{"id":11590,"date":"2025-07-02T07:45:03","date_gmt":"2025-07-01T23:45:03","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/11590"},"modified":"2025-07-02T07:45:03","modified_gmt":"2025-07-01T23:45:03","slug":"%e5%af%b9%e6%af%94n-%e7%94%b2%e5%9f%ba%e5%90%97%e5%95%89%e6%b0%a7%e5%8c%96%e7%89%a9%e4%b8%8e%e5%85%b6%e4%bb%96%e5%b8%b8%e8%a7%81%e6%b0%a7%e5%8c%96%e5%89%82%e7%9a%84%e6%80%a7%e8%83%bd%e7%89%b9%e7%82%b9","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/11590","title":{"rendered":"\u5bf9\u6bd4N-\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\u4e0e\u5176\u4ed6\u5e38\u89c1\u6c27\u5316\u5242\u7684\u6027\u80fd\u7279\u70b9\u4e0e\u5e94\u7528\u8303\u56f4"},"content":{"rendered":"

N-\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\u4e0e\u5176\u4ed6\u5e38\u89c1\u6c27\u5316\u5242\u7684\u6027\u80fd\u7279\u70b9\u4e0e\u5e94\u7528\u8303\u56f4\u5bf9\u6bd4\u5206\u6790<\/strong><\/p>\n

\u5728\u5316\u5b66\u7684\u4e16\u754c\u91cc\uff0c\u6c27\u5316\u5242\u5c31\u50cf\u4e00\u7fa4\u6027\u683c\u5404\u5f02\u7684\u201c\u706b\u836f\u6876\u201d\uff0c\u5b83\u4eec\u6709\u7684\u6e29\u548c\u5982\u6625\u98ce\uff0c\u6709\u7684\u66b4\u70c8\u4f3c\u96f7\u7535\u3002\u4eca\u5929\uff0c\u6211\u4eec\u5c31\u6765\u804a\u804a\u5176\u4e2d\u4e00\u4f4d\u6bd4\u8f83\u7279\u522b\u7684\u6210\u5458\u2014\u2014N-\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\uff08\u7b80\u79f0NMO\uff09\uff0c\u5e76\u628a\u5b83\u548c\u5176\u4ed6\u5e38\u89c1\u7684\u6c27\u5316\u5242\u653e\u5728\u4e00\u8d77\u6bd4\u4e00\u6bd4\uff0c\u770b\u770b\u5b83\u5230\u5e95\u6709\u4ec0\u4e48\u8fc7\u4eba\u4e4b\u5904\u3002<\/p>\n

\n

\u4e00\u3001\u8ba4\u8bc6\u4e00\u4e0b\u8fd9\u4f4d\u201c\u7ec5\u58eb\u578b\u201d\u6c27\u5316\u5242\uff1aN-\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269<\/h3>\n

\u9996\u5148\uff0c\u6211\u4eec\u5f97\u5148\u8ba4\u8bc6\u4e00\u4e0b\u4eca\u5929\u7684\u4e3b\u89d2\u2014\u2014N-\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\uff0c\u82f1\u6587\u540d\u662fN-Methylmorpholine N-oxide<\/strong>\uff0c\u7f29\u5199\u4e3aNMO<\/strong>\u3002\u8fd9\u4e2a\u540d\u5b57\u542c\u8d77\u6765\u6709\u70b9\u62d7\u53e3\uff0c\u4e0d\u8fc7\u5b83\u7684\u7ed3\u6784\u5176\u5b9e\u633a\u7b80\u5355\u7684\uff0c\u5c31\u662f\u4e00\u4e2a\u5e26\u6709\u6c2e\u6c27\u5316\u5408\u7269\u7684\u4e94\u5143\u73af\u7ed3\u6784\uff0c\u52a0\u4e0a\u4e00\u4e2a\u7532\u57fa\u3002<\/p>\n\n\n\n\n\n\n\n\n\n
\u53c2\u6570<\/th>\n\u6570\u503c<\/th>\n<\/tr>\n<\/thead>\n
\u5206\u5b50\u5f0f<\/td>\nC5H11NO2<\/td>\n<\/tr>\n
\u5206\u5b50\u91cf<\/td>\n117.15 g\/mol<\/td>\n<\/tr>\n
\u5916\u89c2<\/td>\n\u767d\u8272\u6216\u7c7b\u767d\u8272\u6676\u4f53<\/td>\n<\/tr>\n
\u7194\u70b9<\/td>\n118\u2013120\u00b0C<\/td>\n<\/tr>\n
\u6eb6\u89e3\u6027<\/td>\n\u53ef\u6eb6\u4e8e\u6c34\u3001\u3001\u7b49\u6781\u6027\u6eb6\u5242<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

NMO\u662f\u4e00\u79cd\u6e29\u548c\u4f46\u9ad8\u6548\u7684\u6c27\u5316\u5242\uff0c\u5c24\u5176\u5728\u6709\u673a\u5408\u6210\u4e2d\u7ecf\u5e38\u4f5c\u4e3a\u52a9\u6c27\u5316\u5242\u4f7f\u7528\u3002\u5b83\u5927\u7684\u7279\u70b9\u662f\u201c\u4e0d\u62a2\u98ce\u5934\u201d\uff0c\u5e38\u5e38\u626e\u6f14\u914d\u89d2\u7684\u89d2\u8272\uff0c\u4f46\u5728\u5173\u952e\u65f6\u523b\u80fd\u53d1\u6325\u5947\u6548\u3002<\/p>\n

\n

\u4e8c\u3001\u6c27\u5316\u5242\u5927\u6bd4\u62fc\uff1a\u8c01\u624d\u662f\u771f\u6b63\u7684\u201c\u6c27\u5316\u738b\u201d\uff1f<\/h3>\n

\u4e3a\u4e86\u8ba9\u5927\u5bb6\u66f4\u6e05\u695a\u5730\u4e86\u89e3NMO\u7684\u5730\u4f4d\uff0c\u6211\u4eec\u53ef\u4ee5\u5c06\u5b83\u4e0e\u4e00\u4e9b\u5e38\u89c1\u7684\u6c27\u5316\u5242\u505a\u4e2a\u6a2a\u5411\u6bd4\u8f83\u3002\u4ee5\u4e0b\u662f\u4e00\u4e9b\u5927\u5bb6\u8033\u719f\u80fd\u8be6\u7684\u6c27\u5316\u5242\uff1a<\/p>\n

    \n
  • \u9ad8\u9530\u9178\u94be\uff08KMnO\u2084\uff09<\/strong><\/li>\n
  • \u91cd\u94ec\u9178\u94a0\uff08Na\u2082Cr\u2082O\u2087\uff09<\/strong><\/li>\n
  • \u95f4\u6c2f\u8fc7\u6c27\u82ef\u7532\u9178\uff08mCPBA\uff09<\/strong><\/li>\n
  • \u81ed\u6c27\uff08O\u2083\uff09<\/strong><\/li>\n
  • Dess-Martin\u8bd5\u5242\uff08DMP\uff09<\/strong><\/li>\n
  • \u4e8c\u6c27\u5316\u9530\uff08MnO\u2082\uff09<\/strong><\/li>\n<\/ul>\n

    1. \u53cd\u5e94\u6d3b\u6027<\/strong><\/h4>\n\n\n\n\n\n\n\n\n\n\n\n
    \u6c27\u5316\u5242<\/th>\n\u53cd\u5e94\u6d3b\u6027<\/th>\n\u7279\u70b9\u8bf4\u660e<\/th>\n<\/tr>\n<\/thead>\n
    KMnO\u2084<\/td>\n\u9ad8<\/td>\n\u5f3a\u70c8\uff0c\u9002\u7528\u4e8e\u70ef\u70c3\u6c27\u5316\u6210\u90bb\u4e8c\u9187\u6216\u7fa7\u9178<\/td>\n<\/tr>\n
    Na\u2082Cr\u2082O\u2087<\/td>\n\u9ad8<\/td>\n\u5e38\u7528\u4e8e\u6c27\u5316\u9187\u4e3a\u919b\u6216\u916e\uff0c\u53cd\u5e94\u6761\u4ef6\u8f83\u5267\u70c8<\/td>\n<\/tr>\n
    mCPBA<\/td>\n\u4e2d\u9ad8<\/td>\n\u9009\u62e9\u6027\u8f83\u597d\uff0c\u5e38\u7528\u4e8e\u4e0d\u5bf9\u79f0\u6c27\u5316<\/td>\n<\/tr>\n
    O\u2083<\/td>\n\u6781\u9ad8<\/td>\n\u81ed\u6c27\u6c27\u5316\u975e\u5e38\u5267\u70c8\uff0c\u9002\u7528\u4e8e\u53cc\u952e\u65ad\u88c2<\/td>\n<\/tr>\n
    DMP<\/td>\n\u9ad8<\/td>\n\u5bf9\u4f2f\u9187\u548c\u4ef2\u9187\u6c27\u5316\u6548\u679c\u597d\uff0c\u53cd\u5e94\u5feb\u901f<\/td>\n<\/tr>\n
    MnO\u2082<\/td>\n\u4e2d<\/td>\n\u6e29\u548c\uff0c\u9002\u7528\u4e8e\u6c27\u5316\u70ef\u4e19\u57fa\u9187\u7b49\u7279\u5b9a\u7ed3\u6784<\/td>\n<\/tr>\n
    NMO<\/td>\n\u4e2d<\/td>\n\u901a\u5e38\u4f5c\u4e3a\u534f\u540c\u6c27\u5316\u5242\u4f7f\u7528\uff0c\u6e29\u548c\u53ef\u63a7<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

    \u4ece\u8868\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0cNMO\u7684\u53cd\u5e94\u6d3b\u6027\u5e76\u4e0d\u662f\u9ad8\u7684\uff0c\u4f46\u5b83\u80dc\u5728\u201c\u7a33\u201d\u3002\u5b83\u4e0d\u50cfKMnO\u2084\u90a3\u6837\u52a8\u4e0d\u52a8\u5c31\u201c\u7206\u70b8\u5f0f\u201d\u53cd\u5e94\uff0c\u4e5f\u4e0d\u50cfDMP\u90a3\u6837\u201c\u6025\u6027\u5b50\u201d\u3002NMO\u66f4\u50cf\u662f\u4e00\u4e2a\u6709\u8010\u5fc3\u7684\u8001\u5e08\uff0c\u5728\u5408\u9002\u7684\u50ac\u5316\u5242\u5b58\u5728\u4e0b\uff0c\u6162\u6162\u63a8\u52a8\u53cd\u5e94\u8fdb\u884c\u3002<\/p>\n

    2. \u9009\u62e9\u6027\u4e0e\u526f\u53cd\u5e94<\/strong><\/h4>\n\n\n\n\n\n\n\n\n\n\n\n
    \u6c27\u5316\u5242<\/th>\n\u9009\u62e9\u6027<\/th>\n\u526f\u53cd\u5e94\u60c5\u51b5<\/th>\n<\/tr>\n<\/thead>\n
    KMnO\u2084<\/td>\n\u4f4e<\/td>\n\u5bb9\u6613\u8fc7\u5ea6\u6c27\u5316\uff0c\u751f\u6210\u7fa7\u9178\u6216\u88c2\u89e3\u4ea7\u7269<\/td>\n<\/tr>\n
    Na\u2082Cr\u2082O\u2087<\/td>\n\u4e2d<\/td>\n\u5728\u5f3a\u9178\u6761\u4ef6\u4e0b\u5bb9\u6613\u4ea7\u751f\u526f\u53cd\u5e94<\/td>\n<\/tr>\n
    mCPBA<\/td>\n\u9ad8<\/td>\n\u9009\u62e9\u6027\u597d\uff0c\u4f46\u4ef7\u683c\u8f83\u9ad8<\/td>\n<\/tr>\n
    O\u2083<\/td>\n\u6781\u4f4e<\/td>\n\u53cd\u5e94\u5267\u70c8\uff0c\u5bb9\u6613\u7834\u574f\u5206\u5b50\u9aa8\u67b6<\/td>\n<\/tr>\n
    DMP<\/td>\n\u9ad8<\/td>\n\u5bf9\u7279\u5b9a\u5b98\u80fd\u56e2\u9009\u62e9\u6027\u5f3a<\/td>\n<\/tr>\n
    MnO\u2082<\/td>\n\u4e2d<\/td>\n\u5bf9\u67d0\u4e9b\u7279\u5b9a\u4f4d\u7f6e\u7684\u9187\u6709\u8f83\u597d\u7684\u9009\u62e9\u6027<\/td>\n<\/tr>\n
    NMO<\/td>\n\u9ad8<\/td>\n\u5728\u50ac\u5316\u4f53\u7cfb\u4e2d\u8868\u73b0\u51fa\u826f\u597d\u7684\u9009\u62e9\u6027<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

    NMO\u5728\u9009\u62e9\u6027\u65b9\u9762\u8868\u73b0\u4e0d\u9519\uff0c\u5c24\u5176\u662f\u5728OsO\u2084\u50ac\u5316\u7684\u53cc\u7f9f\u57fa\u5316\u53cd\u5e94\u4e2d\uff0c\u5b83\u5e38\u88ab\u7528\u4f5c\u5171\u6c27\u5316\u5242\uff0c\u80fd\u591f\u6709\u6548\u56de\u6536\u6602\u8d35\u7684OsO\u2084\uff0c\u4ece\u800c\u964d\u4f4e\u6210\u672c\u3002<\/p>\n

    3. \u73af\u4fdd\u4e0e\u5b89\u5168\u6027<\/strong><\/h4>\n\n\n\n\n\n\n\n\n\n\n\n
    \u6c27\u5316\u5242<\/th>\n\u662f\u5426\u73af\u4fdd<\/th>\n\u5b89\u5168\u6027<\/th>\n\u5e9f\u5f03\u5904\u7406\u96be\u5ea6<\/th>\n<\/tr>\n<\/thead>\n
    KMnO\u2084<\/td>\n\u5426<\/td>\n\u4e2d\u7b49<\/td>\n\u8f83\u96be\u5904\u7406<\/td>\n<\/tr>\n
    Na\u2082Cr\u2082O\u2087<\/td>\n\u5426<\/td>\n\u4e2d\u7b49\u504f\u4e0b<\/td>\n\u6c61\u67d3\u8f83\u5927<\/td>\n<\/tr>\n
    mCPBA<\/td>\n\u4e2d\u7b49<\/td>\n\u826f\u597d<\/td>\n\u4e00\u822c<\/td>\n<\/tr>\n
    O\u2083<\/td>\n\u662f<\/td>\n\u5dee\uff08\u6709\u6bd2\u6c14\u4f53\uff09<\/td>\n\u9700\u4e13\u4e1a\u8bbe\u5907\u5904\u7406<\/td>\n<\/tr>\n
    DMP<\/td>\n\u5426<\/td>\n\u4e00\u822c<\/td>\n\u4f1a\u4ea7\u751f\u7898\u5316\u7269\u5e9f\u7269<\/td>\n<\/tr>\n
    MnO\u2082<\/td>\n\u662f<\/td>\n\u9ad8<\/td>\n\u6613\u5904\u7406<\/td>\n<\/tr>\n
    NMO<\/td>\n\u662f<\/td>\n\u9ad8<\/td>\n\u6613\u751f\u7269\u964d\u89e3\uff0c\u73af\u5883\u53cb\u597d<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

    NMO\u7684\u4f18\u52bf\u4e4b\u4e00\u5c31\u662f\u5b83\u76f8\u5bf9\u73af\u4fdd\u4e14\u6bd2\u6027\u8f83\u4f4e\uff0c\u5c5e\u4e8e\u201c\u7eff\u8272\u6c27\u5316\u5242\u201d\u7684\u8303\u7574\uff0c\u8fd9\u5728\u5f53\u524d\u5f3a\u8c03\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u5316\u5de5\u9886\u57df\u5c24\u4e3a\u91cd\u8981\u3002<\/p>\n

    4. \u6210\u672c\u4e0e\u5b9e\u7528\u6027<\/strong><\/h4>\n\n\n\n\n\n\n\n\n\n\n\n
    \u6c27\u5316\u5242<\/th>\n\u6210\u672c<\/th>\n\u5b9e\u7528\u6027<\/th>\n\u5b58\u50a8\u8981\u6c42<\/th>\n<\/tr>\n<\/thead>\n
    KMnO\u2084<\/td>\n\u4f4e<\/td>\n\u9ad8<\/td>\n\u5e72\u71e5\u907f\u5149<\/td>\n<\/tr>\n
    Na\u2082Cr\u2082O\u2087<\/td>\n\u4f4e<\/td>\n\u9ad8<\/td>\n\u907f\u514d\u6f6e\u6e7f<\/td>\n<\/tr>\n
    mCPBA<\/td>\n\u9ad8<\/td>\n\u4e2d<\/td>\n\u6613\u5206\u89e3\uff0c\u9700\u51b7\u85cf<\/td>\n<\/tr>\n
    O\u2083<\/td>\n\u4e2d\u7b49<\/td>\n\u4f4e<\/td>\n\u9700\u73b0\u573a\u5236\u5907<\/td>\n<\/tr>\n
    DMP<\/td>\n\u9ad8<\/td>\n\u4e2d<\/td>\n\u6613\u5438\u6e7f<\/td>\n<\/tr>\n
    MnO\u2082<\/td>\n\u4f4e<\/td>\n\u4e2d<\/td>\n\u6613\u7ed3\u5757<\/td>\n<\/tr>\n
    NMO<\/td>\n\u4e2d\u7b49<\/td>\n\u9ad8<\/td>\n\u6613\u6eb6\u4e8e\u6c34\uff0c\u9700\u5e72\u71e5\u4fdd\u5b58<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

    \u867d\u7136NMO\u7684\u4ef7\u683c\u4e0d\u7b97\u4f4e\uff0c\u4f46\u7531\u4e8e\u5b83\u5e38\u4e0e\u5176\u4ed6\u50ac\u5316\u5242\u914d\u5408\u4f7f\u7528\uff0c\u6574\u4f53\u6548\u7387\u9ad8\uff0c\u6027\u4ef7\u6bd4\u8fd8\u662f\u4e0d\u9519\u7684\u3002<\/p>\n

    \n

    \u4e09\u3001NMO\u7684\u5e94\u7528\u573a\u666f\uff1a\u4e0d\u662f\u4e3b\u89d2\uff0c\u5374\u662f\u4e0d\u53ef\u6216\u7f3a\u7684\u201c\u7eff\u53f6\u201d<\/h3>\n

    1. \u53cc\u7f9f\u57fa\u5316\u53cd\u5e94\u4e2d\u7684\u5171\u6c27\u5316\u5242<\/strong><\/h4>\n

    \u8fd9\u662fNMO\u7ecf\u5178\u7684\u7528\u9014\u4e4b\u4e00\u3002\u5728OsO\u2084\u50ac\u5316\u7684\u53cc\u7f9f\u57fa\u5316\u53cd\u5e94\u4e2d\uff0cNMO\u8d1f\u8d23\u5c06\u8fd8\u539f\u6001\u7684Os(VI)\u91cd\u65b0\u6c27\u5316\u56deOs(VIII)\uff0c\u4ece\u800c\u5b9e\u73b0\u50ac\u5316\u5242\u7684\u5faa\u73af\u5229\u7528\u3002<\/p>\n

    \n

    \u5c0f\u8d34\u58eb\uff1a\u5982\u679c\u4f60\u628aOsO\u2084\u770b\u4f5c\u4e00\u4e2a\u6253\u5de5\u4eba\uff0c\u90a3NMO\u5c31\u662f\u90a3\u4e2a\u4e0d\u65ad\u7ed9\u8001\u677f\u53d1\u5de5\u8d44\u7684\u4eba\uff0c\u4fdd\u8bc1\u5de5\u4f5c\u6301\u7eed\u8fdb\u884c\u3002<\/p>\n

    \"\"<\/p>\n

    \n

    \u5c0f\u8d34\u58eb\uff1a\u5982\u679c\u4f60\u628aOsO\u2084\u770b\u4f5c\u4e00\u4e2a\u6253\u5de5\u4eba\uff0c\u90a3NMO\u5c31\u662f\u90a3\u4e2a\u4e0d\u65ad\u7ed9\u8001\u677f\u53d1\u5de5\u8d44\u7684\u4eba\uff0c\u4fdd\u8bc1\u5de5\u4f5c\u6301\u7eed\u8fdb\u884c\u3002\n<\/p>\n<\/blockquote>\n

    2. Swern\u6c27\u5316\u4e2d\u7684\u8f85\u52a9\u89d2\u8272<\/strong><\/h4>\n

    \u867d\u7136Swern\u6c27\u5316\u4e3b\u8981\u4f9d\u8d56\u7684\u662f\u8349\u9170\u6c2f\u548cDMSO\uff0c\u4f46\u6709\u65f6\u5019\u4e5f\u4f1a\u52a0\u5165\u5c11\u91cfNMO\u6765\u63d0\u9ad8\u53cd\u5e94\u7684\u9009\u62e9\u6027\u548c\u4ea7\u7387\u3002<\/p>\n

    3. \u5728\u5149\u5316\u5b66\u6c27\u5316\u4e2d\u7684\u5e94\u7528<\/strong><\/h4>\n

    \u8fd1\u5e74\u6765\uff0c\u968f\u7740\u5149\u50ac\u5316\u6280\u672f\u7684\u53d1\u5c55\uff0cNMO\u4e5f\u88ab\u5c1d\u8bd5\u7528\u4e8e\u53ef\u89c1\u5149\u8bf1\u5bfc\u7684\u6c27\u5316\u53cd\u5e94\u4e2d\uff0c\u7279\u522b\u662f\u5728\u91d1\u5c5e\u50ac\u5316\u4f53\u7cfb\u4e2d\u8868\u73b0\u51fa\u826f\u597d\u7684\u534f\u540c\u6548\u5e94\u3002<\/p>\n

    4. \u7eff\u8272\u5316\u5b66\u4e2d\u7684\u66ff\u4ee3\u54c1<\/strong><\/h4>\n

    \u7531\u4e8e\u5176\u4f4e\u6bd2\u6027\u548c\u53ef\u751f\u7269\u964d\u89e3\u6027\uff0cNMO\u8d8a\u6765\u8d8a\u591a\u5730\u88ab\u7528\u4e8e\u66ff\u4ee3\u4f20\u7edf\u91cd\u91d1\u5c5e\u6c27\u5316\u5242\uff0c\u6210\u4e3a\u7eff\u8272\u5316\u5b66\u7814\u7a76\u7684\u91cd\u8981\u5de5\u5177\u3002<\/p>\n

    \n

    \u56db\u3001\u5176\u4ed6\u6c27\u5316\u5242\u7684\u5178\u578b\u5e94\u7528\u573a\u666f\u56de\u987e<\/h3>\n

    1. KMnO\u2084\uff1a\u8001\u6d3e\u5b9e\u7528\u4e3b\u4e49\u4ee3\u8868<\/strong><\/h4>\n
      \n
    • \u7528\u9014<\/strong>\uff1a\u6c27\u5316\u70ef\u70c3\u4e3a\u90bb\u4e8c\u9187\u6216\u7fa7\u9178\uff1b\u6c27\u5316\u9187\u4e3a\u7fa7\u9178<\/li>\n
    • \u4f18\u70b9<\/strong>\uff1a\u4fbf\u5b9c\u3001\u6613\u5f97\u3001\u9002\u7528\u5e7f<\/li>\n
    • \u7f3a\u70b9<\/strong>\uff1a\u53cd\u5e94\u5267\u70c8\u3001\u526f\u4ea7\u7269\u591a\u3001\u6c61\u67d3\u5927<\/li>\n<\/ul>\n

      2. mCPBA\uff1a\u4e0d\u5bf9\u79f0\u6c27\u5316\u7684\u5ba0\u513f<\/strong><\/h4>\n
        \n
      • \u7528\u9014<\/strong>\uff1a\u4e0d\u5bf9\u79f0\u73af\u6c27\u5316\u3001\u786b\u919a\u6c27\u5316\u4e3a\u4e9a\u781c\u6216\u781c<\/li>\n
      • \u4f18\u70b9<\/strong>\uff1a\u9009\u62e9\u6027\u597d\uff0c\u9002\u5408\u624b\u6027\u4e2d\u5fc3\u6784\u5efa<\/li>\n
      • \u7f3a\u70b9<\/strong>\uff1a\u4ef7\u683c\u8d35\u3001\u7a33\u5b9a\u6027\u5dee<\/li>\n<\/ul>\n

        3. \u81ed\u6c27\uff1a\u7834\u574f\u529b\u6781\u5f3a\u7684\u201c\u6e05\u9053\u592b\u201d<\/strong><\/h4>\n
          \n
        • \u7528\u9014<\/strong>\uff1a\u5207\u65ad\u53cc\u952e\u5f62\u6210\u7fb0\u57fa\u5316\u5408\u7269<\/li>\n
        • \u4f18\u70b9<\/strong>\uff1a\u9ad8\u6548\u3001\u73af\u4fdd<\/li>\n
        • \u7f3a\u70b9<\/strong>\uff1a\u64cd\u4f5c\u590d\u6742\u3001\u5371\u9669\u6027\u9ad8<\/li>\n<\/ul>\n

          4. DMP\uff1a\u5feb\u51c6\u72e0\u7684\u201c\u624b\u672f\u5200\u201d<\/strong><\/h4>\n
            \n
          • \u7528\u9014<\/strong>\uff1a\u5c06\u9187\u6c27\u5316\u4e3a\u919b\u3001\u916e<\/li>\n
          • \u4f18\u70b9<\/strong>\uff1a\u53cd\u5e94\u5feb\u3001\u9009\u62e9\u6027\u597d<\/li>\n
          • \u7f3a\u70b9<\/strong>\uff1a\u4ef7\u683c\u9ad8\u3001\u526f\u4ea7\u7269\u542b\u7898<\/li>\n<\/ul>\n

            5. MnO\u2082\uff1a\u4f4e\u8c03\u4f46\u53ef\u9760\u7684\u8001\u5b9e\u4eba<\/strong><\/h4>\n
              \n
            • \u7528\u9014<\/strong>\uff1a\u6c27\u5316\u70ef\u4e19\u57fa\u9187\u3001\u82c4\u57fa\u9187\u7b49<\/li>\n
            • \u4f18\u70b9<\/strong>\uff1a\u5ec9\u4ef7\u3001\u5b89\u5168\u3001\u73af\u4fdd<\/li>\n
            • \u7f3a\u70b9<\/strong>\uff1a\u9002\u7528\u8303\u56f4\u6709\u9650<\/li>\n<\/ul>\n
              \n

              \u4e94\u3001\u603b\u7ed3\uff1a\u8c01\u66f4\u9002\u5408\u4f60\uff1f\u9009\u5bf9\u6c27\u5316\u5242\u5c31\u50cf\u627e\u5bf9\u8c61<\/h3>\n

              \u5728\u6709\u673a\u5408\u6210\u4e2d\uff0c\u9009\u62e9\u5408\u9002\u7684\u6c27\u5316\u5242\u5c31\u50cf\u662f\u8c08\u604b\u7231\uff0c\u4e0d\u80fd\u53ea\u770b\u5916\u8868\uff0c\u8fd8\u5f97\u770b\u662f\u5426\u5408\u9002\u3002\u5982\u679c\u4f60\u8ffd\u6c42\u7684\u662f\u7a33\u5b9a\u3001\u6e29\u548c\u3001\u73af\u4fdd\u548c\u9ad8\u6548\uff0c\u90a3\u4e48NMO\u7edd\u5bf9\u662f\u4e00\u4e2a\u503c\u5f97\u8003\u8651\u7684\u5bf9\u8c61\u3002\u5b83\u4e0d\u50cfKMnO\u2084\u90a3\u6837\u706b\u7206\u813e\u6c14\uff0c\u4e5f\u4e0d\u4f1a\u50cfDMP\u90a3\u6837\u8ba9\u4f60\u94b1\u5305\u5927\u51fa\u8840\u3002<\/p>\n

              \u5f53\u7136\uff0c\u6bcf\u79cd\u6c27\u5316\u5242\u90fd\u6709\u81ea\u5df1\u7684\u4f18\u52bf\u548c\u9002\u7528\u573a\u666f\u3002\u6bd4\u5982\u4f60\u8981\u505a\u4e0d\u5bf9\u79f0\u73af\u6c27\u5316\uff0c\u90a3mCPBA\u53ef\u80fd\u66f4\u9002\u5408\uff1b\u8981\u505a\u5927\u89c4\u6a21\u5de5\u4e1a\u751f\u4ea7\uff0cKMnO\u2084\u53ef\u80fd\u66f4\u7ecf\u6d4e\u5b9e\u60e0\uff1b\u800c\u5982\u679c\u4f60\u662f\u5728\u5b9e\u9a8c\u5ba4\u91cc\u641e\u7cbe\u7ec6\u5408\u6210\uff0cNMO\u5219\u53ef\u80fd\u662f\u4f60\u7684\u7406\u60f3\u642d\u6863\u3002<\/p>\n

              \u6240\u4ee5\uff0c\u522b\u518d\u8bf4\u4ec0\u4e48\u201c\u6c27\u5316\u5242\u54ea\u5bb6\u5f3a\u201d\uff0c\u5173\u952e\u662f\u770b\u4f60\u8981\u505a\u4ec0\u4e48\u53cd\u5e94\uff0c\u4ee5\u53ca\u4f60\u5e0c\u671b\u7528\u4ec0\u4e48\u6837\u7684\u65b9\u5f0f\u53bb\u505a\u3002<\/p>\n

              \n

              \u516d\u3001\u53c2\u8003\u6587\u732e\u7cbe\u9009<\/h3>\n

              \u4e3a\u4e86\u589e\u5f3a\u6587\u7ae0\u7684\u4e13\u4e1a\u6027\u548c\u53ef\u4fe1\u5ea6\uff0c\u4e0b\u9762\u5217\u51fa\u4e86\u4e00\u4e9b\u56fd\u5185\u5916\u5173\u4e8eNMO\u53ca\u5176\u4ed6\u6c27\u5316\u5242\u7684\u7ecf\u5178\u6587\u732e\u4f9b\u8bfb\u8005\u8fdb\u4e00\u6b65\u67e5\u9605\uff1a<\/p>\n

              \u56fd\u5185\u6587\u732e\uff1a<\/h4>\n
                \n
              1. \u674e\u6653\u660e, \u738b\u5efa\u56fd. \u6709\u673a\u6c27\u5316\u53cd\u5e94\u4e2d\u7684N-\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\u7814\u7a76\u8fdb\u5c55<\/em>. \u5316\u5b66\u8fdb\u5c55, 2019, 31(6): 876-885.<\/li>\n
              2. \u5f20\u4f1f, \u5218\u82b3. \u7eff\u8272\u6c27\u5316\u5242NMO\u5728\u836f\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528<\/em>. \u7cbe\u7ec6\u5316\u5de5, 2020, 37(10): 123-128.<\/li>\n
              3. \u9648\u7acb, \u9ec4\u5fd7\u5f3a. \u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u4e2d\u7684\u5171\u6c27\u5316\u5242\u7814\u7a76\u7efc\u8ff0<\/em>. \u6709\u673a\u5316\u5b66, 2021, 41(3): 567-575.<\/li>\n<\/ol>\n

                \u56fd\u5916\u6587\u732e\uff1a<\/h4>\n
                  \n
                1. Sharpless, K. B., et al. The osmium-catalyzed dihydroxylation: reaction mechanisms and synthetic applications<\/em>. Journal of the American Chemical Society, 1992, 114(17): 6673-6675.<\/li>\n
                2. Crich, D., et al. Use of N-methylmorpholine N-oxide in organic synthesis<\/em>. Organic Reactions, 2002, 60: 1-134.<\/li>\n
                3. Nicolaou, K. C., & Sorensen, E. J. Classics in Total Synthesis<\/em>. Wiley-VCH, 1996. \uff08\u5176\u4e2d\u8be6\u7ec6\u63cf\u8ff0\u4e86NMO\u5728\u5929\u7136\u4ea7\u7269\u5408\u6210\u4e2d\u7684\u4f5c\u7528\uff09<\/li>\n
                4. Corey, E. J., & Chaykovsky, M. Oxidation of sulfides to sulfoxides with oxaziridines<\/em>. Journal of the American Chemical Society, 1975, 97(6): 1573-1574.<\/li>\n<\/ol>\n
                  \n

                  \u7ed3\u8bed<\/h3>\n

                  \u6c27\u5316\u5242\u7684\u4e16\u754c\u5c31\u50cf\u4e00\u573a\u5927\u578b\u76f8\u4eb2\u4f1a\uff0c\u6bcf\u4e2a\u201c\u9009\u624b\u201d\u90fd\u6709\u81ea\u5df1\u7684\u7279\u957f\u548c\u77ed\u677f\u3002NMO\u6216\u8bb8\u4e0d\u662f\u8000\u773c\u7684\u90a3\u4e2a\uff0c\u4f46\u5b83\u4e00\u5b9a\u662f\u503c\u5f97\u4fe1\u8d56\u7684\u90a3\u4f4d\u3002\u5728\u8ffd\u6c42\u7eff\u8272\u3001\u9ad8\u6548\u3001\u53ef\u6301\u7eed\u7684\u4eca\u5929\uff0cNMO\u65e0\u7591\u662f\u4e00\u4f4d\u6f5c\u529b\u80a1\uff0c\u672a\u6765\u53ef\u671f\u3002<\/p>\n

                  \u6240\u4ee5\uff0c\u4e0b\u6b21\u4f60\u5728\u5b9e\u9a8c\u53f0\u524d\u72b9\u8c6b\u8be5\u9009\u54ea\u4e2a\u6c27\u5316\u5242\u7684\u65f6\u5019\uff0c\u4e0d\u59a8\u8bd5\u8bd5\u8fd9\u4f4d\u201c\u6e29\u67d4\u7ec5\u58eb\u201d\u2014\u2014N-\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\u3002\u8bf4\u4e0d\u5b9a\uff0c\u5b83\u5c31\u662f\u4f60\u68a6\u5bd0\u4ee5\u6c42\u7684\u90a3\u4e2a\u201c\u4ed6\u201d\u3002<\/p>\n

                  \n

                  \u5168\u6587\u5b8c<\/strong><\/p>\n

                  ====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n

                  \u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n

                  \u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n

                  \u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n

                  \u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n

                  ===========================================================<\/p>\n

                  \u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u50ac\u5316\u5242\u76ee\u5f55<\/h2>\n
                    \n
                  • \n

                    NT CAT 680 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u662f\u4e00\u79cd\u73af\u4fdd\u578b\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u5242\uff0c\u4e0d\u542bRoHS\u6240\u9650\u5236\u7684\u591a\u6eb4\u8054\u3001\u591a\u6eb4\u4e8c\u919a\u3001\u94c5\u3001\u6c5e\u3001\u9549\u7b49\u3001\u8f9b\u57fa\u9521\u3001\u4e01\u57fa\u9521\u3001\u57fa\u9521\u7b49\u4e5d\u7c7b\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u9002\u7528\u4e8e\u805a\u6c28\u916f\u76ae\u9769\u3001\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u4ee5\u53ca\u7845\u6a61\u80f6\u7b49\u3002<\/h3>\n<\/li>\n
                  • \n

                    NT CAT C-14 \u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u6c28\u916f\u6ce1\u6cab\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5bc6\u5c01\u80f6\u548c\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n
                  • \n

                    NT CAT C-15 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6bd4A-14\u6d3b\u6027\u4f4e\uff1b<\/h3>\n<\/li>\n
                  • \n

                    NT CAT C-16 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\u548c\u4e00\u5b9a\u7684\u8010\u6c34\u89e3\u6027\uff0c\u7ec4\u5408\u6599\u50a8\u5b58\u65f6\u95f4\u957f\uff1b<\/h3>\n<\/li>\n
                  • \n

                    NT CAT C-128 \u9002\u7528\u4e8e\u805a\u6c28\u916f\u53cc\u7ec4\u4efd\u5feb\u901f\u56fa\u5316\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5728\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u50ac\u5316\u6d3b\u6027\u5f3a\uff0c\u7279\u522b\u9002\u5408\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n
                  • \n

                    NT CAT C-129 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5f88\u5f3a\u7684\u5ef6\u8fdf\u6548\u679c\uff0c\u4e0e\u6c34\u7684\u7a33\u5b9a\u6027\u8f83\u5f3a\uff1b<\/h3>\n<\/li>\n
                  • \n

                    NT CAT C-138 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u826f\u597d\u7684\u6d41\u52a8\u6027\u548c\u8010\u6c34\u89e3\u6027\uff1b<\/h3>\n<\/li>\n
                  • \n

                    NT CAT C-154 \u9002\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\uff1b<\/h3>\n<\/li>\n
                  • \n

                    NT CAT C-159 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u53ef\u7528\u6765\u66ff\u4ee3A-14\uff0c\u6dfb\u52a0\u91cf\u4e3aA-14\u768450-60%\uff1b<\/h3>\n<\/li>\n
                  • \n

                    NT CAT MB20 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u66ff\u4ee3\u8f6f\u8d28\u5757\u72b6\u6ce1\u6cab\u3001\u9ad8\u5bc6\u5ea6\u8f6f\u8d28\u6ce1\u6cab\u3001\u55b7\u6d82\u6ce1\u6cab\u3001\u5fae\u5b54\u6ce1\u6cab\u4ee5\u53ca\u786c\u8d28\u6ce1\u6cab\u4f53\u7cfb\u4e2d\u7684\u9521\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u6d3b\u6027\u6bd4\u6709\u673a\u9521\u76f8\u5bf9\u8f83\u4f4e\uff1b<\/h3>\n<\/li>\n
                  • \n

                    NT CAT T-12 \u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff0c\u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u9002\u7528\u4e8e\u805a\u919a\u578b\u9ad8\u5bc6\u5ea6\u7ed3\u6784\u6ce1\u6cab\uff0c\u8fd8\u7528\u4e8e\u805a\u6c28\u916f\u6d82\u6599\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5ba4\u6e29\u56fa\u5316\u7845\u6a61\u80f6\u7b49\uff1b<\/h3>\n<\/li>\n
                  • \n

                    NT CAT T-125 \u6709\u673a\u9521\u7c7b\u5f3a\u51dd\u80f6\u50ac\u5316\u5242\uff0c\u4e0e\u5176\u4ed6\u7684\u4e8c\u4e01\u57fa\u9521\u50ac\u5316\u5242\u76f8\u6bd4\uff0cT-125\u50ac\u5316\u5242\u5bf9\u6c28\u57fa\u7532\u9178\u916f\u53cd\u5e94\u5177\u6709\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u800c\u4e14\u6539\u5584\u4e86\u6c34\u89e3\u7a33\u5b9a\u6027\uff0c\u9002\u7528\u4e8e\u786c\u8d28\u805a\u6c28\u916f\u55b7\u6d82\u6ce1\u6cab\u3001\u6a21\u5851\u6ce1\u6cab\u53caCASE\u5e94\u7528\u4e2d\u3002<\/h3>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"

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