{"id":13024,"date":"2025-07-23T10:43:25","date_gmt":"2025-07-23T02:43:25","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/13024"},"modified":"2025-07-23T10:43:25","modified_gmt":"2025-07-23T02:43:25","slug":"dbu%e4%ba%8c%e6%b0%ae%e6%9d%82%e4%ba%8c%e7%8e%af%e5%9c%a8%e5%8a%a0%e6%88%90%e5%8f%8d%e5%ba%94%e3%80%81%e8%81%9a%e5%90%88%e5%8f%8d%e5%ba%94%e5%92%8c%e5%82%ac%e5%8c%96%e8%81%9a%e5%90%88%e4%b8%ad","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/13024","title":{"rendered":"DBU\u4e8c\u6c2e\u6742\u4e8c\u73af\u5728\u52a0\u6210\u53cd\u5e94\u3001\u805a\u5408\u53cd\u5e94\u548c\u50ac\u5316\u805a\u5408\u4e2d\u7684\u5b9e\u8df5\u5e94\u7528"},"content":{"rendered":"

DBU\u2014\u2014\u5168\u540d1,8-\u4e8c\u6c2e\u6742\u4e8c\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff081,8-Diazabicyclo[5.4.0]undec-7-ene\uff09\uff0c\u8fd9\u4e2a\u540d\u5b57\u542c\u8d77\u6765\u50cf\u662f\u5316\u5b66\u5b9e\u9a8c\u5ba4\u91cc\u67d0\u4e2a\u201c\u51b7\u9762\u5b66\u9738\u201d\u7684\u4ee3\u53f7\uff0c\u5176\u5b9e\u5b83\u662f\u4e2a\u6027\u683c\u76f8\u5f53\u6d3b\u6cfc\u7684\u5bb6\u4f19\u3002\u522b\u770b\u5b83\u5206\u5b50\u5f0f\u7b80\u5355\uff08C9H16N2\uff09\uff0c\u7ed3\u6784\u50cf\u4e2a\u88ab\u538b\u6241\u7684\u8774\u8776\u7ed3\uff0c\u4f46\u5b83\u5728\u6709\u673a\u5408\u6210\u3001\u9ad8\u5206\u5b50\u5316\u5b66\u548c\u50ac\u5316\u9886\u57df\u91cc\u53ef\u662f\u4e2a\u201c\u591a\u9762\u624b\u201d\uff0c\u5c24\u5176\u5728\u52a0\u6210\u53cd\u5e94\u3001\u805a\u5408\u53cd\u5e94\u548c\u50ac\u5316\u805a\u5408\u4e2d\uff0c\u582a\u79f0\u201c\u5316\u5b66\u754c\u7684\u745e\u58eb\u519b\u5200\u201d\u3002<\/p>\n

\u4eca\u5929\u54b1\u5c31\u804a\u804aDBU\u8fd9\u4f4d\u201c\u5316\u5b66\u754c\u8001\u70ae\u513f\u201d\u662f\u5982\u4f55\u5728\u5b9e\u9a8c\u5ba4\u548c\u5de5\u4e1a\u754c\u6df7\u5f97\u98ce\u751f\u6c34\u8d77\u7684\u3002\u4e0d\u8bb2\u9ad8\u6df1\u672f\u8bed\uff0c\u4e0d\u6446\u67b6\u5b50\uff0c\u54b1\u4eec\u5c31\u5f53\u662f\u8336\u9986\u91cc\u5520\u55d1\uff0c\u8fb9\u559d\u8fb9\u804a\u3002<\/p>\n

\n

\u4e00\u3001DBU\u662f\u8c01\uff1f\u5148\u6765\u4e2a\u201c\u81ea\u6211\u4ecb\u7ecd\u201d<\/h3>\n

DBU\u65e9\u662f\u4e0a\u4e16\u7eaa70\u5e74\u4ee3\u7531\u5fb7\u56fd\u5316\u5b66\u5bb6Karl Dimroth\u5408\u6210\u7684\uff0c\u5b83\u662f\u4e00\u79cd\u65e0\u8272\u81f3\u6de1\u9ec4\u8272\u6db2\u4f53\uff0c\u78b1\u6027\u5f88\u5f3a\uff08pKa\u7ea612\uff09\uff0c\u6bd4\u4e09\u4e59\u80fa\u8fd8\u731b\uff0c\u4f46\u4e0d\u50cf\u6c22\u6c27\u5316\u94a0\u90a3\u6837\u201c\u66b4\u813e\u6c14\u201d\uff0c\u5b83\u6e29\u548c\u53c8\u9ad8\u6548\uff0c\u7279\u522b\u9002\u5408\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u5e72\u6d3b\u513f\u3002<\/p>\n

\u4ea7\u54c1\u53c2\u6570\u4e00\u89c8\u8868\uff08\u5b9e\u9a8c\u5ba4\u5e38\u7528\u89c4\u683c\uff09\uff1a<\/strong><\/p>\n\n\n\n\n\n\n\n\n\n\n\n\n
\u53c2\u6570\u540d\u79f0<\/th>\n\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n
\u5206\u5b50\u5f0f<\/td>\nC9H16N2<\/td>\n<\/tr>\n
\u5206\u5b50\u91cf<\/td>\n152.24 g\/mol<\/td>\n<\/tr>\n
\u5916\u89c2<\/td>\n\u65e0\u8272\u81f3\u6de1\u9ec4\u8272\u900f\u660e\u6db2\u4f53<\/td>\n<\/tr>\n
\u6cb8\u70b9<\/td>\n258\u2013260\u00b0C<\/td>\n<\/tr>\n
\u5bc6\u5ea6\uff0825\u00b0C\uff09<\/td>\n0.92\u20130.94 g\/cm\u00b3<\/td>\n<\/tr>\n
pKa\uff08\u5171\u8f6d\u9178\uff09<\/td>\n~11.5\u201312.0\uff08\u5728\u6c34\/\u4e2d\uff09<\/td>\n<\/tr>\n
\u6eb6\u89e3\u6027<\/td>\n\u6613\u6eb6\u4e8e\u6c34\u3001\u3001\u3001DMF\u7b49\u6781\u6027\u6eb6\u5242<\/td>\n<\/tr>\n
\u7a33\u5b9a\u6027<\/td>\n\u5e38\u6e29\u7a33\u5b9a\uff0c\u907f\u5149\u5bc6\u5c01\u4fdd\u5b58<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4f60\u770b\uff0c\u8fd9\u53c2\u6570\u8868\u662f\u4e0d\u662f\u6709\u70b9\u50cf\u7b80\u5386\uff1f\u5b66\u5386\uff08\u5206\u5b50\u91cf\uff09\u4e0d\u9ad8\uff0c\u4f46\u6280\u80fd\u70b9\u62c9\u6ee1\uff0c\u5c24\u5176\u64c5\u957f\u201c\u62c9\u7535\u5b50\u201d\u548c\u201c\u63a8\u8d28\u5b50\u201d\uff0c\u662f\u4e2a\u5178\u578b\u7684\u201c\u78b1\u6027\u884c\u52a8\u6d3e\u201d\u3002<\/p>\n

\n

\u4e8c\u3001\u52a0\u6210\u53cd\u5e94\u4e2d\u7684\u201c\u52a9\u653b\u738b\u201d<\/h3>\n

DBU\u64c5\u957f\u7684\uff0c\u5c31\u662f\u5f53\u201c\u50ac\u5316\u5242\u5c0f\u52a9\u624b\u201d\u2014\u2014\u5c24\u5176\u662f\u5728Michael\u52a0\u6210\u3001Mannich\u53cd\u5e94\u3001\u4eb2\u6838\u53d6\u4ee3\u8fd9\u4e9b\u573a\u5408\u91cc\uff0c\u5b83\u4e0d\u62a2\u4e3b\u89d2\u98ce\u5934\uff0c\u4f46\u80fd\u8ba9\u53cd\u5e94\u901f\u5ea6\u63d0\u5347\u597d\u51e0\u500d\u3002<\/p>\n

\u4e3e\u4e2a\u4f8b\u5b50\uff1a\u4f60\u8ba9\u4e00\u4e2a\u03b1,\u03b2-\u4e0d\u9971\u548c\u7fb0\u57fa\u5316\u5408\u7269\u548c\u4e00\u4e2a\u4eb2\u6838\u8bd5\u5242\uff08\u6bd4\u5982\u80fa\u6216\u786b\u9187\uff09\u78b0\u5934\uff0c\u5b83\u4eec\u672c\u6765\u78e8\u78e8\u5527\u5527\u534a\u5929\u4e0d\u52a8\uff0cDBU\u4e00\u6765\uff0c\u7acb\u9a6c\u558a\u4e00\u53e5\uff1a\u201c\u5144\u5f1f\u4eec\uff0c\u522b\u5bb3\u7f9e\uff0c\u4e0a\u554a\uff01\u201d\u7136\u540e\u53cd\u5e94\u5c31\u55d6\u5730\u5b8c\u6210\u4e86\u3002<\/p>\n

\u4e3a\u5565\uff1f\u56e0\u4e3aDBU\u80fd\u5feb\u901f\u62d4\u6389\u4eb2\u6838\u8bd5\u5242\u4e0a\u7684\u8d28\u5b50\uff0c\u8ba9\u5b83\u53d8\u6210\u66f4\u5f3a\u7684\u201c\u8fdb\u653b\u8005\u201d\uff0c\u8fd8\u80fd\u7a33\u5b9a\u4e2d\u95f4\u4f53\uff0c\u9632\u6b62\u526f\u53cd\u5e94\u3002\u8fd9\u5c31\u50cf\u4f60\u6253\u6e38\u620f\u65f6\uff0cDBU\u662f\u90a3\u4e2a\u5e2e\u4f60\u52a0\u8840\u3001\u63d0\u901f\u3001\u8fd8\u63d0\u9192\u4f60\u522b\u8d70\u9519\u8def\u7684\u961f\u53cb\u3002<\/p>\n

\u7ecf\u5178\u6848\u4f8b\uff1aDBU\u50ac\u5316\u786b\u9187-Michael\u52a0\u6210<\/strong><\/p>\n\n\n\n\n\n\n
\u53cd\u5e94\u7c7b\u578b<\/th>\nDBU\u7528\u91cf\uff08mol%\uff09<\/th>\n\u53cd\u5e94\u65f6\u95f4<\/th>\n\u4ea7\u7387\uff08%\uff09<\/th>\n\u5907\u6ce8<\/th>\n<\/tr>\n<\/thead>\n
\u786b\u9187 + \u4e19\u70ef\u9178\u916f<\/td>\n5\u201310<\/td>\n1\u20133 h<\/td>\n85\u201395<\/td>\n\u5ba4\u6e29\uff0c\u65e0\u9700\u91d1\u5c5e\u50ac\u5316\u5242<\/td>\n<\/tr>\n
\u80fa + \u785d\u57fa\u70ef\u70c3<\/td>\n10<\/td>\n2 h<\/td>\n90<\/td>\n\u9002\u7528\u4e8e\u836f\u7269\u4e2d\u95f4\u4f53\u5408\u6210<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4f60\u770b\uff0cDBU\u4e0d\u4ec5\u9ad8\u6548\uff0c\u8fd8\u73af\u4fdd\u2014\u2014\u4e0d\u4f9d\u8d56\u91cd\u91d1\u5c5e\uff0c\u7b26\u5408\u7eff\u8272\u5316\u5b66\u6f6e\u6d41\u3002\u96be\u602a\u73b0\u5728\u5f88\u591a\u5236\u836f\u516c\u53f8\u90fd\u628a\u5b83\u5f53\u201c\u4eb2\u513f\u5b50\u201d\u4f9b\u7740\u3002<\/p>\n

\n

\u4e09\u3001\u805a\u5408\u53cd\u5e94\u91cc\u7684\u201c\u8282\u594f\u5927\u5e08\u201d<\/h3>\n

DBU\u5728\u805a\u5408\u53cd\u5e94\u91cc\uff0c\u53ef\u4e0d\u662f\u6253\u9171\u6cb9\u7684\u3002\u5b83\u7279\u522b\u64c5\u957f\u50ac\u5316\u5f00\u73af\u805a\u5408\uff08ROP\uff09\uff0c\u5c24\u5176\u662f\u73af\u72b6\u5355\u4f53\uff0c\u6bd4\u5982\u03b5-\u5df1\u5185\u916f\uff08\u03b5-CL\uff09\u3001\u4e19\u4ea4\u916f\uff08LA\uff09\u3001\u78b3\u9178\u916f\u8fd9\u4e9b\u3002\u5b83\u4e0d\u50cf\u4f20\u7edf\u91d1\u5c5e\u50ac\u5316\u5242\u90a3\u6837\u5bb9\u6613\u6b8b\u7559\u91d1\u5c5e\u79bb\u5b50\uff08\u8fd9\u5bf9\u533b\u7528\u6750\u6599\u53ef\u662f\u5927\u5fcc\uff09\uff0cDBU\u50ac\u5316\u5b8c\u8fd8\u80fd\u8f7b\u677e\u6d17\u6389\uff0c\u5e72\u51c0\u5229\u843d\u3002<\/p>\n

\u6bd4\u5982\uff0c\u4f60\u8ba9\u03b5-\u5df1\u5185\u916f\u5728DBU\u50ac\u5316\u4e0b\u805a\u5408\uff0c\u5b83\u5c31\u50cf\u4e2aDJ\uff0c\u63a7\u5236\u7740\u8282\u594f\uff0c\u8ba9\u5355\u4f53\u4e00\u4e2a\u4e2a\u4e56\u4e56\u6392\u961f\u5f62\u6210\u805a\u5df1\u5185\u916f\uff08PCL\uff09\uff0c\u5206\u5b50\u91cf\u5206\u5e03\u8fd8\u7a84\uff0c\u6027\u80fd\u7a33\u5b9a\u3002<\/p>\n

DBU\u50ac\u5316\u03b5-\u5df1\u5185\u916f\u5f00\u73af\u805a\u5408\u6570\u636e\u8868\uff1a<\/strong><\/p>\n\n\n\n\n\n\n\n
DBU\u7528\u91cf\uff08mol%\uff09<\/th>\n\u6e29\u5ea6\uff08\u00b0C\uff09<\/th>\n\u65f6\u95f4\uff08h\uff09<\/th>\nMn\uff08\u7406\u8bba\/\u5b9e\u6d4b\uff09<\/th>\n\u5206\u5b50\u91cf\u5206\u5e03\u0110<\/th>\n\u5e94\u7528\u65b9\u5411<\/th>\n<\/tr>\n<\/thead>\n
1<\/td>\n110<\/td>\n24<\/td>\n5,000 \/ 4,800<\/td>\n1.15<\/td>\n\u53ef\u964d\u89e3\u7f1d\u5408\u7ebf<\/td>\n<\/tr>\n
5<\/td>\n80<\/td>\n12<\/td>\n10,000 \/ 9,600<\/td>\n1.20<\/td>\n\u533b\u7528\u690d\u5165\u6750\u6599<\/td>\n<\/tr>\n
10<\/td>\n60<\/td>\n6<\/td>\n20,000 \/ 19,200<\/td>\n1.25<\/td>\n\u836f\u7269\u7f13\u91ca\u8f7d\u4f53<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u6ce8\u610f\u770b\uff0cDBU\u7528\u91cf\u8d8a\u5c11\uff0c\u6e29\u5ea6\u8d8a\u9ad8\uff0c\u805a\u5408\u8d8a\u6162\u4f46\u66f4\u53ef\u63a7\uff1b\u7528\u91cf\u591a\u70b9\uff0c\u53cd\u5e94\u5feb\uff0c\u9002\u5408\u5de5\u4e1a\u5316\u751f\u4ea7\u3002\u8fd9\u5c31\u50cf\u7092\u83dc\uff0c\u706b\u5019\u548c\u8c03\u6599\u6bd4\u4f8b\u51b3\u5b9a\u6210\u8d25\u3002<\/p>\n

\n

\u56db\u3001\u50ac\u5316\u805a\u5408\u4e2d\u7684\u201c\u9690\u5f62\u51a0\u519b\u201d<\/h3>\n

DBU\u725b\u7684\u5730\u65b9\uff0c\u5176\u5b9e\u662f\u5b83\u5728\u201c\u50ac\u5316\u805a\u5408\u201d\u4e2d\u7684\u201c\u9690\u8eab\u80fd\u529b\u201d\u3002\u5b83\u4e0d\u50cf\u9521\u7c7b\u50ac\u5316\u5242\uff08\u6bd4\u5982\u8f9b\u9178\u4e9a\u9521\uff09\u90a3\u6837\u4f1a\u6b8b\u7559\u5728\u805a\u5408\u7269\u91cc\uff0c\u5f71\u54cd\u751f\u7269\u76f8\u5bb9\u6027\u3002DBU\u672c\u8eab\u662f\u6709\u673a\u78b1\uff0c\u53cd\u5e94\u5b8c\u57fa\u672c\u4e0d\u6b8b\u7559\uff0c\u5c31\u7b97\u6709\uff0c\u4e5f\u80fd\u7528\u9178\u6d17\u8f7b\u677e\u53bb\u6389\u3002<\/p>\n

\u8fd9\u5728\u751f\u7269\u533b\u7528\u9ad8\u5206\u5b50\u9886\u57df\u7b80\u76f4\u662f\u6551\u547d\u7a3b\u8349\u3002\u6bd4\u5982\u805a\u4e73\u9178\uff08PLA\uff09\u7528\u4e8e\u53ef\u5438\u6536\u7f1d\u5408\u7ebf\u3001\u9aa8\u9489\u3001\u652f\u67b6\u7b49\uff0cDBU\u50ac\u5316\u51fa\u6765\u7684PLA\u7eaf\u5ea6\u9ad8\u3001\u65e0\u6bd2\uff0cFDA\u90fd\u70b9\u5934\u8ba4\u53ef\u3002<\/p>\n

\"\"<\/p>\n

\u8fd9\u5728\u751f\u7269\u533b\u7528\u9ad8\u5206\u5b50\u9886\u57df\u7b80\u76f4\u662f\u6551\u547d\u7a3b\u8349\u3002\u6bd4\u5982\u805a\u4e73\u9178\uff08PLA\uff09\u7528\u4e8e\u53ef\u5438\u6536\u7f1d\u5408\u7ebf\u3001\u9aa8\u9489\u3001\u652f\u67b6\u7b49\uff0cDBU\u50ac\u5316\u51fa\u6765\u7684PLA\u7eaf\u5ea6\u9ad8\u3001\u65e0\u6bd2\uff0cFDA\u90fd\u70b9\u5934\u8ba4\u53ef\u3002<\/p>\n

DBU vs \u4f20\u7edf\u50ac\u5316\u5242\uff08\u8f9b\u9178\u4e9a\u9521\uff09\u5bf9\u6bd4\u8868\uff1a<\/strong><\/p>\n\n\n\n\n\n\n\n\n\n
\u6307\u6807<\/th>\nDBU\u50ac\u5316<\/th>\n\u8f9b\u9178\u4e9a\u9521\u50ac\u5316<\/th>\n<\/tr>\n<\/thead>\n
\u50ac\u5316\u6548\u7387<\/td>\n\u9ad8\uff08\u5ba4\u6e29\u5373\u53ef\u542f\u52a8\uff09<\/td>\n\u4e2d\u7b49\uff08\u9700\u52a0\u70ed\uff09<\/td>\n<\/tr>\n
\u91d1\u5c5e\u6b8b\u7559<\/td>\n\u65e0<\/td>\n\u6709\uff08\u9700\u540e\u5904\u7406\u53bb\u9664\uff09<\/td>\n<\/tr>\n
\u751f\u7269\u76f8\u5bb9\u6027<\/td>\n\u6781\u4f73<\/td>\n\u4e00\u822c\uff08\u53ef\u80fd\u81f4\u708e\uff09<\/td>\n<\/tr>\n
\u5de5\u4e1a\u653e\u5927\u96be\u5ea6<\/td>\n\u4f4e<\/td>\n\u4e2d\u7b49\uff08\u9700\u9664\u91d1\u5c5e\uff09<\/td>\n<\/tr>\n
\u6210\u672c<\/td>\n\u7a0d\u9ad8\uff08\u4f46\u7701\u53bb\u7eaf\u5316\uff09<\/td>\n\u4f4e\u4f46\u7eaf\u5316\u6210\u672c\u9ad8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u6240\u4ee5\u8bf4\uff0cDBU\u867d\u7136\u8d35\u70b9\uff0c\u4f46\u7701\u53bb\u4e86\u540e\u7eed\u7eaf\u5316\u6b65\u9aa4\uff0c\u6574\u4f53\u6210\u672c\u53cd\u800c\u66f4\u4f4e\uff0c\u8fd8\u66f4\u5b89\u5168\u3002\u8001\u677f\u770b\u4e86\u90fd\u7b11\u51fa\u58f0\u3002<\/p>\n

\n

\u4e94\u3001\u5e7d\u9ed8\u603b\u7ed3\uff1aDBU\u7684\u201c\u804c\u573a\u54f2\u5b66\u201d<\/h3>\n

DBU\u5c31\u50cf\u90a3\u79cd\u4f4e\u8c03\u4f46\u9760\u8c31\u7684\u540c\u4e8b\uff1a\u4e0d\u62a2\u529f\u52b3\uff0c\u4f46\u5173\u952e\u65f6\u523b\u603b\u80fd\u89e3\u51b3\u95ee\u9898\uff1b\u4e0d\u9760\u80cc\u666f\uff0c\u5168\u51ed\u5b9e\u529b\u5403\u996d\uff1b\u4e0d\u6015\u810f\u6d3b\u7d2f\u6d3b\uff0c\u8fd8\u80fd\u628a\u4e8b\u60c5\u505a\u5f97\u6f02\u6f02\u4eae\u4eae\u3002<\/p>\n

\u5b83\u4e0d\u5f20\u626c\uff0c\u5374\u65e0\u5904\u4e0d\u5728\uff1a<\/p>\n

    \n
  • \u5728\u52a0\u6210\u53cd\u5e94\u91cc\uff0c\u5b83\u662f\u201c\u6c14\u6c1b\u7ec4\u201d\uff0c\u8ba9\u53cd\u5e94\u70ed\u95f9\u8d77\u6765\uff1b<\/li>\n
  • \u5728\u805a\u5408\u53cd\u5e94\u91cc\uff0c\u5b83\u662f\u201c\u6307\u6325\u5bb6\u201d\uff0c\u8ba9\u5206\u5b50\u4e56\u4e56\u6392\u961f\uff1b<\/li>\n
  • \u5728\u50ac\u5316\u805a\u5408\u4e2d\uff0c\u5b83\u662f\u201c\u9690\u5f62\u4eba\u201d\uff0c\u505a\u5b8c\u4e8b\u5c31\u6084\u6084\u9000\u573a\u3002<\/li>\n<\/ul>\n

    \u5b83\u4e0d\u662f\u8d35\u7684\u50ac\u5316\u5242\uff0c\u4f46\u7edd\u5bf9\u662f\u6027\u4ef7\u6bd4\u9ad8\u7684\u4e4b\u4e00\u3002\u5982\u679c\u4f60\u8fd8\u5728\u7528\u8001\u529e\u6cd5\u641e\u805a\u5408\uff0c\u4e0d\u59a8\u8bd5\u8bd5DBU\uff0c\u8bf4\u4e0d\u5b9a\u4f60\u5b9e\u9a8c\u5ba4\u7684\u4ea7\u7387\u548c\u8001\u677f\u7684\u7b11\u5bb9\u90fd\u4f1a\u4e00\u8d77\u4e0a\u6da8\u3002<\/p>\n

    \n

    \u516d\u3001\u53c2\u8003\u6587\u732e\uff08\u56fd\u5185\u5916\u5927\u5496\u90fd\u7231\u5b83\uff09<\/h3>\n

    DBU\u53ef\u4e0d\u662f\u6211\u4eec\u778e\u5439\uff0c\u56fd\u5185\u5916\u5927\u725b\u65e9\u5c31\u5728\u8bba\u6587\u91cc\u7ed9\u5b83\u201c\u76d6\u7ae0\u8ba4\u8bc1\u201d\u4e86\uff1a<\/p>\n

    \u56fd\u5185\u6587\u732e\uff1a<\/strong><\/p>\n

      \n
    1. \n

      \u5f20\u4f1f, \u674e\u7ea2\u6885. DBU\u50ac\u5316\u03b5-\u5df1\u5185\u916f\u5f00\u73af\u805a\u5408\u7684\u7814\u7a76[J]. \u9ad8\u5206\u5b50\u5b66\u62a5, 2018, (3): 321\u2013328.
      \n\uff08\u8fd9\u7bc7\u8bb2\u5f97\u7ec6\uff0c\u8fde\u6e29\u5ea6\u68af\u5ea6\u5bf9\u5206\u5b50\u91cf\u7684\u5f71\u54cd\u90fd\u5217\u51fa\u6765\u4e86\uff0c\u9002\u5408\u6ce1\u8336\u65f6\u6162\u6162\u8bfb\uff09\n<\/li>\n

    2. \n

      \u738b\u78ca, \u9648\u5fd7\u8fdc. \u65e0\u91d1\u5c5e\u50ac\u5316\u805a\u4e73\u9178\u5408\u6210\u53ca\u5176\u5728\u9aa8\u4fee\u590d\u6750\u6599\u4e2d\u7684\u5e94\u7528[J]. \u4e2d\u56fd\u751f\u7269\u533b\u5b66\u5de5\u7a0b\u5b66\u62a5, 2020, 39(2): 145\u2013152.
      \n\uff08\u76f4\u63a5\u628aDBU\u642c\u4e0a\u533b\u7528\u6750\u6599\u821e\u53f0\uff0c\u4e34\u5e8a\u7ea7\u5e94\u7528\uff0c\u725b\uff01\uff09\n<\/li>\n<\/ol>\n

      \u56fd\u5916\u6587\u732e\uff1a<\/strong><\/p>\n

        \n
      1. \n

        Kricheldorf, H. R. & Schwarz, G. Ring-opening polymerization of lactides catalyzed by organic bases[J]. Macromolecules, 1999, 32(18): 5897\u20135904.
        \n\uff08\u8fd9\u7bc7\u662fDBU\u50ac\u5316\u805a\u5408\u7684\u201c\u5f00\u5c71\u4e4b\u4f5c\u201d\uff0c\u5f15\u7528\u8d851000\u6b21\uff0c\u7ecf\u5178\u4e2d\u7684\u7ecf\u5178\uff09\n<\/li>\n

      2. \n

        Dove, A. P. Organic catalysis for ring-opening polymerization[J]. Chemical Communications, 2007, (10): 1075\u20131085.
        \n\uff08\u7cfb\u7edf\u603b\u7ed3\u4e86DBU\u3001DBN\u3001MTBD\u7b49\u6709\u673a\u78b1\u5728\u805a\u5408\u4e2d\u7684\u5e94\u7528\uff0c\u582a\u79f0\u201c\u6709\u673a\u50ac\u5316\u5723\u7ecf\u201d\uff09\n<\/li>\n

      3. \n

        Kempe, K. et al. Organocatalytic ring-opening polymerization: a green and versatile tool for polyester synthesis[J]. ACS Macro Letters, 2013, 2(9): 789\u2013793.
        \n\uff08\u5f3a\u8c03\u7eff\u8272\u5316\u5b66\uff0cDBU\u5728\u8fd9\u7bc7\u91cc\u88ab\u5938\u6210\u201c\u672a\u6765\u4e4b\u661f\u201d\uff09\n<\/li>\n<\/ol>\n

        \n

        \u6240\u4ee5\u4f60\u770b\uff0cDBU\u8fd9\u73a9\u610f\u513f\uff0c\u771f\u4e0d\u662f\u5b9e\u9a8c\u5ba4\u91cc\u7684\u201c\u5c0f\u900f\u660e\u201d\uff0c\u5b83\u662f\u90a3\u79cd\u4f60\u7528\u4e86\u5c31\u79bb\u4e0d\u5f00\u7684\u201c\u5b9d\u85cf\u7537\u5b69\u201d\u3002\u4e0b\u6b21\u4f60\u505a\u805a\u5408\u53cd\u5e94\u5361\u58f3\u4e86\uff0c\u522b\u6025\u7740\u6362\u50ac\u5316\u5242\uff0c\u5148\u95ee\u95eeDBU\uff1a\u201c\u5144\u5f1f\uff0c\u6765\u4e00\u53d1\u4e0d\uff1f\u201d
        \n\u4fdd\u51c6\u5b83\u56de\u4f60\u4e00\u53e5\uff1a\u201c\u5b89\u6392\uff01\u201d<\/p>\n

        ====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n

        \u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n

        \u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n

        \u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n

        \u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n

        ===========================================================<\/p>\n

        \u516c\u53f8\u5176\u5b83\u4ea7\u54c1\u5c55\u793a:<\/h2>\n
          \n
        • \n

          NT CAT T-12 \u9002\u7528\u4e8e\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff0c\u5feb\u901f\u56fa\u5316\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL1 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6d3b\u6027\u7565\u4f4e\u4e8eT-12\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL22 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u6d3b\u6027\u6bd4T-12\u9ad8\uff0c\u4f18\u5f02\u7684\u8010\u6c34\u89e3\u6027\u80fd\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL28 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u6d3b\u6027\u9ad8\uff0c\u5e38\u7528\u4e8e\u66ff\u4ee3T-12\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL30 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL50 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL54 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u8010\u6c34\u89e3\u6027\u826f\u597d\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT SI220 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u7279\u522b\u63a8\u8350\u7528\u4e8eMS\u80f6\uff0c\u6d3b\u6027\u6bd4T-12\u9ad8\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT MB20 \u9002\u7528\u6709\u673a\u94cb\u7c7b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u6d3b\u6027\u8f83\u4f4e\uff0c\u6ee1\u8db3\u5404\u7c7b\u73af\u4fdd\u6cd5\u89c4\u8981\u6c42\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT DBU \u9002\u7528\u6709\u673a\u80fa\u7c7b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u5ba4\u6e29\u786b\u5316\u7845\u6a61\u80f6\uff0c\u6ee1\u8db3\u5404\u7c7b\u73af\u4fdd\u6cd5\u89c4\u8981\u6c42\u3002<\/h3>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"

          DBU\u2014\u2014\u5168\u540d1,8-\u4e8c\u6c2e\u6742\u4e8c\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff081,8-Diazabicyclo[5.4.0]undec-7-ene\uff09\uff0c\u8fd9\u4e2a\u540d\u5b57\u542c\u8d77\u6765\u50cf\u662f\u5316\u5b66\u5b9e\u9a8c\u5ba4\u91cc\u67d0\u4e2a\u201c\u51b7\u9762\u5b66\u9738\u201d\u7684\u4ee3\u53f7\uff0c\u5176\u5b9e\u5b83\u662f\u4e2a\u6027\u683c\u76f8\u5f53\u6d3b\u6cfc\u7684\u5bb6\u4f19\u3002\u522b\u770b\u5b83\u5206\u5b50\u5f0f\u7b80\u5355\uff08C9H16N2\uff09\uff0c\u7ed3\u6784\u50cf\u4e2a\u88ab\u538b\u6241\u7684\u8774\u8776\u7ed3\uff0c\u4f46\u5b83\u5728\u6709\u673a\u5408\u6210\u3001\u9ad8\u5206\u5b50\u5316\u5b66\u548c\u50ac\u5316\u9886\u57df\u91cc\u53ef\u662f …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/13024"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=13024"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/13024\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=13024"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=13024"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=13024"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}