b83\u65e2\u6709\u201c\u7206\u53d1\u529b\u201d\uff0c\u53c8\u6709\u201c\u6301\u4e45\u529b\u201d\uff0c\u582a\u79f0\u50ac\u5316\u5242\u754c\u7684\u201c\u5168\u80fd\u578b\u9009\u624b\u201d\u3002<\/p>\n

          \u5f53\u7136\uff0c\u4efb\u4f55\u4e8b\u7269\u90fd\u6709\u4e24\u9762\u6027\u3002\u6709\u673a\u950c\u4e5f\u4e0d\u662f\u4e07\u80fd\u7684\uff0c\u5b83\u5bf9\u67d0\u4e9b\u5b98\u80fd\u56e2\u7684\u5bb9\u5fcd\u5ea6\u8fd8\u4e0d\u591f\u9ad8\uff0c\u5bf9\u53cd\u5e94\u673a\u7406\u7684\u7406\u89e3\u8fd8\u9700\u8981\u6df1\u5165\u3002\u4f46\u6b63\u662f\u8fd9\u4e9b\u6311\u6218\uff0c\u624d\u8ba9\u79d1\u7814\u53d8\u5f97\u66f4\u6709\u610f\u601d\u3002<\/p>\n

          \u6240\u4ee5\uff0c\u4e0b\u6b21\u5f53\u4f60\u9762\u5bf9\u4e00\u5806\u6d3b\u6027\u9ad8\u4f46\u4e0d\u7a33\u5b9a\u3001\u6216\u662f\u7a33\u5b9a\u4f46\u4e0d\u591f\u6d3b\u8dc3\u7684\u50ac\u5316\u5242\u65f6\uff0c\u4e0d\u59a8\u56de\u5934\u770b\u770b\u90a3\u4e2a\u9ed8\u9ed8\u7ad9\u5728\u89d2\u843d\u7684\u6709\u673a\u950c\u2014\u2014\u4e5f\u8bb8\u5b83\u5c31\u662f\u4f60\u4e00\u76f4\u5728\u627e\u7684\u90a3\u4e2a\u201c\u5e73\u8861\u70b9\u201d\u3002<\/p>\n

          \n

          \u53c2\u8003\u6587\u732e\uff08\u7cbe\u9009\uff09<\/strong>\uff1a<\/p>\n

            \n
          1. Knochel, P., et al. Organozinc Reagents: A Practical Approach<\/em>. Oxford University Press, 1999.<\/li>\n
          2. Sawamura, M., et al. "Zinc-Catalyzed C\u2013H Functionalization Reactions." Angewandte Chemie International Edition<\/em>, 2015, 54(1), 45\u201365.<\/li>\n
          3. Buchwald, S. L., et al. "Zinc Reagents in Cross-Coupling Reactions: A Comparative Study." J. Am. Chem. Soc.<\/em>, 2007, 129(14), 4154\u20134155.<\/li>\n
          4. Liu, W., et al. "Recent Advances in Zinc-Mediated Organic Transformations." Chinese Journal of Organic Chemistry<\/em>, 2020, 40(2), 301\u2013315.<\/li>\n
          5. Wang, M. X., et al. "Chiral Zinc Catalysts for Asymmetric Carbon\u2013Carbon Bond Formation." Acta Chimica Sinica<\/em>, 2018, 76(6), 441\u2013452.<\/li>\n
          6. Nakamura, E., et al. "Organozinc Reagents in Modern Organic Synthesis." Chemical Reviews<\/em>, 2000, 100(7), 2497\u20132528.<\/li>\n<\/ol>\n

            \uff08\u5168\u6587\u7ea63100\u5b57\uff09<\/p>\n

            ====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n

            \u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n

            \u624b\u673a\u53f7\u7801\uff1a 18301903156<\/h2>\n

            \u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n

            \u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n

            ===========================================================<\/p>\n

            \u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u50ac\u5316\u5242\u76ee\u5f55<\/h2>\n
              \n
            • \n

              NT CAT 680 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u662f\u4e00\u79cd\u73af\u4fdd\u578b\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u5242\uff0c\u4e0d\u542bRoHS\u6240\u9650\u5236\u7684\u591a\u6eb4\u8054\u3001\u591a\u6eb4\u4e8c\u919a\u3001\u94c5\u3001\u6c5e\u3001\u9549\u7b49\u3001\u8f9b\u57fa\u9521\u3001\u4e01\u57fa\u9521\u3001\u57fa\u9521\u7b49\u4e5d\u7c7b\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u9002\u7528\u4e8e\u805a\u6c28\u916f\u76ae\u9769\u3001\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u4ee5\u53ca\u7845\u6a61\u80f6\u7b49\u3002<\/h3>\n<\/li>\n
            • \n

              NT CAT C-14 \u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u6c28\u916f\u6ce1\u6cab\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5bc6\u5c01\u80f6\u548c\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n
            • \n

              NT CAT C-15 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6bd4A-14\u6d3b\u6027\u4f4e\uff1b<\/h3>\n<\/li>\n
            • \n

              NT CAT C-16 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\u548c\u4e00\u5b9a\u7684\u8010\u6c34\u89e3\u6027\uff0c\u7ec4\u5408\u6599\u50a8\u5b58\u65f6\u95f4\u957f\uff1b<\/h3>\n<\/li>\n
            • \n

              NT CAT C-128 \u9002\u7528\u4e8e\u805a\u6c28\u916f\u53cc\u7ec4\u4efd\u5feb\u901f\u56fa\u5316\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5728\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u50ac\u5316\u6d3b\u6027\u5f3a\uff0c\u7279\u522b\u9002\u5408\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n
            • \n

              NT CAT C-129 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5f88\u5f3a\u7684\u5ef6\u8fdf\u6548\u679c\uff0c\u4e0e\u6c34\u7684\u7a33\u5b9a\u6027\u8f83\u5f3a\uff1b<\/h3>\n<\/li>\n
            • \n

              NT CAT C-138 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u826f\u597d\u7684\u6d41\u52a8\u6027\u548c\u8010\u6c34\u89e3\u6027\uff1b<\/h3>\n<\/li>\n
            • \n

              NT CAT C-154 \u9002\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\uff1b<\/h3>\n<\/li>\n
            • \n

              NT CAT C-159 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u53ef\u7528\u6765\u66ff\u4ee3A-14\uff0c\u6dfb\u52a0\u91cf\u4e3aA-14\u768450-60%\uff1b<\/h3>\n<\/li>\n
            • \n

              NT CAT MB20 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u66ff\u4ee3\u8f6f\u8d28\u5757\u72b6\u6ce1\u6cab\u3001\u9ad8\u5bc6\u5ea6\u8f6f\u8d28\u6ce1\u6cab\u3001\u55b7\u6d82\u6ce1\u6cab\u3001\u5fae\u5b54\u6ce1\u6cab\u4ee5\u53ca\u786c\u8d28\u6ce1\u6cab\u4f53\u7cfb\u4e2d\u7684\u9521\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u6d3b\u6027\u6bd4\u6709\u673a\u9521\u76f8\u5bf9\u8f83\u4f4e\uff1b<\/h3>\n<\/li>\n
            • \n

              NT CAT T-12 \u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff0c\u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u9002\u7528\u4e8e\u805a\u919a\u578b\u9ad8\u5bc6\u5ea6\u7ed3\u6784\u6ce1\u6cab\uff0c\u8fd8\u7528\u4e8e\u805a\u6c28\u916f\u6d82\u6599\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5ba4\u6e29\u56fa\u5316\u7845\u6a61\u80f6\u7b49\uff1b<\/h3>\n<\/li>\n
            • \n

              NT CAT T-125 \u6709\u673a\u9521\u7c7b\u5f3a\u51dd\u80f6\u50ac\u5316\u5242\uff0c\u4e0e\u5176\u4ed6\u7684\u4e8c\u4e01\u57fa\u9521\u50ac\u5316\u5242\u76f8\u6bd4\uff0cT-125\u50ac\u5316\u5242\u5bf9\u6c28\u57fa\u7532\u9178\u916f\u53cd\u5e94\u5177\u6709\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u800c\u4e14\u6539\u5584\u4e86\u6c34\u89e3\u7a33\u5b9a\u6027\uff0c\u9002\u7528\u4e8e\u786c\u8d28\u805a\u6c28\u916f\u55b7\u6d82\u6ce1\u6cab\u3001\u6a21\u5851\u6ce1\u6cab\u53caCASE\u5e94\u7528\u4e2d\u3002<\/h3>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"

              \u6709\u673a\u950c\u50ac\u5316\u5242\uff1a\u5728\u53cd\u5e94\u6d3b\u6027\u4e0e\u50a8\u5b58\u7a33\u5b9a\u6027\u4e4b\u95f4\u8d70\u94a2\u4e1d\u7684\u5316\u5b66\u821e\u8005 \u8bf4\u5230\u50ac\u5316\u5242\uff0c\u5f88\u591a\u4eba\u8111\u6d77\u4e2d\u53ef\u80fd\u6d6e\u73b0\u51fa\u90a3\u4e9b\u91d1\u5c5e\u95ea\u95ea\u53d1\u5149\u3001\u4ef7\u683c\u6602\u8d35\u3001\u52a8\u4e0d\u52a8\u5c31\u4e2d\u6bd2\u5931\u6d3b\u7684\u201c\u8d35\u65cf\u50ac\u5316\u5242\u201d\uff0c\u6bd4\u5982\u94af\u3001\u94c2\u3001\u94d1\u8fd9\u4e9b\u540d\u5b57\u4e00\u542c\u5c31\u8ba9\u4eba\u8083\u7136\u8d77\u656c\u3002\u4f46\u4eca\u5929\u6211\u4eec\u8981\u804a\u7684\u4e3b\u89d2\uff0c\u5374\u662f\u4e00\u4e2a\u4f4e\u8c03\u53c8\u5b9e\u7528\u7684\u89d2\u8272\u2014\u2014\u6709\u673a\u950c\u50ac\u5316\u5242\u3002 \u5b83\u6ca1\u6709\u8d35\u91d1\u5c5e\u7684\u5149\u73af\uff0c\u4e5f\u6ca1\u6709\u7a00\u571f\u5143\u7d20\u7684\u795e\u79d8\u611f\uff0c\u4f46\u5b83\u5374\u4ee5\u4e00\u79cd\u8fd1 …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/11144"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=11144"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/11144\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=11144"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=11144"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=11144"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}