{"id":11214,"date":"2025-06-27T02:06:42","date_gmt":"2025-06-26T18:06:42","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/11214"},"modified":"2025-06-27T02:06:42","modified_gmt":"2025-06-26T18:06:42","slug":"%e5%88%86%e6%9e%90%e6%9c%89%e6%9c%ba%e9%94%8c%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e6%88%90%e6%9c%ac%e6%95%88%e7%9b%8a%e4%b8%8e%e5%b8%82%e5%9c%ba%e7%ab%9e%e4%ba%89%e5%8a%9b","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/11214","title":{"rendered":"\u5206\u6790\u6709\u673a\u950c\u50ac\u5316\u5242\u7684\u6210\u672c\u6548\u76ca\u4e0e\u5e02\u573a\u7ade\u4e89\u529b"},"content":{"rendered":"<p><strong>\u6709\u673a\u950c\u50ac\u5316\u5242\u7684\u6210\u672c\u6548\u76ca\u4e0e\u5e02\u573a\u7ade\u4e89\u529b\u5206\u6790<\/strong><\/p>\n<p>\u5728\u5316\u5b66\u5de5\u4e1a\u7684\u6d69\u701a\u6d77\u6d0b\u4e2d\uff0c\u50ac\u5316\u5242\u72b9\u5982\u4e00\u8258\u8258\u5f15\u822a\u7684\u706f\u5854\uff0c\u4e3a\u53cd\u5e94\u6307\u660e\u65b9\u5411\u3001\u52a0\u901f\u8fdb\u7a0b\u3002\u800c\u5728\u4f17\u591a\u50ac\u5316\u5242\u5bb6\u65cf\u4e2d\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u8fd1\u5e74\u6765\u6084\u7136\u5d1b\u8d77\uff0c\u9010\u6e10\u6210\u4e3a\u7cbe\u7ec6\u5316\u5de5\u3001\u533b\u836f\u5408\u6210\u3001\u6750\u6599\u79d1\u5b66\u7b49\u9886\u57df\u7684\u4e00\u5339\u201c\u9ed1\u9a6c\u201d\u3002\u5b83\u4e0d\u4ec5\u5177\u5907\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u66f4\u5728\u6210\u672c\u63a7\u5236\u548c\u73af\u5883\u53cb\u597d\u6027\u65b9\u9762\u5c55\u73b0\u51fa\u5f3a\u5927\u7684\u7ade\u4e89\u529b\u3002<\/p>\n<p>\u672c\u6587\u5c06\u4ee5\u901a\u4fd7\u5e7d\u9ed8\u7684\u8bed\u8a00\uff0c\u7ed3\u5408\u5177\u4f53\u53c2\u6570\u548c\u5e02\u573a\u6570\u636e\uff0c\u5e26\u5927\u5bb6\u8d70\u8fdb\u6709\u673a\u950c\u50ac\u5316\u5242\u7684\u4e16\u754c\uff0c\u770b\u770b\u5b83\u662f\u5982\u4f55\u4ece\u5b9e\u9a8c\u5ba4\u8d70\u5411\u5de5\u5382\uff0c\u53c8\u5982\u4f55\u5728\u6210\u672c\u4e0e\u6548\u7387\u4e4b\u95f4\u627e\u5230\u5e73\u8861\u70b9\uff0c\u7ec8\u5728\u6fc0\u70c8\u7684\u5e02\u573a\u7ade\u4e89\u4e2d\u7ad9\u7a33\u811a\u8ddf\u7684\u3002<\/p>\n<hr \/>\n<h3>\u4e00\u3001\u4ec0\u4e48\u662f\u6709\u673a\u950c\u50ac\u5316\u5242\uff1f<\/h3>\n<p>\u9996\u5148\uff0c\u54b1\u4eec\u5148\u6765\u8ba4\u8bc6\u4e00\u4e0b\u8fd9\u4f4d\u201c\u4e3b\u89d2\u201d\u2014\u2014\u6709\u673a\u950c\u50ac\u5316\u5242\u3002<\/p>\n<p>\u7b80\u5355\u6765\u8bf4\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u5c31\u662f\u5c06\u91d1\u5c5e\u950c\u4e0e\u6709\u673a\u914d\u4f53\u7ed3\u5408\u5f62\u6210\u7684\u4e00\u7c7b\u5316\u5408\u7269\uff0c\u5e38\u7528\u4e8e\u4fc3\u8fdb\u78b3-\u78b3\u952e\u3001\u78b3-\u6742\u539f\u5b50\u952e\u7b49\u5173\u952e\u5316\u5b66\u952e\u7684\u5f62\u6210\u3002\u5b83\u4eec\u5e7f\u6cdb\u5e94\u7528\u4e8e\u683c\u6c0f\u8bd5\u5242\u53cd\u5e94\u3001\u5076\u8054\u53cd\u5e94\u3001\u52a0\u6210\u53cd\u5e94\u7b49\u591a\u4e2a\u9886\u57df\uff0c\u5c24\u5176\u5728\u4e0d\u5bf9\u79f0\u5408\u6210\u4e2d\u8868\u73b0\u7a81\u51fa\u3002<\/p>\n<p>\u4e0e\u4f20\u7edf\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\uff08\u5982\u94af\u3001\u94c2\u3001\u94d1\uff09\u76f8\u6bd4\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u7684\u5927\u4f18\u52bf\u5728\u4e8e\uff1a<\/p>\n<ul>\n<li><strong>\u4ef7\u683c\u4eb2\u6c11<\/strong>\uff1a\u950c\u8d44\u6e90\u4e30\u5bcc\uff0c\u539f\u6599\u4fbf\u5b9c\uff1b<\/li>\n<li><strong>\u6bd2\u6027\u4f4e<\/strong>\uff1a\u5bf9\u73af\u5883\u548c\u4eba\u4f53\u76f8\u5bf9\u53cb\u597d\uff1b<\/li>\n<li><strong>\u53ef\u56de\u6536\u6027\u5f3a<\/strong>\uff1a\u90e8\u5206\u4f53\u7cfb\u4e0b\u53ef\u5faa\u73af\u4f7f\u7528\uff1b<\/li>\n<li><strong>\u9009\u62e9\u6027\u9ad8<\/strong>\uff1a\u5728\u67d0\u4e9b\u7279\u5b9a\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u6781\u9ad8\u7684\u533a\u57df\u548c\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/li>\n<\/ul>\n<hr \/>\n<h3>\u4e8c\u3001\u4ea7\u54c1\u53c2\u6570\u5bf9\u6bd4\uff1a\u8c01\u624d\u662f\u6027\u4ef7\u6bd4\u4e4b\u738b\uff1f<\/h3>\n<p>\u4e3a\u4e86\u8ba9\u5927\u5bb6\u6709\u4e2a\u76f4\u89c2\u7684\u8ba4\u8bc6\uff0c\u6211\u4eec\u4e0d\u59a8\u628a\u6709\u673a\u950c\u50ac\u5316\u5242\u4e0e\u5176\u4ed6\u5e38\u89c1\u50ac\u5316\u5242\u505a\u4e00\u4e2a\u6a2a\u5411\u6bd4\u8f83\u3002\u4ee5\u4e0b\u8868\u683c\u5217\u51fa\u4e86\u51e0\u7c7b\u5e38\u7528\u50ac\u5316\u5242\u7684\u57fa\u672c\u53c2\u6570\u53ca\u5e94\u7528\u573a\u666f\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n<th>\u5178\u578b\u4ee3\u8868<\/th>\n<th>\u6210\u672c\uff08\u5143\/kg\uff09<\/th>\n<th>\u6bd2\u6027\u7b49\u7ea7<\/th>\n<th>\u53cd\u5e94\u6d3b\u6027<\/th>\n<th>\u53ef\u56de\u6536\u6027<\/th>\n<th>\u5e94\u7528\u573a\u666f\u4e3e\u4f8b<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6709\u673a\u950c\u50ac\u5316\u5242<\/td>\n<td>Zn(OTf)\u2082\u3001ZnCl\u2082<\/td>\n<td>500~2000<\/td>\n<td>\u4f4e<\/td>\n<td>\u4e2d\u9ad8<\/td>\n<td>\u4e2d<\/td>\n<td>\u7cbe\u7ec6\u5316\u5b66\u54c1\u3001\u836f\u7269\u4e2d\u95f4\u4f53<\/td>\n<\/tr>\n<tr>\n<td>\u94af\u50ac\u5316\u5242<\/td>\n<td>Pd(PPh\u2083)\u2084<\/td>\n<td>8000~30000<\/td>\n<td>\u4e2d<\/td>\n<td>\u9ad8<\/td>\n<td>\u5f31<\/td>\n<td>C\u2013C\u5076\u8054\u3001\u4ea4\u53c9\u5076\u8054\u53cd\u5e94<\/td>\n<\/tr>\n<tr>\n<td>\u94c1\u50ac\u5316\u5242<\/td>\n<td>FeCl\u2083<\/td>\n<td>100~500<\/td>\n<td>\u4f4e<\/td>\n<td>\u4e2d<\/td>\n<td>\u5f3a<\/td>\n<td>\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3001Friedel-Crafts<\/td>\n<\/tr>\n<tr>\n<td>\u94dc\u50ac\u5316\u5242<\/td>\n<td>CuI<\/td>\n<td>300~1000<\/td>\n<td>\u4e2d<\/td>\n<td>\u4e2d<\/td>\n<td>\u4e2d<\/td>\n<td>Ullmann\u53cd\u5e94\u3001Chan-Lam\u5076\u8054<\/td>\n<\/tr>\n<tr>\n<td>\u8d35\u91d1\u5c5e\u50ac\u5316\u5242<\/td>\n<td>PtO\u2082<\/td>\n<td>100000+<\/td>\n<td>\u9ad8<\/td>\n<td>\u6781\u9ad8<\/td>\n<td>\u6781\u5f31<\/td>\n<td>\u52a0\u6c22\u53cd\u5e94\u3001\u71c3\u6599\u7535\u6c60<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u4e0a\u8868\u53ef\u4ee5\u770b\u51fa\uff0c\u867d\u7136\u6709\u673a\u950c\u50ac\u5316\u5242\u5728\u6d3b\u6027\u4e0a\u7565\u900a\u4e8e\u94af\u3001\u94c2\u7b49\u8d35\u91d1\u5c5e\uff0c\u4f46\u5728\u6210\u672c\u3001\u6bd2\u6027\u548c\u73af\u4fdd\u65b9\u9762\u5374\u6709\u7740\u663e\u8457\u4f18\u52bf\u3002\u5c24\u5176\u662f\u5728\u4e00\u4e9b\u5bf9\u50ac\u5316\u5242\u7528\u91cf\u8f83\u5927\u3001\u5bf9\u6210\u672c\u654f\u611f\u7684\u5de5\u827a\u4e2d\uff0c\u6709\u673a\u950c\u65e0\u7591\u662f\u9996\u9009\u3002<\/p>\n<hr \/>\n<h3>\u4e09\u3001\u6210\u672c\u6548\u76ca\u5206\u6790\uff1a\u7701\u94b1\u4e0d\u51cf\u6548\u7684\u79d8\u5bc6<\/h3>\n<h4>1. \u539f\u6599\u6210\u672c\u4f4e\u5ec9\uff0c\u4f9b\u5e94\u94fe\u7a33\u5b9a<\/h4>\n<p>\u950c\u662f\u4e00\u79cd\u5e38\u89c1\u7684\u91d1\u5c5e\u5143\u7d20\uff0c\u5728\u5730\u58f3\u4e2d\u7684\u542b\u91cf\u7ea6\u4e3a75 ppm\uff0c\u5168\u7403\u50a8\u91cf\u8d85\u8fc710\u4ebf\u5428\u3002\u6211\u56fd\u662f\u950c\u77ff\u8d44\u6e90\u5927\u56fd\uff0c\u5e74\u4ea7\u91cf\u4f4d\u5c45\u4e16\u754c\u524d\u5217\uff0c\u539f\u6750\u6599\u83b7\u53d6\u4fbf\u5229\u4e14\u4ef7\u683c\u6ce2\u52a8\u5c0f\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u94af\u3001\u94c2\u7b49\u8d35\u91d1\u5c5e\u53d7\u56fd\u9645\u5e02\u573a\u5f71\u54cd\u5927\uff0c\u4ef7\u683c\u8d77\u4f0f\u5267\u70c8\uff0c\u7ed9\u4f01\u4e1a\u5e26\u6765\u8f83\u5927\u7684\u6210\u672c\u538b\u529b\u3002<\/p>\n<h4>2. \u5408\u6210\u8def\u7ebf\u6210\u719f\uff0c\u6613\u4e8e\u89c4\u6a21\u5316\u751f\u4ea7<\/h4>\n<p>\u6709\u673a\u950c\u50ac\u5316\u5242\u7684\u5408\u6210\u901a\u5e38\u91c7\u7528\u7ecf\u5178\u7684\u91d1\u5c5e\u6709\u673a\u65b9\u6cd5\uff0c\u5982\u5364\u4ee3\u70c3\u4e0e\u950c\u7c89\u5728\u6eb6\u5242\u4e2d\u56de\u6d41\u53cd\u5e94\uff0c\u6216\u8005\u901a\u8fc7\u8f6c\u91d1\u5c5e\u5316\u53cd\u5e94\u5236\u5907\u3002\u8fd9\u4e9b\u65b9\u6cd5\u64cd\u4f5c\u7b80\u4fbf\u3001\u6536\u7387\u8f83\u9ad8\uff0c\u9002\u5408\u5de5\u4e1a\u5316\u751f\u4ea7\u3002\u4f8b\u5982\uff1a<\/p>\n<ul>\n<li>ZnCl\u2082\u7684\u5408\u6210\u51e0\u4e4e\u662f\u65e0\u95e8\u69db\uff1b<\/li>\n<li>Zn(OTf)\u2082\u53ef\u901a\u8fc7ZnO\u4e0e\u4e09\u6c1f\u7532\u78fa\u9178\u76f4\u63a5\u53cd\u5e94\u83b7\u5f97\uff0c\u4ea7\u7387\u53ef\u8fbe90%\u4ee5\u4e0a\uff1b<\/li>\n<li>\u624b\u6027\u914d\u4f53\u4fee\u9970\u7684\u6709\u673a\u950c\u50ac\u5316\u5242\u867d\u590d\u6742\u4e9b\uff0c\u4f46\u5df2\u6709\u6210\u719f\u7684\u5546\u4e1a\u4f9b\u5e94\u6e20\u9053\u3002<\/li>\n<\/ul>\n<h4>3. \u50ac\u5316\u6548\u7387\u9ad8\uff0c\u5355\u4f4d\u6210\u672c\u66f4\u4f4e<\/h4>\n<p>\u5c3d\u7ba1\u5355\u6b21\u4f7f\u7528\u7684\u50ac\u5316\u5242\u6210\u672c\u53ef\u80fd\u4e0d\u5982\u94c1\u6216\u94dc\u90a3\u4e48\u4f4e\uff0c\u4f46\u7531\u4e8e\u5176\u50ac\u5316\u6548\u7387\u9ad8\uff0c\u6240\u9700\u7528\u91cf\u5c11\uff0c\u53cd\u800c\u5728\u6574\u4f53\u6210\u672c\u4e0a\u66f4\u5177\u4f18\u52bf\u3002\u6bd4\u5982\u5728\u67d0\u4e2a\u836f\u7269\u4e2d\u95f4\u4f53\u7684\u5408\u6210\u4e2d\uff0c\u4f7f\u7528Pd\u50ac\u5316\u5242\u6bcf\u6279\u6b21\u9700\u82b1\u8d39\u7ea65\u4e07\u5143\uff0c\u800c\u6362\u6210\u6709\u673a\u950c\u540e\uff0c\u6210\u672c\u964d\u81f31\u4e07\u5143\u4ee5\u5185\uff0c\u4e14\u4ea7\u7387\u4ec5\u4e0b\u964d\u4e86\u4e0d\u52305%\uff0c\u5b8c\u5168\u5728\u53ef\u63a5\u53d7\u8303\u56f4\u5185\u3002<\/p>\n<hr \/>\n<h3>\u56db\u3001\u5e02\u573a\u7ade\u4e89\u529b\u5256\u6790\uff1a\u6709\u673a\u950c\u4e3a\u4f55\u80fd\u8131\u9896\u800c\u51fa\uff1f<\/h3>\n<h4>1. \u7eff\u8272\u5316\u5b66\u8d8b\u52bf\u4e0b\u7684\u5ba0\u513f<\/h4>\n<p>\u968f\u7740\u5168\u7403\u5bf9\u73af\u4fdd\u6cd5\u89c4\u7684\u65e5\u76ca\u4e25\u683c\uff0c\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u6df1\u5165\u4eba\u5fc3\u3002\u6709\u673a\u950c\u50ac\u5316\u5242\u4ee5\u5176\u4f4e\u6bd2\u3001\u6613\u5904\u7406\u3001\u526f\u4ea7\u7269\u5c11\u7684\u7279\u70b9\uff0c\u6b63\u597d\u5951\u5408\u8fd9\u4e00\u8d8b\u52bf\u3002\u8bb8\u591a\u56fd\u5bb6\u548c\u5730\u533a\u5df2\u51fa\u53f0\u653f\u7b56\u9650\u5236\u91cd\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u4f7f\u7528\uff0c\u8fd9\u65e0\u7591\u4e3a\u6709\u673a\u950c\u6253\u5f00\u4e86\u65b0\u7684\u5e02\u573a\u7a7a\u95f4\u3002<\/p>\n<h4>2. \u5728\u5236\u836f\u9886\u57df\u7684\u5e7f\u6cdb\u5e94\u7528<\/h4>\n<p>\u5728\u5236\u836f\u884c\u4e1a\uff0c\u5c24\u5176\u662f\u5c0f\u5206\u5b50\u836f\u7269\u7684\u5408\u6210\u4e2d\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u56e0\u5176\u826f\u597d\u7684\u5b98\u80fd\u56e2\u8010\u53d7\u6027\u548c\u624b\u6027\u63a7\u5236\u80fd\u529b\uff0c\u6210\u4e3a\u6784\u5efa\u590d\u6742\u7ed3\u6784\u7684\u7406\u60f3\u5de5\u5177\u3002\u4f8b\u5982\uff0c\u5728\u6297\u6291\u90c1\u836f\u5e15\u7f57\u897f\u6c40\u7684\u5408\u6210\u4e2d\uff0c\u5c31\u91c7\u7528\u4e86\u6709\u673a\u950c\u50ac\u5316\u7684\u70f7\u57fa\u5316\u6b65\u9aa4\uff0c\u5927\u5e45\u63d0\u5347\u4e86\u53cd\u5e94\u6548\u7387\u548c\u9009\u62e9\u6027\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/81.jpg\" alt=\"\"><\/p>\n<h4>2. \u5728\u5236\u836f\u9886\u57df\u7684\u5e7f\u6cdb\u5e94\u7528<\/h4>\n<p>\u5728\u5236\u836f\u884c\u4e1a\uff0c\u5c24\u5176\u662f\u5c0f\u5206\u5b50\u836f\u7269\u7684\u5408\u6210\u4e2d\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u56e0\u5176\u826f\u597d\u7684\u5b98\u80fd\u56e2\u8010\u53d7\u6027\u548c\u624b\u6027\u63a7\u5236\u80fd\u529b\uff0c\u6210\u4e3a\u6784\u5efa\u590d\u6742\u7ed3\u6784\u7684\u7406\u60f3\u5de5\u5177\u3002\u4f8b\u5982\uff0c\u5728\u6297\u6291\u90c1\u836f\u5e15\u7f57\u897f\u6c40\u7684\u5408\u6210\u4e2d\uff0c\u5c31\u91c7\u7528\u4e86\u6709\u673a\u950c\u50ac\u5316\u7684\u70f7\u57fa\u5316\u6b65\u9aa4\uff0c\u5927\u5e45\u63d0\u5347\u4e86\u53cd\u5e94\u6548\u7387\u548c\u9009\u62e9\u6027\u3002<\/p>\n<h4>3. \u4e0e\u751f\u7269\u50ac\u5316\u534f\u540c\u53d1\u5c55\u7684\u6f5c\u529b<\/h4>\n<p>\u8fd1\u5e74\u6765\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u8fd8\u88ab\u5c1d\u8bd5\u4e0e\u9176\u50ac\u5316\u7ed3\u5408\uff0c\u53d1\u5c55\u51fa\u201c\u53cc\u529f\u80fd\u50ac\u5316\u4f53\u7cfb\u201d\uff0c\u5728\u67d0\u4e9b\u8f6c\u5316\u4e2d\u5b9e\u73b0\u4e86\u66f4\u9ad8\u7684\u9009\u62e9\u6027\u548c\u66f4\u4f4e\u7684\u80fd\u91cf\u6d88\u8017\u3002\u8fd9\u79cd\u8de8\u754c\u7684\u7ec4\u5408\u6a21\u5f0f\uff0c\u6b63\u5728\u5438\u5f15\u8d8a\u6765\u8d8a\u591a\u7814\u7a76\u8005\u7684\u5173\u6ce8\u3002<\/p>\n<hr \/>\n<h3>\u4e94\u3001\u6311\u6218\u4e0e\u672a\u6765\u5c55\u671b\uff1a\u8def\u6f2b\u6f2b\u5176\u4fee\u8fdc\u516e<\/h3>\n<p>\u5f53\u7136\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u4e5f\u4e0d\u662f\u5341\u5168\u5341\u7f8e\u3002\u5b83\u4e5f\u6709\u81ea\u5df1\u7684\u201c\u77ed\u677f\u201d\uff1a<\/p>\n<ul>\n<li><strong>\u7a33\u5b9a\u6027\u95ee\u9898<\/strong>\uff1a\u67d0\u4e9b\u6709\u673a\u950c\u914d\u5408\u7269\u5728\u7a7a\u6c14\u4e2d\u5bb9\u6613\u6c27\u5316\u6216\u6c34\u89e3\uff1b<\/li>\n<li><strong>\u9002\u7528\u8303\u56f4\u6709\u9650<\/strong>\uff1a\u5e76\u975e\u6240\u6709\u7c7b\u578b\u7684\u53cd\u5e94\u90fd\u9002\u5408\u4f7f\u7528\uff1b<\/li>\n<li><strong>\u9ad8\u7aef\u5e94\u7528\u4f9d\u8d56\u8fdb\u53e3<\/strong>\uff1a\u90e8\u5206\u9ad8\u6027\u80fd\u624b\u6027\u950c\u50ac\u5316\u5242\u4ecd\u9700\u4ece\u56fd\u5916\u8fdb\u53e3\u3002<\/li>\n<\/ul>\n<p>\u4e0d\u8fc7\uff0c\u8fd9\u4e9b\u95ee\u9898\u4e5f\u6070\u6070\u662f\u672a\u6765\u7814\u7a76\u7684\u91cd\u70b9\u65b9\u5411\u3002\u968f\u7740\u65b0\u6750\u6599\u3001\u65b0\u914d\u4f53\u7684\u8bbe\u8ba1\u4e0e\u5f00\u53d1\uff0c\u4ee5\u53ca\u56fd\u4ea7\u66ff\u4ee3\u6280\u672f\u7684\u8fdb\u6b65\uff0c\u8fd9\u4e9b\u95ee\u9898\u6709\u671b\u5728\u672a\u6765\u51e0\u5e74\u5185\u9010\u6b65\u89e3\u51b3\u3002<\/p>\n<hr \/>\n<h3>\u516d\u3001\u56fd\u5185\u5916\u7814\u7a76\u8fdb\u5c55\u4e0e\u5f15\u7528\u6587\u732e<\/h3>\n<p>\u6709\u673a\u950c\u50ac\u5316\u5242\u7684\u7814\u7a76\u65e9\u5df2\u4e0d\u662f\u51b7\u95e8\u8bfe\u9898\u3002\u56fd\u5185\u5916\u4f17\u591a\u79d1\u7814\u56e2\u961f\u90fd\u5728\u79ef\u6781\u63a2\u7d22\u5176\u66f4\u591a\u53ef\u80fd\u6027\u3002<\/p>\n<p>\u5728\u56fd\u5185\uff0c\u6e05\u534e\u5927\u5b66\u3001\u5317\u4eac\u5927\u5b66\u3001\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u6240\u7b49\u673a\u6784\u5728\u8be5\u9886\u57df\u5747\u6709\u5efa\u6811\u3002\u4f8b\u5982\uff1a<\/p>\n<ul>\n<li>\u674e\u6559\u6388\u56e2\u961f\u5728\u300a<strong>Chinese Journal of Organic Chemistry<\/strong>\u300b\u4e2d\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u578b\u624b\u6027\u950c\u50ac\u5316\u5242\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u7684aldol\u53cd\u5e94[1]\uff1b<\/li>\n<li>\u5317\u4eac\u5927\u5b66\u67d0\u8bfe\u9898\u7ec4\u5728\u300a<strong>Acta Chimica Sinica<\/strong>\u300b\u4e2d\u53d1\u8868\u6587\u7ae0\uff0c\u63a2\u8ba8\u4e86\u950c\u50ac\u5316\u5728\u5929\u7136\u4ea7\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528\u524d\u666f[2]\u3002<\/li>\n<\/ul>\n<p>\u5728\u56fd\u5916\uff0c\u76f8\u5173\u7814\u7a76\u66f4\u4e3a\u6df1\u5165\uff1a<\/p>\n<ul>\n<li>\u7f8e\u56fd\u9ebb\u7701\u7406\u5de5\u5b66\u9662\uff08MIT\uff09\u7684MacMillan\u6559\u6388\u56e2\u961f\u66fe\u591a\u6b21\u5728\u300a<strong>Science<\/strong>\u300b\u548c\u300a<strong>Nature<\/strong>\u300b\u4e0a\u53d1\u8868\u5173\u4e8e\u6709\u673a\u950c\u50ac\u5316\u7684\u524d\u6cbf\u6210\u679c\uff0c\u7279\u522b\u662f\u5728\u5149\u50ac\u5316\u4e0e\u950c\u534f\u540c\u4f5c\u7528\u65b9\u9762\u7684\u7a81\u7834\u4ee4\u4eba\u77a9\u76ee[3]\uff1b<\/li>\n<li>\u65e5\u672c\u4e1c\u4eac\u5927\u5b66\u7684Yamamoto\u6559\u6388\u5219\u4e13\u6ce8\u4e8e\u950c\u50ac\u5316\u7684\u4e0d\u5bf9\u79f0\u5408\u6210\uff0c\u5176\u5f00\u53d1\u7684\u591a\u79cd\u950c\u914d\u5408\u7269\u5df2\u88ab\u5546\u4e1a\u5316[4]\uff1b<\/li>\n<li>\u5fb7\u56fd\u9a6c\u514b\u65af\u00b7\u666e\u6717\u514b\u7814\u7a76\u6240\u4e5f\u5728\u950c\u50ac\u5316\u673a\u7406\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u4e86\u91cd\u8981\u8fdb\u5c55\uff0c\u63a8\u52a8\u4e86\u7406\u8bba\u8ba1\u7b97\u4e0e\u5b9e\u9a8c\u9a8c\u8bc1\u7684\u7ed3\u5408[5]\u3002<\/li>\n<\/ul>\n<p>\u8fd9\u4e9b\u7814\u7a76\u6210\u679c\u4e0d\u4ec5\u63a8\u52a8\u4e86\u57fa\u7840\u79d1\u5b66\u7684\u53d1\u5c55\uff0c\u4e5f\u4e3a\u5de5\u4e1a\u754c\u63d0\u4f9b\u4e86\u5b9d\u8d35\u7684\u6280\u672f\u50a8\u5907\u3002<\/p>\n<hr \/>\n<h3>\u7ed3\u8bed\uff1a\u6709\u673a\u950c\u50ac\u5316\u5242\uff0c\u672a\u6765\u7684\u201c\u6027\u4ef7\u6bd4\u738b\u8005\u201d<\/h3>\n<p>\u603b\u800c\u8a00\u4e4b\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u6b63\u4ee5\u4e00\u79cd\u4f4e\u8c03\u5374\u6709\u529b\u7684\u59ff\u6001\uff0c\u6084\u7136\u6539\u53d8\u7740\u6211\u4eec\u7684\u5316\u5b66\u4e16\u754c\u3002\u5b83\u65e2\u4e0d\u50cf\u8d35\u91d1\u5c5e\u90a3\u6837\u9ad8\u4e0d\u53ef\u6500\uff0c\u4e5f\u4e0d\u50cf\u5ec9\u4ef7\u50ac\u5316\u5242\u90a3\u6837\u201c\u529b\u4e0d\u4ece\u5fc3\u201d\uff0c\u800c\u662f\u4ee5\u4e00\u79cd\u6070\u5230\u597d\u5904\u7684\u65b9\u5f0f\uff0c\u5728\u6210\u672c\u4e0e\u6027\u80fd\u4e4b\u95f4\u627e\u5230\u4e86\u5b8c\u7f8e\u7684\u5e73\u8861\u70b9\u3002<\/p>\n<p>\u5bf9\u4e8e\u4f01\u4e1a\u800c\u8a00\uff0c\u9009\u62e9\u6709\u673a\u950c\u50ac\u5316\u5242\uff0c\u4e0d\u4ec5\u662f\u51fa\u4e8e\u7ecf\u6d4e\u8003\u91cf\uff0c\u66f4\u662f\u987a\u5e94\u65f6\u4ee3\u6f6e\u6d41\u3001\u54cd\u5e94\u73af\u4fdd\u53f7\u53ec\u7684\u4e00\u79cd\u667a\u6167\u4e4b\u4e3e\uff1b\u5bf9\u4e8e\u79d1\u7814\u4eba\u5458\u6765\u8bf4\uff0c\u5b83\u5219\u662f\u63a2\u7d22\u672a\u77e5\u3001\u521b\u65b0\u7a81\u7834\u7684\u91cd\u8981\u5de5\u5177\u3002<\/p>\n<p>\u672a\u6765\uff0c\u968f\u7740\u6280\u672f\u7684\u8fdb\u6b65\u548c\u5e02\u573a\u7684\u62d3\u5c55\uff0c\u6709\u673a\u950c\u50ac\u5316\u5242\u5fc5\u5c06\u5728\u66f4\u591a\u9886\u57df\u5927\u653e\u5f02\u5f69\uff0c\u6210\u4e3a\u5316\u5b66\u5de5\u4e1a\u4e2d\u4e00\u9897\u8000\u773c\u7684\u65b0\u661f\u3002<\/p>\n<hr \/>\n<h3>\u53c2\u8003\u6587\u732e\uff1a<\/h3>\n<p>[1] Li, J. et al., <em>Chin. J. Org. Chem.<\/em>, 2022, 42(6), 1678\u20131685.<br \/>\n[2] \u5317\u4eac\u5927\u5b66\u6709\u673a\u5316\u5b66\u8bfe\u9898\u7ec4, <em>\u5316\u5b66\u5b66\u62a5<\/em>, 2021, 79(10), 1123\u20131130.<br \/>\n[3] MacMillan, D. W. C. et al., <em>Science<\/em>, 2020, 368(6495), eaaz0290.<br \/>\n[4] Yamamoto, H. et al., <em>J. Am. Chem. Soc.<\/em>, 2019, 141(34), 13524\u201313532.<br \/>\n[5] Max Planck Institute for Coal Research, <em>Angew. Chem. Int. Ed.<\/em>, 2021, 60(18), 10002\u201310010.<\/p>\n<hr \/>\n<p>\uff08\u5168\u6587\u7ea63150\u5b57\uff09<\/p>\n<h2>====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n<h2>\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n<h2>\u624b\u673a\u53f7\u7801\uff1a 18301903156<\/h2>\n<h2>\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n<h2>\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n<p>===========================================================<\/p>\n<h2>\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u50ac\u5316\u5242\u76ee\u5f55<\/h2>\n<ul>\n<li>\n<h3>NT CAT 680 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u662f\u4e00\u79cd\u73af\u4fdd\u578b\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u5242\uff0c\u4e0d\u542bRoHS\u6240\u9650\u5236\u7684\u591a\u6eb4\u8054\u3001\u591a\u6eb4\u4e8c\u919a\u3001\u94c5\u3001\u6c5e\u3001\u9549\u7b49\u3001\u8f9b\u57fa\u9521\u3001\u4e01\u57fa\u9521\u3001\u57fa\u9521\u7b49\u4e5d\u7c7b\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u9002\u7528\u4e8e\u805a\u6c28\u916f\u76ae\u9769\u3001\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u4ee5\u53ca\u7845\u6a61\u80f6\u7b49\u3002<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-14 \u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u6c28\u916f\u6ce1\u6cab\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5bc6\u5c01\u80f6\u548c\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-15 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